Meso-Neoproterozoic tectono-thermal evolution in the northern margin of North China Craton: Constraints from zircon (U-Th)/He ages
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摘要: 由于复杂的构造沉积史和缺乏有效古温标，华北克拉通北缘燕辽裂陷带中—新元古界热史研究很薄弱，造成古老烃源岩成熟演化过程一直存在争议。研究利用锆石（U-Th）/He热定年技术探讨了燕辽裂陷带自中元古代以来的构造-热演化史，并分析了中元古界两套烃源岩成熟演化期次。燕辽裂陷带中—新元古界单颗粒锆石（U-Th）/He年龄均小于地层年龄，有效地记录了研究区早期的热信息，其中新元古界龙山组单颗粒（U-Th）/He年龄与有效铀浓度具有负相关性。通过正、反演耦合模拟明确了燕辽裂陷带曾经历过440~310 Ma和~220 Ma至今两期快速冷却事件，分别由白乃庙岛弧碰撞和蒙古-鄂霍次克洋洋壳俯冲引起；并揭示出奥陶纪末期和三叠纪末期地层温度变化对古老烃源岩成熟演化具有重要影响。
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关键词:
- 锆石(U-Th)/He /
- 燕辽裂陷带 /
- 中—新元古界 /
- 正演模拟 /
- 烃源岩成熟演化
Abstract: Due to the complicated tectonic and sedimentary history and the lack of effective paleo-thermal indicators, the Meso-Neoproterozoic thermal history of the Yanliao rift zone in the northern margin of the North China Craton is ambiguous, which causes the maturation evolution of ancient source rocks controversial. In this study, zircon (U-Th)/He dating is used to study the tectono-thermal evolution of the Yanliao rift zone since the Mesoproterozoic, and we also analyzed the maturation evolution stages of two sets of Mesoproterozoic source rocks. The single-grain zircon (U-Th)/He ages from the Meso-Neoproterozoic strata in the Yanliao rift zone are all younger than the corresponding stratigraphic ages and therefore recorded the thermal information in the past. Moreover, the single-grain zircon (U-Th)/He ages of the Neoproterozoic Longshan formation show a negative correlation with the effective uranium concentration. The forward and inverse coupling simulation revealed that the Yanliao rift zone experienced two rapid cooling events of 440~320 Ma and 220~0 Ma, probably related to the collision between the Bainaimiao island arc and the northern margin of the North China Craton and the subduction of Mongolia Okhotsk oceanic crust below the eastern North China Craton, respectively. In addition, the formation temperature variations at the end of Ordovician and the end of Triassic had an important influence on the maturation evolution of Mesoproterozoic source rock. -
图 1 华北克拉通北缘燕辽裂陷带构造单元及样品位置(据王铁冠等, 2016修改)
Figure 1. Tectonic units of the Yanliao rift zone in the northern margin of North China Carton, showing the sample locations (modified after Wang et al., 2016)
图 2 燕辽裂陷带中新元古界地层柱状图(据王浩等, 2019修改)
Figure 2. Stratigraphic column of Meso-Neoproterozoic strata in the Yanliao rift zone (modified after Wang et al., 2019)
图 3 华北克拉通北缘燕辽裂陷带样品单颗粒锆石(U-Th)/He年龄与有效铀浓度和颗粒半径关系图
图中虚线表示样品沉积年龄
a—锆石(U-Th)/He年龄与有效铀浓度关系; b—锆石(U-Th)/He年龄与颗粒半径关系Figure 3. Correlation of zircon (U-Th)/He age with effective uranium concentration (a) and particle radius (b) in the samples from the Yanliao rift zone
The dotted lines in the figures indicate the deposition age of the samples
图 4 青白口系龙山组样品热史模拟结果
a—正演模拟中输入的热史路径; b—e—分别表示不同热史路径下模拟得出的继承性包络线与实测年龄之间的关系(图中浅灰色、中灰色、深灰色区域分别对应起始时间为2500 Ma、1800 Ma和900 Ma的模拟结果); f—反演模拟得到的可能热史路径(其中绿色线代表拟合度较低的热史路径, 紫色线代表拟合度较高的热史路径, 黑色线为最佳热史路径, 黑色方框为反演模拟的约束条件)
Figure 4. Thermal history modeling results of the samples from the Longshan formation in the Qingbaikou system
(a) The input thermal history path in a forward modeling; (b-e) The inherited envelopes obtained from different thermal history paths; The light gray area, medium gray area and dark gray area in the figure represent the modeling results corresponding to the starting time of 2500 Ma, 1800 Ma, and 900 Ma, respectively; (f) The possible thermal history path obtained by inversion modeling, in which green lines represent the thermal history path with low fitting degree, purple lines represent the thermal history path with high fitting degree, black line is the most possible thermal history path, and black boxes are constraints of inverse modeling
图 5 长城系大红峪组样品热史模拟结果
a—正演模拟中输入的热史路径; b—e—分别表示不同热史路径下模拟得出的继承性包络线与实测年龄之间的关系(图中深灰色和灰色区域分别对应起始时间为2500 Ma和1620 Ma的模拟结果); f—反演模拟得到的可能热史路径(其中绿色线代表拟合度较低的热史路径, 紫色线代表拟合度较高的热史路径, 黑色线为最佳热史路径, 黑色方框为反演模拟的约束条件)
Figure 5. Thermal history modeling results of the samples from the Dahongyu formation in the Changcheng system
(a) The Input thermal history path in a forward modeling; (b-e) The inherited envelopes obtained from different thermal history paths; The dark gray area and the gray area in the figure represent the modeling results corresponding to the starting time of 2500 Ma and 1620 Ma, respectively; (f) The possible thermal history path obtained by inversion modeling, in which green lines represent the thermal history path with low fitting degree, purple lines represent the thermal history path with high fitting degree, black line is the most possible thermal history path, and black boxes are constraints of inverse modeling
图 6 常州沟组样品热史模拟结果
a—正演模拟中输入的热史路径; b—e—分别表示不同热史路径下模拟得出的继承性包络线与实测年龄之间的关系(图中深灰色和灰色区域分别对应起始时间为2500 Ma和1800 Ma的模拟结果); f—反演模拟得到的可能热史路径(其中绿色线代表拟合度较低的热史路径, 紫色线代表拟合度较高的热史路径, 黑色线为最佳热史路径, 黑色方框为反演模拟的约束条件)
Figure 6. Thermal history modeling results of the samples from the Changzhougou formation in the Changcheng system
(a) The input thermal history path in a forward modeling; (b-e) The inherited envelopes obtained from different thermal history paths; The dark gray area and the gray area in the figure represent the modeling results corresponding to the starting time of 2500 Ma and 1800 Ma, respectively; (f) The possible thermal history path obtained by inversion modeling, in which green lines represent the thermal history path with low fitting degree, purple lines represent the thermal history path with high fitting degree, black line is the most possible thermal history path, and black boxes are constraints of inverse modeling
图 7 燕辽裂陷带热演化史与烃源岩成熟度演化史
Figure 7. Thermal evolution history and maturity evolution of source rocks in the Yanliao rift zone
表 1 燕辽裂陷带中新元古界锆石(U-Th)/He年龄测试结果
Table 1. Zircon (U-Th)/He data of Meso-Neoproterozoic in the Yanliao rift zone
样品号 U/×10-6 Th/×10-6 He/(nmol/g) Th/U 半径/μm 质量/μg eU/×10-6 年龄/Ma ±1σ/Ma Ft 校正年龄/Ma ±1σ/Ma LX1-1 215.141 147.737 378.94 0.710 39.8 3.08 249.9 276.46 4.49 0.721 383.44 20.16 LX1-2 64.033 63.799 160.62 1.030 37.1 2.63 79.0 367.82 6.53 0.701 524.71 27.84 LX1-3 121.428 116.531 269.33 0.992 31.9 1.64 148.8 328.55 5.53 0.657 500.08 26.38 LX1-4 98.279 90.884 308.12 0.956 37.3 2.43 119.6 462.42 8.71 0.702 658.72 35.20 LX1-5 122.785 76.599 313.18 0.645 42.2 3.37 140.8 401.21 7.09 0.737 544.38 28.87 LX1-6 93.467 83.668 284.90 0.925 32.1 1.53 113.1 452.50 8.92 0.662 683.53 36.74 LX1-7 558.091 324.982 602.87 0.602 29.6 1.37 634.5 174.73 2.96 0.637 274.30 14.48 LX1-8 255.394 177.548 429.69 0.718 33.0 1.69 297.1 263.93 4.57 0.671 393.34 20.81 LX2-1 109.620 66.037 92.85 0.622 50.9 6.41 125.1 136.88 2.27 0.779 175.71 9.26 LX2-2 187.939 93.531 124.31 0.514 39.1 2.69 209.9 109.52 2.07 0.718 152.53 8.15 LX2-3 172.895 104.976 152.60 0.627 46.6 4.96 197.6 142.43 2.34 0.759 187.65 9.88 LX2-5 174.687 100.043 111.15 0.592 41.6 2.98 198.2 103.76 1.83 0.734 141.36 7.49 LX2-6 347.411 93.139 140.20 0.277 30.1 1.31 369.3 70.49 1.23 0.646 109.12 5.78 LX2-7 171.052 99.991 104.70 0.604 48.2 5.15 194.5 99.60 1.66 0.767 129.86 6.84 LX2-8 213.721 173.049 156.02 0.837 41.4 2.96 254.4 113.33 1.89 0.731 155.03 8.17 LX3-1 220.110 98.923 124.56 0.464 40.2 2.99 243.4 94.79 1.60 0.725 130.74 6.90 LX3-2 230.152 109.995 169.00 0.494 44.2 4.05 256.0 121.97 2.23 0.748 163.06 8.68 LX3-3 735.832 442.919 466.39 0.622 33.8 1.76 839.9 102.74 1.69 0.678 151.53 7.98 LX3-4 159.371 50.203 80.15 0.486 38.0 2.40 136.0 108.99 1.89 0.712 153.08 8.10 LX3-5 99.963 30.396 86.51 0.325 38.8 2.38 171.2 93.64 1.56 0.72 130.06 6.85 LX3-6 297.526 84.226 46.24 0.314 27.2 0.99 107.1 80.08 1.71 0.613 130.64 7.10 LX3-7 165.490 37.400 177.01 0.293 37.4 2.21 317.3 103.27 1.82 0.71 145.45 7.71 LX3-8 159.371 50.203 86.37 0.234 33.7 1.80 174.3 91.85 2.34 0.681 134.88 7.57 注: Ft为α粒子射出效应的校正参数, 计算方法详见Farley et al. (1996); eU为有效铀浓度, 计算公式为eU=U+0.235×Th (Flowers et al., 2009) 
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