不同变质条件下变基性岩中磷灰石地球化学特征：以古元古代华北中部造山带为例

杨钰清; 高彭; 张健; 刘晓光; 程昌泉; 尹常青; 钱加慧

doi:10.12090/j.issn.1006-6616.2024046

不同变质条件下变基性岩中磷灰石地球化学特征：以古元古代华北中部造山带为例

doi: 10.12090/j.issn.1006-6616.2024046

1.
中山大学地球科学与工程学院，广东珠海 519082
2.
中国科学院壳幔物质与环境重点实验室中国科学技术大学地球和空间科学学院，安徽合肥 230026
3.
香港大学地球科学系，香港 999077
4.
海底科学与探测技术教育部重点实验室中国海洋大学海洋地球科学学院，山东青岛 266100

基金项目: 国家自然科学基金项目（42025204）

详细信息

作者简介:
杨钰清（1999—），女，在读硕士，主要从事构造地质学研究。Email：623359651@qq.com

通讯作者:
张健（1978—），男，教授，主要从事构造地质学和前寒武纪地质学研究。Email：jian@hku.hk

中图分类号: P584； P588.3
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- 被引次数: 0
出版历程
- 收稿日期: 2024-04-28
- 修回日期: 2024-05-22
- 录用日期: 2024-05-23
- 预出版日期: 2024-07-25
- 刊出日期: 2024-12-27

Geochemical characteristics of apatite in metabasic rocks under different metamorphic conditions: a case study from the Paleoproterozoic Trans-North China Orogen

1.
School of Earth Sciences and Engineering, Sun Yat-sen University, Zhuhai 519082, Guangdong, China
2.
CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, Anhui, China
3.
Department of Earth Sciences, The University of Hong Kong, Hong Kong 999077, China
4.
Key Lab of Submarine Geosciences and Prospecting Techniques, and College of Marine Geosciences, Ocean University of China, Qingdao 266100, Shandong, China

Funds: This research is financially supported by the National Natural Science Foundation of China (Grant No. 42025204).

摘要

摘要: 磷灰石是一种常见的副矿物，在各种岩石类型中均有产出，其U-Pb年龄、微量元素（特别是REE、Th、U和Sr等）和Sr-Nd同位素组成可提供重要的年代学和地球化学信息。目前对于其在造山过程中不同变质级别下的地球化学行为的研究并不清楚。作为古元古代典型的陆−陆碰撞造山带，华北克拉通中部造山带记录了一套从绿片岩相、经角闪岩相至麻粒岩相的完整变质岩石组合，因而是研究基性岩变质演化过程磷灰石地球化学属性的理想区域。文章在中部造山带的五台—恒山地区系统采集了绿片岩、斜长角闪岩和基性麻粒岩样品，并对不同变质级别变基性岩中的磷灰石进行了详细的岩相学和微量元素研究。研究结果表明，绿片岩样品中含有岩浆成因和变质成因2种类型的磷灰石，斜长角闪岩样品中主要为变质成因磷灰石，而基性麻粒岩样品中主要为深熔型磷灰石，表现出岩浆成因磷灰石的微量元素特征，可能结晶自深熔熔体。研究表明磷灰石的微量元素变化能够清晰地反映变质演化过程中随温压条件变化而出现的熔体和共存结晶矿物的影响，为了解造山作用过程中的元素迁移和平衡提供了新的约束。
- 华北克拉通 /
- 中部造山带 /
- 变基性岩 /
- 变质作用 /
- 磷灰石 /
- 微量元素
Abstract: Objective Apatite is a common accessory mineral that is widely distributed in various rock types. Its U-Pb age, trace elements (particularly REE, Th, U, and Sr), and Sr-Nd isotopic compositions provide important information on its chronology and magmatism. However, the geochemical behavior at different metamorphic levels during orogenesis remains unclear. As a typical continent-to-continent collisional orogenic belt in the Paleoproterozoic, the Trans-North China Orogen (TNCO) has recorded an integrated metamorphic sequence ranging from greenschist to amphibolite to granulite facies. Therefore, it is an ideal area to study the geochemical behavior of apatite during various grades of metamorphism involving the orogenic process. Methods In this study, we systematically collected metabasic samples of different metamorphic grades, including greenschist, amphibolite, and mafic granulite, in the Wutai-Hengshan area of the TNCO. We conducted detailed petrographic observations and geochemical analyses of apatite grains from metabasic rocks with different metamorphic grades. Results Our results showed that the apatite grains from the greenschist samples had both magmatic and metamorphic origins. The apatite grains in the amphibolite samples were mainly of metamorphic origin. In contrast, the grains from the granulite samples were closely related to crustal anatexis, exhibiting geochemical characteristics of magmatic-origin apatite. Conclusion This study shows that trace element variations in apatite can clearly reflect the influence of metamorphic grades, crustal anatexis, and coexisting rock-forming minerals with variations in temperature and pressure conditions during metamorphism. Significance The results of this study provide new constraints to our understanding of elemental migration and the geochemical balance within apatite during orogeny.
- North China Craton /
- Trans-North China Orogen /
- metabasic rocks /
- metamorphism /
- apatite /
- trace elements

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图 1 华北克拉通构造单元划分（据Zhao et al.，2001，2005修改）

Figure 1. Tectonic subdivision of the North China Craton (modified after Zhao et al., 2001, 2005)

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图 2 五台杂岩和恒山杂岩主要岩性单元划分以及样品采集位置（据Zhao et al.，2007；Zhang et al.，2012修改）

Figure 2. Lithologic map of the Wutai-Hengshan Complex and the sampling locations in this study (modified after Zhao et al., 2007; Zhang et al., 2012)

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图 3 五台—恒山地区杂岩体中不同变质级别变基性岩野外照片和其对应的近照

a、b—绿片岩；c、d—斜长角闪岩；e、f—基性麻粒岩

Figure 3. Field photograph of metabasic rocks of different metamorphic grades in the Wutai-Hengshan Complex and the representative photos

(a, b) Greenschist; (c, d) Plagioclase amphibolite; (e, f) Mafic granulite

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图 4 样品显微镜下特征

Ap—磷灰石；Chl—绿泥石；Fsp—长石；Grt—石榴子石；Hbl—角闪石；Ilm—钛铁矿；Px—辉石；Qtz—石英；Zr—锆石a、b—22WT-03样品；c、d—22WT-21样品；e、f—22WT-07样品；g、h—22WT-22样品；i、j—22WT-09样品；k、l—22WT-12样品

Figure 4. Microscopic characteristics of the samples

(a, b) Sample 22WT-03; (c, d) Sample 22WT-21; (e, f) Sample 22WT-07; (g, h) Sample 22WT-22; (i, j) Sample 22WT-09; (k, l) Sample 22WT-12Ap—apatite; Chl—chlorite; Fsp—feldspar; Grt—garnet; Hbl—hornblende; Ilm—ilmenite; Px—pyroxene; Qtz—quartz; Zr—zircon

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图 5 代表性磷灰石CL图

红圈为原位微量元素分析点，束斑直径为32 uma、b—绿片岩；c、d—斜长角闪岩；e、f—基性麻粒岩

Figure 5. Cathodoluminescence (CL) images of the representative samples

(a, b) Greenschist; (c, d) Plagioclase amphibolite；(e, f) Mafic granuliteThe red circle is the location of in-situ analysis, with a beam spot of 32 μm in width.

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图 6 五台—恒山地区变基性岩全岩主量元素图解

a—Nb/Y-Zr/Ti图解（底图据Pearce，1996）；b—SiO₂−TFeO/MgO图解（底图据Miyashiro，1974）；c—TiO₂−TFeO/MgO图

Figure 6. Diagram of whole rock major element of the metabasic rocks in the Wutai-Hengshan area

(a) Nb/Y-Zr/Ti classification diagram of metabasic rocks in Wutai and Hengshan (modified after Pearce, 1996); (b) SiO₂-TFeO/MgO classification diagram (modified afterMiyashiro, 1974); (c) Diagram of TiO₂-TFeO/MgO

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图 7 全岩微量元素图解（标准化值据Sun and McDonough, 1989）

a—变基性岩球粒陨石标准化稀土元素配分图；b—原始地幔标准化微量元素蛛网图

Figure 7. Diagram of whole rock trace element (standardized values according to Sun and McDonough, 1989)

(a) Chondrite-normalized diagram of rare earth element for the metabasic rocks; (b) Primitive mantle-normalized diagram of trace elements for the metabasic rocks

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图 8 不同变质级别样品中磷灰石主量元素图解

a—F−CaO图解；b—Cl−CaO图解；c—P₂O₅−CaO图解；d—SiO₂−CaO图解；e—FeO−CaO图解；f—MnO−CaO图解

Figure 8. Major element diagram of apatite grains of different metamorphic grades

(a) F-CaO relationship diagram; (b) Cl-CaO relationship diagram; (c) P₂O₅-CaO relationship diagram; (d) SiO₂-CaO relationship diagram; (e) FeO-CaO relationship diagram; (f) MnO-CaO relationship diagram

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图 9 不同变质级别样品中磷灰石微量元素图解

a—绿片岩样品微量元素图解；b—斜长角闪岩样品微量元素图解；c—基性麻粒岩样品微量元素图解

Figure 9. Trace element diagram of apatite grains of different metamorphic grades

(a) Trace element diagram of apatite grains of greenschist; (b) Trace element diagram of apatite grains of plagioclase amphibolite; (c) Trace element diagram of apatite grains of mafic granulite

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图 10 不同成因类型磷灰石微量元素图解（据O'Sullivan et al., 2020修改）

Figure 10. Trace element diagram of apatite of different genetic types (modified after O'Sullivan et al., 2020)

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图 11 大别−苏鲁造山带固态重结晶深熔锆石球粒陨石标准化稀土模式图（据Chen and Zheng, 2017修改；文献数据参考Chen et al., 2010; Xia et al., 2010）

灰色部分为岩浆成因的原岩锆石

Figure 11. Chondrite-normalized REE patterns for solid-state recrystallization of metamorphosed zircons from the Dabie-Sulu Orogenic Belt (modified after Chen and Zheng, 2017;Reference data: Chen et al., 2010; Xia et al., 2010)

The gray zone denotes the protolith zircon of magmatic origin.

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表 1 五台-恒山地区变基性岩全岩主量元素（%）与微量元素(×10⁻⁶)组成

Table 1. Whole rock major (%) and trace element (×10⁻⁶) compositions of the metabasic rocks in the Wutai-Hengshan area

样品名称	绿片岩		斜长角闪岩		基性麻粒岩
样品名称	22WT-03	22WT-21	22WT-07	22WT-22	22WT-09	22WT-12
SiO₂	44.98	44.66	49.63	48.79	49.89	48.85
TiO₂	0.85	0.86	0.60	0.94	1.74	0.96
Al₂O₃	15.41	14.36	15.86	14.56	12.70	13.79
TFe₂O₃	8.46	8.38	11.31	12.71	18.70	14.98
MnO	0.16	0.18	0.15	0.17	0.26	0.22
MgO	3.69	3.57	7.64	7.22	4.54	6.95
CaO	12.58	11.02	9.60	11.36	9.31	10.82
Na₂O	1.32	1.08	1.79	1.75	2.31	1.75
K₂O	2.65	3.13	0.75	0.15	0.78	1.00
P₂O₅	0.30	0.34	0.07	0.07	0.20	0.10
LOI	8.72	11.90	2.08	2.07	−0.01	0.32
SUM	99.12	99.49	99.48	99.79	100.41	99.72
FeO	5.28	5.05	6.60	8.60	10.90	10.30
TFeO	7.61	7.55	9.28	11.44	16.83	13.48
Sc	12.47	22.45	35.43	40.88	43.82	46.57
Ti	5095.75	5167.69	3620.98	5605.33	10413.32	5725.23
V	95.41	174.57	213.12	284.21	356.60	297.35
Cr	124.66	501.90	134.69	184.70	29.56	77.51
Co	14.30	29.08	51.54	50.83	49.84	58.67
Ni	55.87	133.80	177.18	106.60	26.91	69.78
Cu	11.02	74.26	78.99	122.01	45.55	83.11
Zn	304.52	72.84	74.29	88.04	141.05	92.70
Ga	15.46	18.13	15.63	16.69	19.38	16.84
Rb	57.80	116.88	20.92	2.86	26.98	47.35
Sr	99.51	774.66	199.13	112.84	119.17	64.81
Y	13.38	24.35	14.14	18.32	44.90	24.79
Zr	121.28	130.53	44.74	46.49	138.71	60.03
Nb	5.04	9.80	1.88	2.62	7.51	3.12
Sn	0.94	1.36	0.51	0.47	1.27	0.61
Cs	0.61	1.42	2.45	0.38	0.60	0.51
Ba	311.93	1053.04	93.76	18.27	199.41	151.06
La	16.21	23.60	4.91	2.32	13.49	5.87
Ce	36.33	52.03	10.97	6.24	33.84	13.63
Pr	4.32	6.60	1.57	1.06	4.67	2.02
Nd	15.92	27.17	6.64	5.50	20.39	9.50
Sm	3.29	5.31	1.84	1.95	5.67	2.78
Eu	0.91	1.40	0.72	0.69	1.68	0.91
Gd	2.77	4.60	2.22	2.67	6.58	3.53
Tb	0.44	0.72	0.40	0.48	1.10	0.60
Dy	2.53	4.17	2.48	3.11	7.62	4.14
Ho	0.53	0.85	0.54	0.67	1.63	0.90
Er	1.41	2.37	1.54	1.98	4.78	2.46
Tm	0.21	0.35	0.22	0.28	0.66	0.36
Yb	1.42	2.34	1.53	1.92	4.61	2.48
Lu	0.21	0.36	0.22	0.29	0.69	0.38
Hf	3.14	3.13	1.26	1.29	3.75	1.66
Ta	0.38	0.47	0.11	0.15	0.47	0.18
Pb	4.95	8.84	2.03	0.98	2.66	0.90
Th	5.33	3.95	0.50	0.21	2.30	0.58
U	1.17	1.01	0.12	0.06	0.50	0.09
(La/Sm) _N	3.08	2.77	1.67	0.74	1.49	1.32
(La/Yb) _N	7.74	6.84	2.18	0.82	1.99	1.60
δEu	0.89	0.84	1.08	0.92	0.84	0.89
注：部分样品的烧失量为负数，因为样品中可能含有较多的低价态金属氧化物，高温氧化，所以烧失量为负数

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表 2 五台—恒山地区变基性岩磷灰石主量元素组成 (%)

Table 2. Apatite major element compositions of the metabasic rocks in the Wutai-Hengshan area (%)

样品点号	K₂O	SO₃	CaO	FeO	MgO	Al₂O₃	P₂O₅	SrO	MnO	Na₂O	SiO₂	F	Cl	合计
Ap-03-1	0	0.12	54.83	0	0	0	41.34	0.03	0.02	0.05	0.26	4.31	0.02	99.17
Ap-03-2	0	0.06	55.00	0	0	0.02	41.18	0.08	0	0	0.01	4.24	0.02	98.83
Ap-03-3	0	0.12	54.03	0.12	0.02	0	41.59	0.07	0.04	0.03	0.03	4.07	0.03	98.44
Ap-03-4	0	0	54.49	0.01	0	0.03	42.13	0.10	0.03	0	0	4.73	0.02	99.52
Ap-03-5	0	0.26	54.54	0.08	0	0	42.05	0.14	0.06	0.06	0.18	4.65	0.02	100.07
Ap-03-6	0	0	54.81	0.05	0	0	41.21	0.03	0.10	0.06	0	4.74	0.03	99.02
Ap-03-7	0	0.16	54.24	0.13	0	0	41.05	0.04	0.02	0.04	0.32	4.50	0	98.62
Ap-03-8	0	0.32	54.44	0.07	0.01	0.02	40.28	0.16	0	0.06	0.37	4.32	0.01	98.23
Ap-03-9	0.02	0.24	54.50	0.17	0.13	0	41.25	0.19	0.04	0.11	0.24	4.45	0.03	99.47
Ap-03-10	0	0.07	54.49	0.01	0.01	0.02	42.47	0.05	0	0.08	0	4.34	0.01	99.72
Ap-21-1	0	0.01	54.54	0.05	0	0	42.88	0.35	0.06	0	0	4.46	0.01	100.49
Ap-21-2	0	0	54.84	0	0	0.01	42.38	0.34	0.02	0	0.01	4.50	0	100.20
Ap-21-3	0	0.01	55.01	0.01	0	0.01	42.21	0.34	0	0	0.02	4.45	0.01	100.20
Ap-21-4	0.01	0	53.86	0	0	0.01	42.06	0.40	0	0.01	0	5.22	0.01	99.38
Ap-21-5	0.02	0.01	54.42	0.01	0	0	42.27	0.43	0.02	0	0.01	4.58	0	99.84
Ap-21-6	0.01	0	54.76	0.10	0	0	42.30	0.38	0.02	0.01	0.01	4.49	0	100.20
Ap-21-7	0	0	54.27	0.04	0	0	42.38	0.32	0	0	0	4.40	0.02	99.57
Ap-21-8	0.02	0.02	54.08	0	0	0	42.71	0.17	0.02	0	0	5.00	0	99.90
Ap-21-9	0	0.01	54.51	0.09	0.02	0.01	42.56	0.36	0	0	0	4.43	0.01	100.14
Ap-21-10	0	0.03	54.72	0	0.01	0.02	42.44	0.36	0	0	0	4.74	0.01	100.33
Ap-07-1	0.01	0.05	55.20	0	0	0.02	41.56	0.10	0.03	0.03	0	4.50	0	99.62
Ap-07-2	0.03	0	53.24	0.01	0.36	0.38	40.96	0.02	0.05	0.02	0.08	1.70	1.38	98.18
Ap-07-3	0	0.02	54.37	0	0	0	41.79	0.02	0.07	0.01	0.02	1.29	1.28	98.04
Ap-07-4	0.01	0	54.27	0.05	0	0	41.72	0.01	0.04	0.03	0	1.35	1.42	98.01
Ap-07-5	0	0	54.25	0	0.03	0	41.53	0.04	0.06	0	0	1.45	1.22	97.69
Ap-07-6	0.01	0.08	54.44	0.01	0.01	0	41.84	0.03	0.05	0	0.01	1.51	1.24	98.30
Ap-07-7	0.03	0	53.83	0.14	0	0	41.46	0.04	0.05	0.01	0	1.24	1.54	97.46
Ap-07-8	0	0.03	53.70	0	0.01	0	42.09	0	0.02	0.02	0	1.64	0.91	97.51
Ap-07-9	0	0	54.17	0.01	0.02	0	42.58	0.01	0.01	0.04	0	1.39	1.49	98.80
Ap-07-10	0.01	0.03	53.84	0.11	0	0	41.31	0.01	0	0	0	1.64	1.19	97.19
Ap-22-1	0	0.03	54.19	0.04	0	0	42.53	0.01	0.08	0.04	0.03	1.43	2.27	99.53
Ap-22-2	0	0.07	54.51	0.03	0	0	41.83	0.01	0.05	0.07	0	1.44	2.24	99.13
Ap-22-3	0.01	0.03	54.84	0	0.04	0	42.35	0	0.06	0	0.01	2.08	0.87	99.20
Ap-22-4	0.01	0	54.99	0	0	0.01	42.37	0.03	0.04	0	0	2.38	0.41	99.13
Ap-22-5	0	0.02	54.57	0.08	0	0	42.59	0.02	0.05	0	0.03	2.13	0.54	99.01
Ap-22-6	0	0	54.02	0.01	0	0.01	41.74	0.02	0.04	0.02	0.01	1.61	2.32	98.58
Ap-22-7	0	0.02	54.80	0.09	0	0	41.65	0.04	0.07	0	0	2.22	1.31	98.98
Ap-22-8	0	0.04	54.77	0.06	0.01	0.02	42.47	0.01	0.04	0	0	2.89	0.61	99.56
Ap-22-9	0	0.01	54.32	0	0	0	41.91	0.01	0.06	0	0	1.35	2.17	98.78
Ap-22-10	0.01	0	55.00	0.01	0.03	0	42.08	0	0.08	0	0.03	2.14	0.37	98.75
Ap-09-1	0	0	54.95	0.04	0.01	0	41.20	0.02	0.02	0.01	0	3.43	0.03	98.26
Ap-09-2	0	0.03	54.18	0	0.02	0	42.13	0.01	0	0.01	0	3.91	0.03	98.67
Ap-09-3	0	0	54.45	0.06	0.01	0	41.32	0	0.02	0	0.04	3.46	0.04	97.93
Ap-09-4	0	0.02	53.81	0	0	0.01	41.67	0	0	0.01	0.02	3.49	0.05	97.60
Ap-09-5	0.01	0	54.91	0.01	0.01	0	42.06	0.02	0	0.02	0.02	3.69	0.05	99.23
Ap-09-6	0	0	54.79	0.06	0	0	41.93	0.01	0.06	0	0.04	3.54	0.02	98.96
Ap-09-7	0	0.03	54.57	0	0.02	0.02	41.45	0	0	0.03	0.01	3.73	0.04	98.32
Ap-09-8	0	0.05	53.88	0	0	0.01	41.97	0	0.04	0	0	3.49	0.03	98.00
Ap-09-9	0	0	54.11	0.04	0.02	0	42.30	0	0.06	0.04	0.03	3.78	0.04	98.83
Ap-09-10	0	0.01	54.19	0.05	0	0	41.75	0	0.02	0.04	0	3.56	0.05	98.15
Ap-12-1	0	0	54.49	0.08	0	0	41.50	0.02	0.02	0.09	0	3.78	0.15	98.51
Ap-12-2	0	0.06	54.59	0.03	0	0.02	42.05	0.02	0.04	0.01	0.01	3.56	0.14	99.00
Ap-12-3	0	0	53.69	0	0	0.01	41.54	0.02	0.04	0	0.07	3.75	0.15	97.65
Ap-12-4	0.01	0.04	54.56	0.03	0	0	41.83	0.03	0.06	0	0.06	3.97	0.17	99.04
Ap-12-5	0	0	54.17	0.03	0.01	0	42.08	0.01	0.06	0.04	0.04	3.57	0.16	98.62
Ap-12-6	0	0.04	55.07	0	0	0.01	41.87	0	0.06	0.04	0.05	3.52	0.15	99.30
Ap-12-7	0.03	0.01	53.69	0.08	0	0	41.92	0	0.04	0.05	0.06	3.57	0.13	98.03
Ap-12-8	0.03	0.02	54.64	0.06	0	0.04	41.74	0	0.07	0.03	0.05	3.86	0.16	99.05
Ap-12-9	0	0	54.93	0.05	0	0	41.96	0	0.09	0	0.09	3.82	0.24	99.52
Ap-12-10	0	0.01	54.40	0.04	0	0.01	41.75	0.03	0.03	0.01	0	3.56	0.22	98.49

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表 3 五台—恒山地区变基性岩岩浆成因磷灰石微量元素组成(×10⁻⁶)

Table 3. Trace element compositions of magmatic apatite in metabasic rocks from the Wutai-Hengshan area (×10⁻⁶)

样品点号	Rb	Sr	Y	Zr	Ba	Ga	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Hf	Nb	Ta	Pb	Th	U	(La/Yb) _N	δEu
Ap-03-2	0.03	1368.16	211.21	0.28	0.68	3.41	17.86	94.98	25.52	195.47	64.37	16.93	61.55	7.52	40.58	7.49	19.22	2.42	14.94	2.14	0	0	0	7.2	2.3	11.06	0.81	0.82
Ap-03-3	0.05	1004.23	296.07	0.1	0.42	2.44	10.16	65.76	19.06	162.25	61.25	17.09	69.89	9.26	55.28	11.22	28.42	3.69	22.18	3.08	0	0	0	8.62	2.35	8.91	0.31	0.8
Ap-03-5	0.32	1396.01	315.92	0.27	1.13	3.28	18.47	108.84	29.5	228.15	63.76	17.67	63.88	9.38	60.91	12.21	30.68	3.75	20.79	2.55	0	0.03	0	7.13	3.4	3.33	0.6	0.84
Ap-03-6	0.18	367.66	1340.29	0.04	0.21	7.86	90.85	361.61	71.45	430.42	181.11	17.02	244.68	43.53	262.76	48.27	125.31	16.59	106.09	13.88	0	0	0	6.58	4.02	5.11	0.58	0.25
Ap-03-10	0	400.93	277.6	0.12	0.38	5.04	61.86	223.69	41.29	243.34	66.91	15.85	80.09	9.31	49.3	9.67	25.2	3.19	18.84	3.07	0	0	0	4.01	4.4	3.18	2.23	0.66
Ap-03-11	0.06	3514.45	496.51	0	0	0.87	3.4	14.53	3.42	27.13	16.93	7.58	44.2	9.37	78.37	18.61	47.6	4.62	17.23	1.39	0	0	0	7.44	0.01	0	0	0.84
Ap-03-12	0.28	680.29	509.08	0.15	0.49	1.37	7.57	29.7	6.22	45.09	19.65	10.8	49.3	12.85	99.75	20.92	53.53	6.51	36.49	4.15	0	0	0	12.46	5.52	5.43	0.14	1.06
Ap-03-15	0.06	590.07	378.58	0.38	0.25	5.19	86.02	278.72	42.66	208.67	38.25	15.59	50.64	9.32	68.37	14	37.43	4.72	30.12	3.87	0	0	0	10.25	11.55	4.28	1.94	1.08
Ap-03-16	0.06	1536.28	400.4	0.44	0.93	5.73	36.02	195.81	53.63	424.94	134.48	31.84	133.31	15.13	77.7	14.2	35.62	4.49	26.12	3.88	0	0.01	0	9.36	1.11	12.28	0.94	0.72
Ap-03-20	0.14	713.26	704.28	1.81	0.88	3.05	25.82	99.77	20.58	140.25	63.02	17.53	104.35	20.36	142.86	27.93	70.25	8.6	48.61	5.58	0.02	0	0	13.05	5.44	8.91	0.36	0.66
Ap-21-2	0.19	2541.29	234.71	43.83	1.29	0.63	1.57	6.63	1.61	12.12	8.03	3.4	19.56	4.35	34.53	8.82	23.31	2.24	8.16	0.62	1.04	−	−	5.43	0.02	−	0.13	0.83
Ap-21-3	0.12	3120.9	411.41	310.55	0.65	1.34	17.83	43.35	7.04	36.6	15.44	5.55	32.7	6.56	57.17	14.8	42.15	4.44	19.46	1.75	8.63	−	−	7.35	5.47	−	0.62	0.75
Ap-21-4	0.03	3577.44	471.93	1.04	0	0.75	3.5	15.55	3.52	28.49	19.27	8.4	48.87	10.15	80.46	17.99	45.16	4.26	15.77	1.38	0.04	−	−	7.51	0.02	−	0.15	0.83
Ap-21-5	1.4	3460.81	418.28	0.02	11.13	1.24	4.06	16.16	3.83	29.19	17.46	7.39	42.59	8.55	67.3	15.87	38.51	3.65	13.88	1.09	0	−	−	7.24	2.24	−	0.2	0.83
Ap-21-6	2.12	1051.97	84.37	104.44	48.64	1.28	11.56	30.85	4.65	23.65	6.31	1.77	8.74	1.64	13.2	2.9	8.3	0.98	5.12	0.53	2.55	−	−	2.67	4.93	−	1.53	0.73
Ap-21-7	0.06	3547.7	459.25	710.89	0	0.85	3.16	13.83	3.29	27.35	17.51	8.09	46.13	9.45	75.56	16.63	41.57	4.08	16.33	1.69	19.92	−	−	8.54	0.06	−	0.13	0.87
Ap-21-8	0.08	3476.36	399.06	15.65	0	0.92	2.84	11.96	2.87	22.26	13.67	6.52	35.76	7.89	64.21	14.77	37.38	3.59	12.79	1.09	0.43	−	−	7.35	0.26	−	0.15	0.9
Ap-21-9	0.09	2984.42	305.04	25.91	0.36	1.33	12.68	33.04	4.77	25.79	11.75	4.86	26.74	5.67	46.4	10.95	29.01	2.84	10.24	0.87	0.56	−	−	6.72	1.45	−	0.84	0.84
Ap-21-11	0.05	3517.78	500.66	−	0	0.91	3.55	14.91	3.51	27.66	18.25	7.84	47.01	10.19	83.51	18.66	46.43	4.21	15.35	1.28	0	−	−	7.5	0.01	−	0.16	0.82
Ap-07-1	0.01	379.37	2.94	0	1.25	0.67	0.76	1.88	0.26	1.84	0.6	0.16	0.57	0.08	0.51	0.11	0.38	0.08	0.49	0.08	0	0	0	0.78	0.02	0.11	1.05	0.85
Ap-07-2	−	360.8	4.31	0	0.71	0.84	0.47	1.16	0.17	0.93	0.39	0.09	0.82	0.09	0.49	0.16	0.58	0.1	0.69	0.14	0	0	0	0.64	0.01	0.07	0.46	0.46
Ap-07-3	0.18	312.5	4.89	0.01	0.46	0.75	0.78	1.3	0.23	1.6	0.38	0.1	0.78	0.12	0.66	0.17	0.63	0.11	0.9	0.18	0	0	0	0.52	0.02	0.05	0.59	0.54
Ap-07-4	−	312.78	3.28	0	0.42	0.87	0.18	0.44	0.05	0.4	0.17	0.01	0.31	0.05	0.37	0.12	0.4	0.1	0.7	0.08	0	0	0	0.51	0.04	0.06	0.18	0.12
Ap-07-5	0.44	370.84	3.57	0.09	4.94	1.24	0.88	2.19	0.3	2.09	0.38	0.11	0.74	0.09	0.45	0.14	0.51	0.07	0.69	0.13	0	0	0	0.73	0.01	0.08	0.87	0.61
Ap-07-6	0	328.42	2.55	0.19	0.51	0.72	0.1	0.2	0.03	0.23	0.08	0.01	0.09	0.03	0.28	0.08	0.31	0.07	0.51	0.11	0	0	0	0.56	0.03	0.09	0.13	0.33
Ap-07-7	0	440.71	3.92	1.51	1.24	0.96	0.94	2.28	0.36	2.26	0.54	0.2	1.16	0.12	0.75	0.16	0.47	0.07	0.63	0.1	0.05	0	0	1.01	0.01	0.07	1.01	0.79
Ap-07-8	0.01	335.44	2.18	0	0.37	0.82	0.14	0.2	0.03	0.27	0.05	0.01	0.15	0.03	0.21	0.08	0.36	0.05	0.5	0.12	0	0	0	0.52	0	0.07	0.18	0.53
Ap-07-9	0.01	243.68	5.52	0	0.29	0.68	0.08	0.14	0.02	0.14	0.03	0.01	0.17	0.05	0.55	0.18	0.74	0.1	0.91	0.18	0	0	0	0.38	0	0.12	0.06	0.64
Ap-07-10	0	303.45	24.04	0.44	0.54	0.83	1.56	4.63	0.84	4.86	1.79	0.67	3.25	0.53	4.13	0.94	3.29	0.54	4.87	0.93	0	0.01	0	1.19	5.22	0.08	0.22	0.85
Ap-07-11	0.03	342.21	105.74	2.13	0.59	1.02	7.83	23.13	4.04	23.98	9.55	3.45	16.7	2.82	18.24	4.31	12.4	1.73	13.57	2.53	0	0	0	1.11	2.97	0.02	0.39	0.83
Ap-07-12	0	221.87	4.24	0	0.42	0.74	0.09	0.24	0.03	0.33	0.13	0.02	0.3	0.07	0.47	0.16	0.56	0.12	0.8	0.15	0	0	0	0.42	0	0.03	0.08	0.36
Ap-07-13	−	369.02	35.61	84.63	0.45	0.96	2.18	6.89	1.27	7.67	3.16	1.02	5.16	0.94	5.85	1.45	4.15	0.62	4.66	0.82	1.98	0	0	1.23	2.21	0.65	0.32	0.77
Ap-07-14	−	313.06	4.55	0.01	0.87	0.7	0.1	0.21	0.03	0.27	0.1	0.03	0.37	0.07	0.55	0.16	0.68	0.12	0.94	0.18	0	0	0	0.51	0.39	0.07	0.07	0.47
Ap-22-1	0	184.15	99.84	0	0.17	0.9	3.97	15.11	3.62	27.59	14.61	5.84	21.41	3.22	19.21	3.58	9.16	1.08	5.61	0.67	0	−	−	0.57	0	−	0.48	1.01
Ap-22-2	0	185.64	152.79	0	0.18	0.76	3.62	13.6	3.4	26.77	17.04	6.33	29.14	4.89	29.73	5.83	14.31	1.62	8.3	1	0	−	−	0.56	0.01	−	0.3	0.87
Ap-22-3	0.01	177.59	64.89	0	0.29	0.9	3.48	14.66	3.58	25.88	12.64	5.11	16.03	2.2	11.92	2.3	5.97	0.64	3.83	0.59	0	−	−	0.92	0	−	0.62	1.1
Ap-22-4	0.14	211.54	81.79	0.04	0.22	1.04	3.55	16.16	4.08	30.14	15.09	4.91	20.47	3.05	16.92	3.04	7.78	0.92	4.82	0.68	0	−	−	1.5	0.01	−	0.5	0.85
Ap-22-5	0.03	183.41	149.24	0	0	1.11	3.41	14.81	3.68	31.45	19.64	5.74	30.47	5.06	27.99	5.23	11.89	1.29	6.47	0.82	0	−	−	0.47	0	−	0.36	0.72
Ap-22-6	0.04	161.4	46.19	0	0.37	0.88	2.12	11.38	3.25	25.04	11.11	4.2	11.72	1.72	9.14	1.67	4.23	0.53	3.11	0.41	0	−	−	0.79	0.01	−	0.46	1.12
Ap-22-7	0.03	189.95	80.26	−	0.17	0.89	3.68	14.65	3.63	27.58	15.01	4.56	20.06	2.76	16.16	2.82	7.24	0.77	4.12	0.5	0	−	−	1.02	0	−	0.61	0.8
Ap-22-8	0	191.69	100.46	0	0	0.84	3.23	13.76	3.51	28.49	15.54	5.45	22.08	3.34	19.13	3.69	9.29	1.11	5.68	0.75	0	−	−	0.42	0.01	−	0.39	0.9
Ap-22-9	0	186.33	121.87	0	0.16	0.8	3.9	15.23	3.57	26.74	14.89	6.22	23.94	3.81	23.66	4.55	11.84	1.39	8.11	0.95	0	−	−	0.95	0.01	−	0.33	1
Ap-22-10	0.25	193.79	169	45.78	0.55	1.25	4.95	19.56	4.5	33.69	19	5.87	31.62	4.97	30.63	6.13	15.53	1.76	9.8	1.19	1.27	−	−	0.56	0.02	−	0.34	0.73
Ap-22-11	0.08	184.26	148.02	0	0.25	0.96	4.24	16.11	3.96	29.57	16.53	5.73	27.79	4.56	28.27	5.77	14.57	1.64	8.95	1.04	0	−	−	0.42	0.01	−	0.32	0.81
Ap-22-12	−	177.85	55.42	1.39	0.2	0.78	3.95	14.74	3.31	24.43	11.95	4.48	15.02	2.09	11.53	2.05	5.1	0.61	3.67	0.46	0.02	−	−	0.94	0	−	0.73	1.02
Ap-22-13	0.01	178.61	101.4	0	0.2	1.1	3.12	13.43	3.29	26.7	14.79	5.57	21.88	3.25	20.13	3.81	10.13	1.1	6.35	0.82	0	−	−	0.85	0	−	0.33	0.94
Ap-22-14	0	197.55	62.3	0	0.11	0.8	2.27	11.49	2.93	23.35	10.66	3.25	13.73	2.06	12.26	2.45	6.39	0.78	4.16	0.49	0	−	−	1.33	0.01	−	0.37	0.82
Ap-22-15	0.12	172.03	61.61	0	0.22	0.93	3.46	16.78	4.04	29.51	11.54	2.99	12.34	1.88	11.1	2.28	6.08	0.79	4.88	0.8	0	−	−	0.94	0	−	0.48	0.76
Ap-22-16	0	179.23	104.41	0	0.25	0.62	3.53	14.85	3.51	29.62	17	5.36	26.23	3.71	20.08	4	9.64	1.06	5.6	0.62	0	−	−	0.32	0	−	0.43	0.77
Ap-22-17	0	192.03	110.25	0	0.11	0.84	4.34	17.93	4.12	33.57	19.55	5.36	29.49	4.15	23.07	4.32	10.41	1.2	5.61	0.67	0	−	−	0.3	0	−	0.53	0.68
Ap-22-18	−	189.31	111.03	0	0	0.77	3.73	16.01	3.72	29.33	18.51	5.44	28.42	4.04	23.24	4.26	9.64	0.99	4.83	0.61	0	−	−	0.41	0	−	0.52	0.72

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表 4 五台—恒山地区变基性岩变质成因磷灰石微量元素组成(×10⁻⁶)

Table 4. Trace element compositions of metamorphic apatite in metabasic rocks from the Wutai-Hengshan area (×10⁻⁶)

样品点号	Rb	Sr	Y	Zr	Ba	Ga	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb	Lu	Hf	Nb	Ta	Pb	Th	U	（La/Yb） _N	δEu
Ap-03-2	0.03	1368.16	211.21	0.28	0.68	3.41	17.86	94.98	25.52	195.47	64.37	16.93	61.55	7.52	40.58	7.49	19.22	2.42	14.94	2.14	0	0	0	7.2	2.3	11.06	0.81	0.82
Ap-03-3	0.05	1004.23	296.07	0.1	0.42	2.44	10.16	65.76	19.06	162.25	61.25	17.09	69.89	9.26	55.28	11.22	28.42	3.69	22.18	3.08	0	0	0	8.62	2.35	8.91	0.31	0.8
Ap-03-5	0.32	1396.01	315.92	0.27	1.13	3.28	18.47	108.84	29.5	228.15	63.76	17.67	63.88	9.38	60.91	12.21	30.68	3.75	20.79	2.55	0	0.03	0	7.13	3.4	3.33	0.6	0.84
Ap-03-6	0.18	367.66	1340.29	0.04	0.21	7.86	90.85	361.61	71.45	430.42	181.11	17.02	244.68	43.53	262.76	48.27	125.31	16.59	106.09	13.88	0	0	0	6.58	4.02	5.11	0.58	0.25
Ap-03-10	0	400.93	277.6	0.12	0.38	5.04	61.86	223.69	41.29	243.34	66.91	15.85	80.09	9.31	49.3	9.67	25.2	3.19	18.84	3.07	0	0	0	4.01	4.4	3.18	2.23	0.66
Ap-03-11	0.06	3514.45	496.51	0	0	0.87	3.4	14.53	3.42	27.13	16.93	7.58	44.2	9.37	78.37	18.61	47.6	4.62	17.23	1.39	0	0	0	7.44	0.01	0	0	0.84
Ap-03-12	0.28	680.29	509.08	0.15	0.49	1.37	7.57	29.7	6.22	45.09	19.65	10.8	49.3	12.85	99.75	20.92	53.53	6.51	36.49	4.15	0	0	0	12.46	5.52	5.43	0.14	1.06
Ap-03-15	0.06	590.07	378.58	0.38	0.25	5.19	86.02	278.72	42.66	208.67	38.25	15.59	50.64	9.32	68.37	14	37.43	4.72	30.12	3.87	0	0	0	10.25	11.55	4.28	1.94	1.08
Ap-03-16	0.06	1536.28	400.4	0.44	0.93	5.73	36.02	195.81	53.63	424.94	134.48	31.84	133.31	15.13	77.7	14.2	35.62	4.49	26.12	3.88	0	0.01	0	9.36	1.11	12.28	0.94	0.72
Ap-03-20	0.14	713.26	704.28	1.81	0.88	3.05	25.82	99.77	20.58	140.25	63.02	17.53	104.35	20.36	142.86	27.93	70.25	8.6	48.61	5.58	0.02	0	0	13.05	5.44	8.91	0.36	0.66
Ap-21-2	0.19	2541.29	234.71	43.83	1.29	0.63	1.57	6.63	1.61	12.12	8.03	3.4	19.56	4.35	34.53	8.82	23.31	2.24	8.16	0.62	1.04	−	−	5.43	0.02	−	0.13	0.83
Ap-21-3	0.12	3120.9	411.41	310.55	0.65	1.34	17.83	43.35	7.04	36.6	15.44	5.55	32.7	6.56	57.17	14.8	42.15	4.44	19.46	1.75	8.63	−	−	7.35	5.47	−	0.62	0.75
Ap-21-4	0.03	3577.44	471.93	1.04	0	0.75	3.5	15.55	3.52	28.49	19.27	8.4	48.87	10.15	80.46	17.99	45.16	4.26	15.77	1.38	0.04	−	−	7.51	0.02	−	0.15	0.83
Ap-21-5	1.4	3460.81	418.28	0.02	11.13	1.24	4.06	16.16	3.83	29.19	17.46	7.39	42.59	8.55	67.3	15.87	38.51	3.65	13.88	1.09	0	−	−	7.24	2.24	−	0.2	0.83
Ap-21-6	2.12	1051.97	84.37	104.44	48.64	1.28	11.56	30.85	4.65	23.65	6.31	1.77	8.74	1.64	13.2	2.9	8.3	0.98	5.12	0.53	2.55	−	−	2.67	4.93	−	1.53	0.73
Ap-21-7	0.06	3547.7	459.25	710.89	0	0.85	3.16	13.83	3.29	27.35	17.51	8.09	46.13	9.45	75.56	16.63	41.57	4.08	16.33	1.69	19.92	−	−	8.54	0.06	−	0.13	0.87
Ap-21-8	0.08	3476.36	399.06	15.65	0	0.92	2.84	11.96	2.87	22.26	13.67	6.52	35.76	7.89	64.21	14.77	37.38	3.59	12.79	1.09	0.43	−	−	7.35	0.26	−	0.15	0.9
Ap-21-9	0.09	2984.42	305.04	25.91	0.36	1.33	12.68	33.04	4.77	25.79	11.75	4.86	26.74	5.67	46.4	10.95	29.01	2.84	10.24	0.87	0.56	−	−	6.72	1.45	−	0.84	0.84
Ap-21-11	0.05	3517.78	500.66	−	0	0.91	3.55	14.91	3.51	27.66	18.25	7.84	47.01	10.19	83.51	18.66	46.43	4.21	15.35	1.28	0	−	−	7.5	0.01	−	0.16	0.82
Ap-07-1	0.01	379.37	2.94	0	1.25	0.67	0.76	1.88	0.26	1.84	0.6	0.16	0.57	0.08	0.51	0.11	0.38	0.08	0.49	0.08	0	0	0	0.78	0.02	0.11	1.05	0.85
Ap-07-2	−	360.8	4.31	0	0.71	0.84	0.47	1.16	0.17	0.93	0.39	0.09	0.82	0.09	0.49	0.16	0.58	0.1	0.69	0.14	0	0	0	0.64	0.01	0.07	0.46	0.46
Ap-07-3	0.18	312.5	4.89	0.01	0.46	0.75	0.78	1.3	0.23	1.6	0.38	0.1	0.78	0.12	0.66	0.17	0.63	0.11	0.9	0.18	0	0	0	0.52	0.02	0.05	0.59	0.54
Ap-07-4	−	312.78	3.28	0	0.42	0.87	0.18	0.44	0.05	0.4	0.17	0.01	0.31	0.05	0.37	0.12	0.4	0.1	0.7	0.08	0	0	0	0.51	0.04	0.06	0.18	0.12
Ap-07-5	0.44	370.84	3.57	0.09	4.94	1.24	0.88	2.19	0.3	2.09	0.38	0.11	0.74	0.09	0.45	0.14	0.51	0.07	0.69	0.13	0	0	0	0.73	0.01	0.08	0.87	0.61
Ap-07-6	0	328.42	2.55	0.19	0.51	0.72	0.1	0.2	0.03	0.23	0.08	0.01	0.09	0.03	0.28	0.08	0.31	0.07	0.51	0.11	0	0	0	0.56	0.03	0.09	0.13	0.33
Ap-07-7	0	440.71	3.92	1.51	1.24	0.96	0.94	2.28	0.36	2.26	0.54	0.2	1.16	0.12	0.75	0.16	0.47	0.07	0.63	0.1	0.05	0	0	1.01	0.01	0.07	1.01	0.79
Ap-07-8	0.01	335.44	2.18	0	0.37	0.82	0.14	0.2	0.03	0.27	0.05	0.01	0.15	0.03	0.21	0.08	0.36	0.05	0.5	0.12	0	0	0	0.52	0	0.07	0.18	0.53
Ap-07-9	0.01	243.68	5.52	0	0.29	0.68	0.08	0.14	0.02	0.14	0.03	0.01	0.17	0.05	0.55	0.18	0.74	0.1	0.91	0.18	0	0	0	0.38	0	0.12	0.06	0.64
Ap-07-10	0	303.45	24.04	0.44	0.54	0.83	1.56	4.63	0.84	4.86	1.79	0.67	3.25	0.53	4.13	0.94	3.29	0.54	4.87	0.93	0	0.01	0	1.19	5.22	0.08	0.22	0.85
Ap-07-11	0.03	342.21	105.74	2.13	0.59	1.02	7.83	23.13	4.04	23.98	9.55	3.45	16.7	2.82	18.24	4.31	12.4	1.73	13.57	2.53	0	0	0	1.11	2.97	0.02	0.39	0.83
Ap-07-12	0	221.87	4.24	0	0.42	0.74	0.09	0.24	0.03	0.33	0.13	0.02	0.3	0.07	0.47	0.16	0.56	0.12	0.8	0.15	0	0	0	0.42	0	0.03	0.08	0.36
Ap-07-13	−	369.02	35.61	84.63	0.45	0.96	2.18	6.89	1.27	7.67	3.16	1.02	5.16	0.94	5.85	1.45	4.15	0.62	4.66	0.82	1.98	0	0	1.23	2.21	0.65	0.32	0.77
Ap-07-14	−	313.06	4.55	0.01	0.87	0.7	0.1	0.21	0.03	0.27	0.1	0.03	0.37	0.07	0.55	0.16	0.68	0.12	0.94	0.18	0	0	0	0.51	0.39	0.07	0.07	0.47
Ap-22-1	0	184.15	99.84	0	0.17	0.9	3.97	15.11	3.62	27.59	14.61	5.84	21.41	3.22	19.21	3.58	9.16	1.08	5.61	0.67	0	−	−	0.57	0	−	0.48	1.01
Ap-22-2	0	185.64	152.79	0	0.18	0.76	3.62	13.6	3.4	26.77	17.04	6.33	29.14	4.89	29.73	5.83	14.31	1.62	8.3	1	0	−	−	0.56	0.01	−	0.3	0.87
Ap-22-3	0.01	177.59	64.89	0	0.29	0.9	3.48	14.66	3.58	25.88	12.64	5.11	16.03	2.2	11.92	2.3	5.97	0.64	3.83	0.59	0	−	−	0.92	0	−	0.62	1.1
Ap-22-4	0.14	211.54	81.79	0.04	0.22	1.04	3.55	16.16	4.08	30.14	15.09	4.91	20.47	3.05	16.92	3.04	7.78	0.92	4.82	0.68	0	−	−	1.5	0.01	−	0.5	0.85
Ap-22-5	0.03	183.41	149.24	0	0	1.11	3.41	14.81	3.68	31.45	19.64	5.74	30.47	5.06	27.99	5.23	11.89	1.29	6.47	0.82	0	−	−	0.47	0	−	0.36	0.72
Ap-22-6	0.04	161.4	46.19	0	0.37	0.88	2.12	11.38	3.25	25.04	11.11	4.2	11.72	1.72	9.14	1.67	4.23	0.53	3.11	0.41	0	−	−	0.79	0.01	−	0.46	1.12
Ap-22-7	0.03	189.95	80.26	−	0.17	0.89	3.68	14.65	3.63	27.58	15.01	4.56	20.06	2.76	16.16	2.82	7.24	0.77	4.12	0.5	0	−	−	1.02	0	−	0.61	0.8
Ap-22-8	0	191.69	100.46	0	0	0.84	3.23	13.76	3.51	28.49	15.54	5.45	22.08	3.34	19.13	3.69	9.29	1.11	5.68	0.75	0	−	−	0.42	0.01	−	0.39	0.9
Ap-22-9	0	186.33	121.87	0	0.16	0.8	3.9	15.23	3.57	26.74	14.89	6.22	23.94	3.81	23.66	4.55	11.84	1.39	8.11	0.95	0	−	−	0.95	0.01	−	0.33	1
Ap-22-10	0.25	193.79	169	45.78	0.55	1.25	4.95	19.56	4.5	33.69	19	5.87	31.62	4.97	30.63	6.13	15.53	1.76	9.8	1.19	1.27	−	−	0.56	0.02	−	0.34	0.73
Ap-22-11	0.08	184.26	148.02	0	0.25	0.96	4.24	16.11	3.96	29.57	16.53	5.73	27.79	4.56	28.27	5.77	14.57	1.64	8.95	1.04	0	−	−	0.42	0.01	−	0.32	0.81
Ap-22-12	−	177.85	55.42	1.39	0.2	0.78	3.95	14.74	3.31	24.43	11.95	4.48	15.02	2.09	11.53	2.05	5.1	0.61	3.67	0.46	0.02	−	−	0.94	0	−	0.73	1.02
Ap-22-13	0.01	178.61	101.4	0	0.2	1.1	3.12	13.43	3.29	26.7	14.79	5.57	21.88	3.25	20.13	3.81	10.13	1.1	6.35	0.82	0	−	−	0.85	0	−	0.33	0.94
Ap-22-14	0	197.55	62.3	0	0.11	0.8	2.27	11.49	2.93	23.35	10.66	3.25	13.73	2.06	12.26	2.45	6.39	0.78	4.16	0.49	0	−	−	1.33	0.01	−	0.37	0.82
Ap-22-15	0.12	172.03	61.61	0	0.22	0.93	3.46	16.78	4.04	29.51	11.54	2.99	12.34	1.88	11.1	2.28	6.08	0.79	4.88	0.8	0	−	−	0.94	0	−	0.48	0.76
Ap-22-16	0	179.23	104.41	0	0.25	0.62	3.53	14.85	3.51	29.62	17	5.36	26.23	3.71	20.08	4	9.64	1.06	5.6	0.62	0	−	−	0.32	0	−	0.43	0.77
Ap-22-17	0	192.03	110.25	0	0.11	0.84	4.34	17.93	4.12	33.57	19.55	5.36	29.49	4.15	23.07	4.32	10.41	1.2	5.61	0.67	0	−	−	0.3	0	−	0.53	0.68
Ap-22-18	−	189.31	111.03	0	0	0.77	3.73	16.01	3.72	29.33	18.51	5.44	28.42	4.04	23.24	4.26	9.64	0.99	4.83	0.61	0	−	−	0.41	0	−	0.52	0.72

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