THE WALL ROCK ALTERATION AND ITS GEOCHEMICAL CHARACTERISTICS OF ZHAOPING FAULT ZONE IN JIAODONG
-
摘要: 招平断裂带是胶东地区重要的金成矿带, 众多蚀变型、石英脉型金矿床产出于该带及下盘次级断裂中。以招平断裂带破头青断裂为研究对象, 进行剖面测量和取样测试分析, 探讨围岩蚀变地球化学特征。研究结果显示, 招平断裂带破头青断裂蚀变分带明显, 不同蚀变强度的蚀变岩中常量元素迁移规律明显, REE配分曲线表现为HREE富集, Eu、Ce均有较明显的负异常, 从弱蚀变至强蚀变过程中, ΣREE、LREE和HREE均有明显降低, 且相应特征值表现出规律的变化, Au-Ag-Bi-Co-Cu-Mo-Ni-Pb-Zn是金成矿密切相关的指示元素组合。Abstract: Zhao-Ping fault belt is an important gold metallogenic belt in Jiaodong area, and lots of altered-rock-types and quartz-vein-type gold deposits output in the belt and secondary faults of the footwall. To explore the geochemical features of the wall rock alteration, the Potouqing fault in Zhao-ping fault belt is taken as the research object, with the profile measuring and sample analyzing. It's showed that the alteration zones of the Potouqing fault are evident in Zhaoping fault belt. With the different alteration intensities in altered rock, the major elements' migration regularity is obvious. The enrichment of HREE is showed in the REE distribution curve. Eu and Ce have obviously negative anomaly. With the process from weak alteration to strong alteration, theΣREE, LREE and HREE significantly decrease, and the regular changes are showed by the corresponding characteristic value, Au-Ag-Bi-Co-Cu-Mo-Ni-Pb-Zn is the indicator element suite which is closely related to the gold mineralization.
-
Key words:
- Zhaoping fault zone /
- geochemical characteristics /
- Jiaodong
-
图 1 胶东西北部金矿区域地质图[8]
1-第四系;2-新第三系;3-白垩系;4-侏罗系;5-蓬莱群;6-粉子山群;7-荆山群;8-胶东岩群;9-玲珑花岗岩;10-郭家岭花岗岩;11-栖霞复背斜轴;12-新华夏系压扭性断裂;13-华夏系压扭性断裂;14-金矿床;15-研究区
Figure 1. The regional geological map of the Jiaodong northwestern gold deposit
表 1 招平断裂带破头青断裂常量元素成分(%)
Table 1. The major element constituents of Potouqing fault in Zhaoping fault zone
样品号 SiO2 Al2O3 CaO TiO2 Fe2O3 K2O MgO MnO Na2O P2O5 LOI Total 1015-1 75.24 13.51 0.39 0.08 1.08 3.84 0.11 0.02 4.31 0.018 1.12 99.79 1015-2 72.10 14.73 0.41 0.12 1.23 4.10 0.11 0.02 4.54 0.021 0.93 98.42 1015-3 76.97 13.37 0.12 0.08 1.13 3.45 0.18 0.01 2.84 0.031 1.58 99.90 1015-4 77.42 12.97 0.11 0.07 1.07 3.64 0.15 0.01 3.25 0.021 1.19 100.00 1015-5 74.91 14.34 0.09 0.09 0.96 3.68 0.19 0.03 3.84 0.025 1.24 99.53 1015-7 73.60 13.28 1.17 0.07 1.61 3.36 0.23 0.09 4.17 0.025 1.98 99.77 1015-9 73.68 13.29 1.04 0.08 0.81 3.61 0.10 0.03 4.36 0.021 1.52 98.65 1015-11 72.43 13.37 2.14 0.09 0.97 4.06 0.13 0.04 3.97 0.024 2.45 99.87 1015-13 75.51 13.76 0.07 0.08 0.89 4.08 0.15 0.02 4.54 0.026 0.72 99.98 注:1015-1、1015-2为弱钾化花岗岩;1015-3、1015-4为强钾化花岗岩;1015-5、1015-7、1015-9、1015-11、1015-13为绢英岩 表 2 招平断裂带破头青断裂稀土元素含量(μg/g)及其特征参数
Table 2. The content of REE and characteristic parameters of Potouqing fault in Zhaoping fault zone
样品号 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y ΣREE LREE HREE LREE/HREE (La/Yb)N δEu δCe 1015-1 27.6 57.6 6.25 22.4 4.83 0.44 3.44 0.49 2.62 0.51 1.19 0.19 1.35 0.20 15.4 129.11 119.12 8.25 11.92 13.82 0.31 1.00 1015-2 23.7 43.6 4.61 15.4 3.13 0.48 2.07 0.29 1.48 0.27 0.70 0.10 0.57 0.10 8.3 96.50 90.92 4.81 16.29 28.10 0.54 0.93 1015-3 25.0 44.2 4.75 16.1 3.14 0.48 2.20 0.38 2.16 0.37 1.12 0.17 0.97 0.14 13.0 101.18 93.67 6.23 12.47 17.42 0.53 0.90 1015-4 20.9 37.2 3.99 13.2 2.59 0.33 1.53 0.22 1.22 0.22 0.60 0.08 0.54 0.07 6.9 82.69 78.21 3.79 17.46 26.15 0.47 0.90 1015-5 25.2 42.7 4.85 17.2 3.32 0.52 2.25 0.34 1.88 0.33 0.93 0.12 0.71 0.10 9.9 100.45 93.79 5.73 14.08 23.98 0.55 0.86 1015-7 18.2 33.5 3.57 12.6 2.40 0.40 1.81 0.28 1.47 0.30 0.72 0.11 0.71 0.10 8.9 76.17 70.67 4.58 12.85 17.32 0.56 0.93 1015-9 20.6 37.9 3.94 13.1 2.93 0.43 1.89 0.27 1.80 0.34 1.01 0.13 0.73 0.10 9.9 85.17 78.90 5.31 12.58 19.07 0.52 0.93 1015-11 19.3 35.5 3.61 12.3 2.38 0.48 1.82 0.30 1.56 0.27 0.79 0.11 0.67 0.10 8.3 79.19 73.57 4.74 13.09 19.47 0.68 0.94 1015-13 17.7 32.7 3.45 11.9 2.21 0.38 1.77 0.27 1.75 0.33 0.86 0.12 0.85 0.11 9.6 74.40 68.34 4.98 11.28 14.07 0.57 0.93 注:1015-1、1015-2为弱钾化花岗岩;1015-3、1015-4为强钾化花岗岩;1015-5、1015-7、1015-9、1015-11、1015-13为绢英岩 表 3 招平断裂带破头青断裂微量元素含量(μg/g)
Table 3. Trace element constituents of Potouqing fault in Zhaoping fault zone
样品号 Au Ag As Bi Co Cu Hg Mo Ni Pb Sb Sn W Zn 1015-1 0.001 0.06 0.2 0.03 1 1 < 0.005 0.52 2 47 < 5 3 < 1 30 1015-2 0.001 0.02 0.1 0.01 1 1 < 0.005 0.28 1 28 < 5 2 < 1 48 1015-3 0.001 0.02 0.1 0.01 1 2 < 0.005 0.28 4 25 5 3 < 1 96 1015-4 0.001 0.01 0.3 0.01 1 1 < 0.005 0.31 3 24 < 5 2 < 1 70 1015-5 0.001 0.03 0.1 0.05 1 2 < 0.005 0.34 2 48 < 5 2 2 64 1015-7 0.002 0.06 0.1 0.06 2 2 < 0.005 0.57 14 24 < 5 2 1 84 1015-9 0.001 0.02 0.1 0.01 1 2 < 0.005 0.45 1 23 < 5 2 1 47 1015-11 0.002 0.26 0.1 0.04 1 1 < 0.005 0.43 1 100 < 5 1 1 66 1015-13 0.001 0.03 0.1 0.04 1 1 < 0.005 0.72 3 26 5 1 1 75 表 4 招平断裂带破头青断裂微量元素相关系数矩阵
Table 4. Trace elements correlation matrix of Potouqing fault in Zhaoping fault zone
Au Ag As Bi Co Cu Mo Ni Pb Sn W Zn Au 1.00 Ag 0.75 1.00 As -0.27 -0.20 1.00 Bi 0.61 0.36 -0.33 1.00 Co 0.66 0.02 -0.18 0.59 1.00 Cu 0.06 -0.29 -0.45 0.17 0.40 1.00 Mo 0.25 0.12 -0.19 0.57 0.34 -0.15 1.00 Ni 0.56 -0.09 -0.10 0.55 0.97 0.42 0.33 1.00 Pb 0.53 0.93 -0.14 0.33 -0.21 -0.31 -0.02 -0.32 1.00 Sn -0.40 -0.47 0.25 -0.36 0.00 0.34 -0.41 0.09 -0.38 1.00 W -0.19 -0.13 -0.18 0.40 -0.13 0.40 -0.23 -0.13 0.14 0.00 1.00 Zn 0.30 -0.01 -0.20 0.20 0.36 0.39 -0.02 0.52 -0.17 -0.13 -0.01 1.00 注:1015-1、1015-2为弱钾化花岗岩;1015-3、1015-4为强钾化花岗岩;1015-5、1015-7、1015-9、1015-11、1015-13为绢英岩 -
[1] 吕古贤, 郭涛, 刘杜鹃.玲珑-焦家式金矿构造地质特征及成矿构造物理化学参量因子分析——以阜山金矿区为例[J].地球学报, 2002, 23(5):409~416. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200205004.htmLÜ Gu-xian, GUO Tao, LIU Du-juan. Geological and structural characteristics of the Linglong-Jiaojia type gold deposits and factor analysis of their metallogenic tectonic physicochemical parameters: Exemplified by the Fushan cold deposit [J]. Acta Geoscientica Sinica, 2002, 23(5):409~416. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200205004.htm [2] 刘晓煌, 张效智, 哈本海, 等.招平断裂带地质特征及成矿预测浅析[J].黄金, 2003, 24(12):10~13. doi: 10.3969/j.issn.1001-1277.2003.12.004ZHANG Xiao-huang, ZHANG Xiao-zhi, HA Ben-hai, et al.The geological characteristics of Zhaoping fault zone and its mineralization prognosis[J]. Gold, 2003, 24(12):10~13. doi: 10.3969/j.issn.1001-1277.2003.12.004 [3] 李金祥. 胶东西北部招平断裂带构造特征与成矿[D]. 中国地质大学(北京)博士学位论文, 2005.LI Jin-xiang. Study on the structural nature and minerlization of Zhaoping fault belt in northwestern Jiaodong peninsula[D]. A Dissertation Submitted toChina University of Geosciences for Doctoral Degree, 2005. [4] 郭涛. 胶西北金矿区域成矿系统及其构造-流体-矿化研究[D]. 北京: 中国地质大学, 2005.GUO Tao. Study on gold metallogenic system and tectono-fluid-mineralization of Jiaoxibei region[D]. Beijing: China University of Geosciences, 2005. [5] 申玉科, 邓军, 徐叶兵.煌斑岩在玲珑金矿田形成过程中的地质意义[J].地质与勘探, 2005, 41(3):45~49. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKT200503011.htmSHEN Yu-ke, DENG Jun, XU Ye-bing.Geological significance of lamprophyre during gold mineralization in the Linglong ore field[J]. Geology and Prospecting, 2005, 41(3):45~49. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKT200503011.htm [6] 申玉科. 胶西北金矿集中区构造-蚀变网络研究[D]. 北京: 中国地质大学, 2006.SHEN Yu-ke. Study on tectono-alteration net of gold in northwest Jiaodong[D]. Beijing: China University of Geosciences, 2005. [7] 张文钊, 徐述平.招平断裂带成矿特征与找矿靶区[J].黄金科学技术, 2005, 13(4):7~16. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKJ200602000.htmZHANG Wen-zhao, XU Shu-ping. Gold metallogenic features and prospecting targets of the Zhaoping fault zone[J]. Gold Science and Technology, 2005, 13(4):7~16. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKJ200602000.htm [8] 徐述平. 招平断裂带金矿勘查模型与成矿预测[D]. 北京: 中国地质大学, 2009.XU Shu-ping.Gold exploration model and mineralization prediction in Zhaoping fault zone[D]. Beijing: China University of Geosciences, 2009. [9] 高海东, 胡宝群, 吕古贤, 等.玲珑金矿大开头矿区47号脉微量元素特征[J].地质力学学报, 2013, 19(1):53~62. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?flag=1&file_no=20130106&journal_id=dzlxxbGUO Hai-dong, HU Bao-qun, LÜ Gu-xian, et al.Trace element characteristics of the No.47 vein in Dakaitou ore districat of Linglong gold deposit[J]. Journal of Geomechanics, 2013, 19(1):53~62. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?flag=1&file_no=20130106&journal_id=dzlxxb [10] 胡宝群, 高海东, 申玉科, 等.玲珑金矿大开头矿区金的赋存特征及其成因意义[J].东华理工大学学报, 2013, 36(4):1~7. http://www.cnki.com.cn/Article/CJFDTOTAL-HDDZ201304002.htmHU Bao-qun, GUO Hai-dong, SHEN Yu-ke, et al. The gold occurrence characteristics and their genetic significance in Dakaitou district of Linglong gold Ore-deposit[J]. Journal of East China Institute of Technology, 2013, 36(4):1~7. http://www.cnki.com.cn/Article/CJFDTOTAL-HDDZ201304002.htm [11] 艾金彪, 马生明, 朱立新, 等.长江中下游马头斑岩型钼铜矿床常量元素、稀土元素特征及迁移规律[J].地质学报, 2013, 87(5):691~702. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201305007.htmAI Jin-biao, MA Sheng-ming, ZHU Li-xin, et al. Characteristic and migration regularity of major elements and REE in Matou porphyry Mo-Cu deposit in the middle-lower reaches of Yangtze River[J]. Acta Geologica Sinica, 2013, 87(5):691~702. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201305007.htm [12] 王超凡, 吕古贤, 郭涛, 等.玲珑金矿田破头青断裂带稀土和矿化元素特征分析[J].吉林地质, 2010, 29(1):103~108. http://www.cnki.com.cn/Article/CJFDTOTAL-JLDZ201001026.htmWANG Chao-fan, LÜ Gu-xian, GUO Tao, et al. Analysis on REE and elements related to mineralization of Potouqing fault in Linglong gold deposit[J]. Jilin Geology, 2010, 29(1):103~108. http://www.cnki.com.cn/Article/CJFDTOTAL-JLDZ201001026.htm [13] 李厚民, 沈远超, 毛景文, 等.石英、黄铁矿及其包裹体的稀土元素特征——以胶东焦家式金矿为例[J].岩石学报, 2003, 19(2):267~274. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200302007.htmLI Hou-min, SHEN Yuan-chao, MAO Jing-wen, et al.REE features of quartz and Pyrite and their fluid inclusions: An example of Jiaojia-type gold deposits, northwestern Jiaodong Peninsula[J]. Aeta Perrologiea Sinica, 2003, 19(2):267~274. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200302007.htm [14] 谭凯旋, 刘顺生.微量元素和稀土元素的断裂构造地球化学研究[J].湘潭矿业学院学报, 1993, 18(1):47~53. http://www.cnki.com.cn/Article/CJFDTOTAL-XTKY199301007.htmTAN Kai-xuan, LIU Shun-sheng.Study on fault tectonogeochemistry of trace element and REE[J]. Journal of Xiangtan Mining Institute, 1993, 18(1):47~53. http://www.cnki.com.cn/Article/CJFDTOTAL-XTKY199301007.htm [15] 徐述平, 杨立强, 张蜀冀, 等.胶东招平断裂带金矿成矿指示元素特征及找矿应用[J].黄金科学技术, 2010, 18(5):7~11. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKJ201005003.htmXU Shu-ping, YANG Li-qiang, ZHANG Shu-ji, et al. Metallogenic indication element characteristics and application of gold deposit in Zhaoyuan-Pingdu fault zone[J]. Gold Science and Technology, 2010, 18(5):7~11. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKJ201005003.htm