江西新余良山钼矿氢-氧-硫-铅同位素特征及指示意义

伍俊杰; 陈正乐; 付蕾; 潘家永; 韩凤彬; 沈滔

江西新余良山钼矿氢-氧-硫-铅同位素特征及指示意义

伍俊杰^1,,
陈正乐^{1, 2},
付蕾^{1, 3},
潘家永¹,
韩凤彬²,
沈滔¹

1.
东华理工大学地球科学学院, 南昌 330013
2.
中国地质科学院地质力学研究所, 北京 100081
3.
赣中南地质矿产勘查研究院, 南昌 330013

基金项目:

国家自然基金项目 U1403292

中国地质调查局地质调查项目 121201120936

"十二五"国家科技支撑计划项目 2015BAB05B04

详细信息

作者简介:
伍俊杰(1990-), 男, 江西抚州人, 硕士研究生, 地质学专业。E-mail:mary_wu901230@sina.com

中图分类号: P618.65
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- 被引次数: 0
出版历程
- 收稿日期: 2015-11-02
- 刊出日期: 2016-06-01

H-O-S-Pb ISOTOPIC COMPONENTS OF THE LIANGSHAN MOLYBDENUM DEPOSIT IN XINYU, JIANGXI PROVINCE AND THEIR IMPLICATIONS FOR THE ORE FORMING PROCESS

1.
East China Institute of Technology, Nanchang 330013, China
2.
Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China

摘要

摘要: 在前人研究成果的基础上，对江西新余良山钼矿床的地质特征进行了详细研究，系统测试了矿床中石英脉型钼矿石样品的氢、氧、硫和铅同位素组成，进而探讨钼矿床的成矿流体性质以及成矿物质来源。良山钼矿床δD值变化范围-61‰~ -57.9‰，平均值-59.1‰；δ¹⁸O_V-SMOW值变化于7.1‰~10.5‰，平均值9.2‰，流体的δ¹⁸O_H₂O值变化于-3.32‰~-0.52‰，平均值-1.52‰，表明成矿流体具有岩浆水和大气降水混合流体特征。硫化物的δ³⁴S_V-CDT值为-1.8‰~2.6‰，极差4.4‰，平均值1.12‰，其中黄铁矿δ³⁴S_V-CDT值为-1.8‰~2.6‰，辉钼矿δ³⁴S_V-CDT值为0.8‰~2.3‰，硫同位素表现为较小的正值特征，具有典型的岩浆硫组成特点。良山钼矿石中的矿石铅同位素²⁰⁶Pb/²⁰⁴Pb值为17.555~19.474，²⁰⁷Pb/²⁰⁴Pb值15.486~15.768，²⁰⁸Pb/²⁰⁴Pb值37.942~39.943，μ值9.35~9.7，ω值37.06~38.31，Th/U值3.8~3.96，矿石铅为混合铅，表明成矿物质为混合来源。良山钼矿床应为岩浆热液型-石英脉型钼矿床，是中生代华南板块板内构造演化区域金属成矿作用大爆发的产物。
- 同位素组成 /
- 成矿物质 /
- 成矿流体 /
- 成矿系统 /
- 良山钼矿床
Abstract: On the basis of predecessors' research results, We study the geological characteristics of the Liangshan molybdenum deposit in Jiangxi province and test H-O-S-Pb isotopic components of the molybdenum stone samples in quartz vein systematically, and then discusse the metallogenic fluid properties as well as the source of ore-forming materials of the molybdenum deposit. The δD of the ore-forming fluids are between -61‰~-57.9‰, with the average of -59.1‰; and the δ¹⁸O_V-SMOW of the ore-forming fluid are between 7.1‰~10.5‰, with the average of 9.2‰; and the δ¹⁸O_H₂O of the ore-foring fluids are between -3.32‰~-0.52‰, with the average of -1.52‰, which indicate that the ore-forming fluid has the characteristics of magmatic water and meteoric water mixed fluid. The δ³⁴S_V-CDT of the sulfide mineral are between -1.8‰~2.6‰, with the range of 4.4‰ and the average of 1.12‰, of which the δ³⁴S_V-CDT of the pyrite are between -1.8‰~2.6‰ and the δ³⁴S_V-CDT of the molybdenite are between 0.8‰~2.3‰. The sulfur isotope values are smaller positive which show the characteristics of typical magmatic sulfur. The values of ²⁰⁶Pb/²⁰⁴Pb of the ore samples are between 17.555~19.474, and the values of ²⁰⁷Pb/²⁰⁴Pb are between 15.486~ 15.768, as well as the values of ²⁰⁸Pb/²⁰⁴Pb are between 37.942~39.943, with the μ values of 9.35~9.7 and the ω values of 37.06~38.31, as well as the Th/U values of 3.8~3.96, which indicate the ore are rich in mixed lead, and the ore-forming material sources are mixed. The Liangshan molybdenum ore should belong to the magmatic hydrothermal type and quartz vein type deposit, which is a product of the metal mineralization outbreak during the intraplate tectonic evolution of south China plate in Mesozoic.
- isotope composition /
- metallogenetic materials /
- ore-forming fluid /
- metallogenic system /
- Liangshan molybdenum deposit

HTML全文

图 1 江西新余铁矿田地质图(据文献[14]略改)

Figure 1. Geological map of the Xinyu iron deposit in Jiangxi Province

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图 2 江西新余良山钼矿床地质简图(据文献[12]略改)

Figure 2. Geological map of the Liangshan molybdenum deposit in Xinyu, Jiangxi Province

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图 3 良山钼矿床矿石形态及镜下特征图片

a—良山钼矿野外露头照片；b—含矿石英脉；c—辉钼矿与钾长石化；d—辉钼矿与硅化；e—石英脉型钼矿石；f—黄铁矿化、黄铜矿化及辉钼矿交代残留；g—辉钼矿纤维状结构

Figure 3. Morphological and microscopical characteristics of ores in the Liangshan molybdenum deposit

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图 4 新余良山钼矿δ¹⁸O_H₂O-δD同位素投影图(底图据文献[21])

Figure 4. The projection graph of δ¹⁸O_H₂O vs. δD of the Liangshan molybdenum deposit

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图 5 良山钼矿床H-O同位素组成与天然H-O同位素对比图解(底图据文献[25])

Figure 5. Contrast of H-O isotopic compositions in Liangshan molybdenum deposit and in nature

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图 6 江西新余良山钼矿硫同位素直方图

Figure 6. Frequency histogram of δ³⁴S_V-CDT in ore sulfides from Liangshan molybdenum deposit in Xinyu, Jiangxi

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图 7 新余良山钼矿矿床铅同位素²⁰⁷Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb模式图(底图据文献[23])

A—地幔; B—造山带; C—上地壳; D—下地壳

Figure 7. The mode pattern of ²⁰⁷Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb for the Liangshan molybdenum deposit in Xinyu, Jiangxi Province

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图 8 新余良山钼矿矿石铅同位素构造环境演化图解(A，B，C，D分别为各区域中样品相对集中区)

LC—下地壳; UC—上地壳; OIV—洋岛火山岩; OR—造山带

Figure 8. The lead isotope diagram of tectonic environment evolution in Liangshan molybdenum deposit in Xinyu, Jiangxi Province

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表 1 江西新余良山钼矿矿床石英氢、氧同位素组成

Table 1. Hydrogen and oxygen isotopic compositions of the Liangshan molybdenum deposit in Xinyu, Jiangxi

样品号	矿物	检测结果
样品号	矿物	δD_V-SMOW/‰	δ¹⁸O_V-PDB/‰	δ¹⁸O_V-SMOW/‰	δ¹⁸O_H₂O/‰	T_h/℃
JX1-7	石英	-61.0	-19.8	10.5	-0.79	206.5
JX1-8	石英	-59.6	-21.1	9.2	-0.52	234.2
JX1-9	石英	-58.9	-21.5	8.8	-2.01	214.0
JX1-11	石英	-57.9	-23.0	7.1	-0.92	221.4
JX1-12	石英	-58.2	-20.8	9.5	-3.32	221.4
注：样品测试在核工业北京地质研究院分析测试研究中心完成

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表 2 江西新余良山钼矿床硫同位素组成

Table 2. Sulfur isotopic composition of the Liangshan molybdenum deposit in Xinyu, Jiangxi Province

样品号	矿物	δ³⁴S_V-CDT/‰
JX1-7	黄铁矿	2.6
JX1-7-h	辉钼矿	2.0
JX1-8	辉钼矿	2.3
JX1-9	黄铁矿	1.2
JX1-10	辉钼矿	2.1
JX52-3	黄铁矿	1.9
JX52-4B	黄铁矿	0.8
JX52-4C	黄铁矿	-0.3
JX52-5B	黄铁矿	-1.8
JX52-6A	黄铁矿	1.8
JX52-6B	黄铁矿	-0.3
JX52-6B-h	辉钼矿	0.8
JX53-2A	黄铁矿	1.3
JX53-2C	黄铁矿	1.3
注：样品测试在核工业北京地质研究院分析测试研究中心完成

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表 3 中文江西新余良山钼矿床铅同位素组成标题

Table 3. Lead isotopic composition of the Liangshan molybdenum deposit in Xinyu, Jiangxi Province

样品号	矿物	²⁰⁸Pb/²⁰⁴Pb	²⁰⁷Pb/²⁰⁴Pb	²⁰⁶Pb/²⁰⁴Pb	t/Ma	μ	ω	Th/U	△α	△β	△γ
JX52-3	黄铁矿	38.931	15.630	18.508	133	9.51	38.27	3.89	76.54	19.85	44.79
JX52-4B	黄铁矿	38.672	15.606	18.365	207	9.48	37.78	3.86	73.98	18.61	41.09
JX52-4C	黄铁矿	37.942	15.486	17.555	648	9.35	38.28	3.96	61.97	13.27	41.09
JX52-5B	黄铁矿	38.430	15.580	18.272	243	9.44	37.06	3.80	71.32	17.08	36.14
JX52-6A	黄铁矿	38.722	15.620	18.490	134	9.49	37.42	3.82	75.54	19.20	39.20
JX52-6B	黄铁矿	39.943	15.768	19.474	-399	9.70	38.31	3.82	122.10	28.32	65.98
JX52-6B-h	辉钼矿	38.503	15.574	18.257	246	9.43	37.39	3.84	70.72	16.70	38.26
JX53-2A	黄铁矿	38.200	15.548	17.945	441	9.42	37.66	3.87	67.94	16.01	38.71
JX53-2C	黄铁矿	38.149	15.532	17.913	444.6	9.39	37.47	3.86	66.37	14.99	37.51
注：样品测试在核工业北京地质研究院分析测试研究中心完成；μ=w(²³⁸U)/w(²⁰⁴Pb)，ω=w(²³²Th)/w(²⁰⁴Pb)；计算结果由Geokit软件计算所得；t为硫化物模式年龄

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