白秧坪铅锌多金属矿集区东矿带成矿地球化学作用与成矿年龄

王晓虎; 宋玉财; 张洪瑞; 刘英超; 潘小菲; 郭涛

白秧坪铅锌多金属矿集区东矿带成矿地球化学作用与成矿年龄

1.
中国地质科学院地质力学研究所, 北京 100081
2.
中国地质科学院地质研究所, 北京 100037

基金项目:

国家自然科学基金项目 41302067

国家自然科学基金项目 41472067

国家自然科学基金项目 41403043

中国地质科学院中央级公益性科研院所基本科研业务费项目 YYWF201614

详细信息

作者简介:
王晓虎(1983-), 男, 助理研究员, 博士, 主要从事矿床学与矿田构造等研究工作。E-mail:wangzykc@yeah.net

中图分类号: P618.4
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- 被引次数: 0
出版历程
- 收稿日期: 2015-11-16
- 刊出日期: 2016-06-28

GEOCHEMICAL CHARACTERISTICS AND METALLOGENIC AGE OF THE EAST ORE BELT IN BAIYANGPING POLYMETALLIC ORE CONCENTRATION AREA

1.
Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China
2.
Institute of Geology, Chinese Academy of Geological Sciences, Beijing 100037, China

摘要

摘要: 通过成矿期方解石的C、O、Sr和含硫矿物的S、Pb同位素，成矿期方解石Sm-Nd测年研究，探讨白秧坪矿集区东矿带矿床成因。测试结果表明，白秧坪矿集区东矿带方解石δ¹³C_PDB值变化范围-4.0‰~2.3‰，平均值-0.2‰，δ¹⁸O_PDB值范围-27.2‰~20.4‰，平均值-14.1‰，δ¹⁸O_SMOW值范围2.9‰~24.4‰，平均值16.4‰；方解石Sr同位素值变化范围0.707669~0.710115，平均值0.709320；硫化物δ³⁴S_V-CDT值分布范围-20.2‰~1.3‰，平均值约-8.8‰，天青石δ³⁴S_V-CDT值分布范围为17.1‰~19.4‰，平均值约18.0‰；Pb同位素测试结果中，²⁰⁶Pb/²⁰⁴Pb的变化范围为18.553~18.857，²⁰⁷Pb/²⁰⁴Pb变化范围为15.501~15.826，²⁰⁸Pb/²⁰⁴Pb变化范围为38.54~39.456；成矿阶段方解石Sm-Nd等时线年龄为29.5±1.7 Ma。对测试结果的研究表明，白秧坪矿集区东矿带碳质的来源较为均一，矿石中热液方解石碳质源自地层中碳酸盐岩溶解，成矿流体来自地层水和大气降水，属于盆地卤水流体系统；成矿物质硫来自海水硫酸盐的还原作用，成矿早期以有机质还原硫为主，成矿后期以生物还原硫为主；金属成矿物质来自沉积地层和盆地基底；测定白秧坪矿集区东矿带铅锌成矿年龄为29.5±1.7 Ma，与地质年龄限定的较为吻合。
- 兰坪盆地 /
- 白秧坪矿集区 /
- 东矿带 /
- 铅锌 /
- 地球化学 /
- 成矿年龄
Abstract: By studying the C, O and Sr isotopic characteristics of calcites in ore-forming stage, the S and Pb isotopic characteristics of sulfides, and the Sm-Nd dating of calcite in mineralization period, we discussed the ore genesis of the east belt in Baiyangping ore concentration area. Test results show that the δ¹³C_PDB values of calcite range from -4.0‰ to -2.3‰ with the average of -0.2‰, the δ¹⁸O_PDB values range from -27.2‰ to 20.4 ‰ with the average of -14.1‰, the δ¹⁸O_SMOW values range from 2.9‰ to 24.4‰ with the average of 16.4‰, and the Sr isotopic values of calcite are between 0.707669 and 0.710115 with the average of 0.709320. The δ³⁴S_V-CDT values of sulfides distribute in the range of -20.2 ‰ to 1.3 ‰ with the average of about -8.8‰, and the δ³⁴S_V-CDT values of celestine distribute in the range of 17.1‰ to 19.4‰ with the average of about 18.0‰. The Pb isotope test results yield ²⁰⁶Pb/²⁰⁴Pb values of 18.553~18.857, ²⁰⁷Pb/²⁰⁴Pb values of 15.501~15.826 and ²⁰⁸Pb/²⁰⁴Pb values of 38.54~39.456, and the Sm-Nd isochron age of calcite in mineralization stage is 29.5±1.7 Ma. The results indicate a homogeneous carbon source in the east ore belt, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata. The ore-forming fluids are from formation water and precipitate water, which are belonged to the basin brine fluid system. The sulfur is from organic thermal chemical sulfate reduction in the early mineralization stage and biological sulfate reduction in the late mineralization stage. And the metal mineralization material is from sedimentary strata and basement. The dating results show that the Pb-Zn mineralization of the east ore belt occurred at 29.5±1.7 Ma ago, which is consistent with the constrainted geological age.
- Lanping basin /
- Baiyangping ore concentration area /
- the east ore belt /
- lead-zinc /
- geochemical feature /
- metallogenic age

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图 1 白秧坪矿集区东矿带地质简图(据文献^[9]修编)

Figure 1. The geological sketch map of the east ore belt of Baiyangping ore concentration area

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图 2 白秧坪矿集区东矿带成矿阶段方解石Sm-Nd等时线图

Figure 2. The Sm-Nd isochron diagram of the calcite in mineralization stage in the east ore belt of Baiyangping metallogenic concentration area

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图 3 白秧坪多金属矿集区东矿带方解石及成矿流体氧同位素组成分布图(底图据文献^[28])

Figure 3. δ¹⁸O values of calcite and ore-forming fluid in the east ore belt of Baiyangping polymetallic ore district

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图 4 白秧坪方解石碳同位素组成分布图(底图据文献[32])

Figure 4. δ¹³C values of calcite in Baiyangping Pb-Zn-Cu-Ag polymetallic deposit

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图 5 白秧坪铅锌铜银多金属矿床方解石的C、O同位素图(底图据文献[33])

Figure 5. Diagram of C-O isotope of calcite in Baiyangping Pb-Zn-Cu-Ag polymetallic deposit

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图 6 白秧坪多金属矿集区东矿带硫同位素组成

Figure 6. S isotopic composition of the east ore belt in Baiyangping polymetallic ore district

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图 7 锶同位素演化图(底图据文献[43])

Figure 7. Evolution diagram of strontium isotope

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图 8 白秧坪矿集区东矿带铅同位素Δβ-Δγ成因分类图解(底图据文献[44])

Δβ=1000×β/(β_M-1)，Δγ=1000×γ/(γ_M-1)，β、γ和β_M、γ_M分别为样品和地幔的²⁰⁷Pb/²⁰⁴Pb和²⁰⁸Pb/²⁰⁴Pb

Figure 8. Δβ-Δγ genetic classification diagram of lead isotope of the east ore belt in Baiyangping Pb-Zn-Cu-Ag polymetallic deposits

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图 9 白秧坪东矿带Pb同位素数据与基底和邻区地层全岩的Pb同位素数据对比

Figure 9. Comparison of Pb isotope composition of sulfides from the east belt of Baiyangping ore concentration area and whole-rock Pb isotope composition of strata from basement and adjacent area

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表 1 白秧坪矿集区东矿带方解石C、O、Sr同位素测试结果

Table 1. The C-O-Sr isotope results of calcites from the east ore belt of Baiyangping ore concentration area

序号	样品号	矿段	矿物	δ¹³C_PDB/‰	δ¹⁸O_PDB/‰	δ¹⁸O_SMOW	成矿流体δ¹⁸O_SMOW	⁸⁷Sr/⁸⁶Sr	SE
1	HS016-7	灰山	方解石	1.7	-9.0	21.6	9.2	0.709508	6
2	HS016-8	灰山	方解石	2.3	-10.3	20.3	7.9	0.708280	5
3	HS016-10	灰山	方解石	0.7	-6.3	24.4	12.0	0.709477	4
4	HS016-12	灰山	方解石	1.2	-9.4	21.2	8.8	0.709482	5
5	HS2-7	灰山	方解石	-3.0	-15.0	15.5	3.1	0.709475	5
6	HS2-10	灰山	方解石	-1.3	-23.5	6.7	-5.7	0.709633	5
7	D019-4	黑山	方解石	-4.0	-11.7	18.8	6.4	0.709331	4
8	D019-9	黑山	方解石	0.7	-27.2	2.9	-9.5	0.709093	4
9	HX024-1	河西	天青石					0.710115	3
10	HX024-2	河西	天青石					0.709926	5
11	HX024-3	河西	天青石					0.709896	6
12	HX024-4	河西	天青石					0.707669	7
13	HX024-5	河西	天青石					0.709971	5
14	HX030-4	河西	天青石					0.709981	4
15	HX2-11	河西	天青石					0.709899	3
16	HX2-12	河西	天青石					0.709977	5
17	HX2-14	河西	天青石					0.709746	4
18	YZD040-5	燕子洞	天青石					0.708749	5
19	YZD040-6	燕子洞	天青石					0.708660	4
20	YZD040-10	燕子洞	天青石					0.708675	5
21	YZD2-1	燕子洞	天青石					0.708173	6

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表 2 兰坪盆地白秧坪矿集区东矿带硫化物、硫盐矿物中S、Pb同位素组成

Table 2. S-Pb isotope composition of sulfide and sulphosalts from the east ore belt of Baiyangping ore concentration area

序号	样品号	矿物	矿床/矿段	δ³⁴S_V-CDT/‰	²⁰⁶Pb/²⁰⁴Pb	²⁰⁷Pb/²⁰⁴Pb	²⁰⁸Pb/²⁰⁴Pb	Δβ	Δγ	样品描述
1	HX024-2	方铅矿	河西	-11.2	18.605	15.623	38.812	19.1	36.1	含方铅矿天青石矿石
2	HX030-1	方铅矿	河西	-20.2	18.598	15.601	38.76	17.6	34.7	块状方铅矿
3	HX030-1	方铅矿	河西	-11.0	18.609	15.619	38.809	18.8	36.1	块状方铅矿
4	HX030-10	方铅矿	河西	-19.1	18.584	15.590	38.706	16.8	33.3	明显的方铅矿胶结灰岩角砾
5	HX2-14	方铅矿	河西	-10.6	18.588	15.594	38.707	17.1	33.3	与天青石共生的团块状方铅矿
6	YZD2-1	闪锌矿	燕子洞	-9.5	18.600	15.572	38.727	15.5	33.9	闪锌矿矿石
7	YZD2-2	闪锌矿	燕子洞	-9.2	18.688	15.642	38.918	20.2	39.0	闪锌矿矿石
8	YZD040-2	闪锌矿	燕子洞	-10.5	18.614	15.591	38.753	16.8	34.6	泥灰岩中的闪锌矿
9	YZD040-3	闪锌矿	燕子洞	-10.6	18.661	15.597	38.752	17.1	34.5	灰岩中的闪锌矿
10	YZD040-6	闪锌矿	燕子洞	-10.8	18.553	15.501	38.54	10.7	28.9	含天青石、闪锌矿矿石
11	YZD040-10	闪锌矿	燕子洞	-13.0	18.681	15.642	38.937	20.2	39.5	天青石、闪锌矿脉
12	HS2-4	闪锌矿	灰山	-6.7	18.742	15.696	39.018	23.8	41.6	不含矿方解石脉穿切含团块状闪锌矿的方解石脉
13	HS2-5	闪锌矿	灰山	-7.7	18.684	15.633	38.822	19.6	36.4	无矿方解石脉切穿闪锌矿-方解石细脉
14	HS2-7	闪锌矿	灰山	-6.2	18.703	15.642	38.822	20.1	36.4	同期形成的呈互层出现的闪锌矿脉和石英脉
15	HS2-8	闪锌矿	灰山	-6.4	18.685	15.631	38.844	19.4	37.0	方解石-闪锌矿脉
16	HS2-9	闪锌矿	灰山	-6.4	18.725	15.647	38.813	20.4	36.2	方解石-闪锌矿脉被晚期无矿方解石脉切穿
17	HS2-10	闪锌矿	灰山	-7.1	18.656	15.616	38.806	18.4	36.0	含少量浸染状闪锌矿的方解石网脉
18	D019-4	黝铜矿	黑山	1.3	18.825	15.788	39.331	30.0	50.0	热液胶结角砾状矿石
19	D019-8	黝铜矿	黑山	-2.7	18.857	15.82	39.129	32.2	44.6	铅锌矿石
20	D019-8	闪锌矿	黑山	-2.9	18.716	15.621	38.800	18.6	35.8	铅锌矿石
21	D019-9	黝铜矿	黑山	-4.1	18.856	15.826	39.456	32.6	53.4	含方解石脉铅锌矿石
22	HX024-1	天青石	河西	17.2
23	HX024-2	天青石	河西	17.8
24	HX024-3	天青石	河西	17.2
25	HX024-4	天青石	河西	18.3
26	HX024-5	天青石	河西	17.1
27	HX030-4	天青石	河西	17.9
28	HX02-11	天青石	河西	17.1
29	HX2-12	天青石	河西	17.3
30	HX2-14	天青石	河西	18.1
31	YZD040-5	天青石	燕子洞	18.7
32	YZD040-6	天青石	燕子洞	18.6
33	YZD040-10	天青石	燕子洞	18.7
34	YZD2-1	天青石	燕子洞	19.4

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表 3 白秧坪矿集区东矿带成矿阶段方解石Sm-Nd分析检测结果

Table 3. Sm-Nd analysis results of the calcite in mineralization stage in the east ore belt of Baiyangping metallogenic concentration area

序号	样品号	Sm/10^-6	Nd/10^-6	¹⁴⁷Sm/¹⁴⁴Nd	¹⁴³Nd/¹⁴⁴Nd(1σ误差)
1	HS016-7	3.298	1.004	0.1682	0.512432±6
2	HS016-8	1.645	0.2753	0.1016	0.512417±8
3	HS016-10	2.597	0.6892	0.1624	0.512431±9
4	HS016-12	2.516	0.5894	0.146	0.512426±7
5	HS2-7	1.207	0.3706	0.1827	0.512435±8
6	D019-4	0.1986	0.1513	0.4238	0.512480±9
7	D019-9	0.3314	0.0982	0.1893	0.512436±6
	美国La Jolla Nd同位素标准				0.511864±3 (国际权威值：0.511860±20)

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参考文献(46)

[1]	He Long-qing, Song Yu-cai, Chen Kai-xu, et al. Thrust-controlled, sediment-hosted, Himalayan Zn-Pb-Cu-Ag deposits in the Lanping foreland fold belt, eastern margin of Tibetan Plateau[J]. Ore Geology Reviews, 2009, 36: 106~132. doi: 10.1016/j.oregeorev.2008.11.001
[2]	田洪亮.兰坪白秧坪铜银多金属矿床地质特征[J].云南地质, 1997, 16(1):105~108. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199701008.htm TIAN Hong-liang. Geological features of Baiyangping copper-silver polymetallic deposit, Lanping[J]. Yunnan Geology, 1997, 16(1): 105~108. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199701008.htm
[3]	朱大岗, 孟宪刚, 冯向阳, 等.云南白秧坪多金属成矿区构造特征及其控矿作用[J].地质地球化学, 2002, 30(1):28~33. http://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200201004.htm ZHU Da-gang, MENG Xian-gang, FENG Xiang-yang, et al. Characteristics of tectonic structures at Baiyangping, Yunnan and Their control over the minerogenesis of polymetal deposit in the ming area[J]. Geology-Geochemistry, 2002, 30(1): 28~33. http://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ200201004.htm
[4]	邵兆刚, 孟宪刚, 冯向阳, 等.云南白秧坪矿化集中区成矿构造动力学分析[J].地球学报, 2002, 23(3):201~206. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200203002.htm SHAO Zhao-gang, MENG Xian-gang, FENG Xiang-yang, et al. Analysis on the ore-forming geodynamics of the Baiyangping ore-concentrated field, Yunnan province [J]. Acta Geoscienta Sinica, 2002, 23(3): 201~206. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB200203002.htm
[5]	邵兆刚, 孟宪刚, 冯向阳, 等.云南白秧坪—华昌山矿带构造特征及其控矿作用[J].地质力学学报, 2003, 9(3):246~253. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20030331&flag=1 SHAO Zhao-gang, MENG Xian-gang, FENG Xiang-yang, et al. Tectonic characteristics of the Baiyangping-Huachangshan ore belt, Yunnan Province and its ore-controlling effect[J]. Journal of Geomechanics, 2003, 9(3): 246~253. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20030331&flag=1
[6]	陈开旭, 何龙清, 杨振强, 等.云南兰坪三山—白秧坪铜银多金属成矿富集区的碳氧同位素地球化学[J].华南地质与矿产, 2000, (4):1~8. http://www.cnki.com.cn/Article/CJFDTOTAL-HNKC200004000.htm CHEN Kai-xu, HE Long-qing, YANG Zhen-qiang, et al. Oxygen and carbon isotope geochemistry in Sanshan-Baiyangping copper-silver polymetallogenic enrichment district, Lanping, Yunnan[J]. Geology and Mineral Resources of South China, 2000, (4): 1~8. http://www.cnki.com.cn/Article/CJFDTOTAL-HNKC200004000.htm
[7]	陈开旭, 何龙清, 魏君奇, 等.云南白秧坪矿化集中区矿石矿物特征及银、钴赋存状态的初步研究[J].矿物学报, 2004, 24(1):61~67. http://www.cnki.com.cn/Article/CJFDTOTAL-KWXB200401010.htm CHEN Kai-xu, HE Long-qing, WEI Jun-qi, et al. Preliminary study on the characteristics of ore minerals and the occurrence states of silver and cobalt in the Baiyangping ore-concentrated field, Yunnan Province[J]. Acta Mineraligica Sinica, 2004, 24(1): 61~67. http://www.cnki.com.cn/Article/CJFDTOTAL-KWXB200401010.htm
[8]	陈开旭, 姚书振, 何龙清, 等.云南兰坪白秧坪银多金属矿集区成矿流体研究[J].地质科技情报, 2004, 23(2):45~50. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ200402011.htm CHEN Kai-xu, YAO Shu-zhen, HE Long-qing, et al. Ore-forming fluid in Baiyangping silver-polymetallic mineralization concentration field in Lanping, Yunnan province[J]. Geological Science and Technology Information, 2004, 23(2): 45~50. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ200402011.htm
[9]	陈开旭. 云南兰坪前陆盆地北部铜、银多金属矿集区形成机制[D]. 武汉: 中国地质大学, 2006. http://www.wenkuxiazai.com/doc/eb383227caaedd3382c4d301-3.html CHEN Kai-xu. The forming mechanism of copper-silver polymetallic ore concentration area in the north of Lanping forelanbasin in Yunnan province[D]. Wuhan: China University of Geosciences, 2006. http://www.wenkuxiazai.com/doc/eb383227caaedd3382c4d301-3.html
[10]	何明勤, 刘家军, 李朝阳, 等.兰坪盆地铅锌铜大型矿集区的流体成矿作用机制——以白秧坪铜钴多金属地区为例[M].北京:地质出版社, 2004:1~117. HE Ming-qin, LIU Jia-jun, LI Chao-yang, et al. Fluid mineralozation mechanism of a large copper-lead-zinc ore-concentrated area in Lanping basin-Taking Baiyangping copper-cobalt polymetallic area as the example[M]. Beijing: Geological Publishing House, 2004: 1~117.
[11]	何龙清, 季玮, 陈开旭, 等.滇西兰坪盆地白秧坪地区东矿带推覆构造的控矿作用[J].地质力学学报, 2007, 13(2):110~118. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20070217&flag=1 HE Long-qing, JI Wei, CHEN Kai-xu, et al. Ore-controlling effect of nappe structure in the east ore zone of the Baiyangping area, Lanping basin, Yunnan[J]. Journal of Geomechanics, 2007, 13(2): 110~118. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20070217&flag=1
[12]	余凤鸣, 何龙清, 陈开旭.云南白秧坪东矿区控矿断裂带构造岩的方解石组构[J].中国地质, 2007, 34(6):1130~1140. http://www.cnki.com.cn/Article/CJFDTOTAL-DIZI200706019.htm YU Feng-ming, HE Long-qing, CHEN Kai-xu. Calcite fabric of tectonite in an ore-controlling fault belt in the Baiyangping east ore district, Yunnan[J]. Geology in China, 2007, 34(6): 1130~1140. http://www.cnki.com.cn/Article/CJFDTOTAL-DIZI200706019.htm
[13]	余凤鸣, 何龙清, 陈开旭.云南白秧坪矿区华昌山断裂带构造岩的微观变形特征[J].地球学报, 2011, 32(1):37~45. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201101007.htm YU Feng-ming, HE Long-qing, CHEN Kai-xu. Microdeformation characteristics of the tectonite from the Huachangshan fault zone in the Baiyangping ore district, Yunnan Province[J]. Acta Geoscientica Sinica, 2011, 32(1): 37~45. http://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201101007.htm
[14]	何龙清, 陈开旭, 魏君奇, 等.云南白秧坪地区东矿带矿床地质地球化学特征及成因分析[J].矿床地质, 2005, 24(1):61~70. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ200501008.htm HE Long-qing, CHEN Kai-xu, WEI Jun-qi, et al. Geological and geochemical characteristics and genesis of ore deposits in eastern ore belt of Baiyangping area, Yunnan Province[J]. Mineral Deposits, 2005, 24(1): 61~70. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ200501008.htm
[15]	何明友, 王玉婷, 白宪洲, 等.云南白秧坪矿田成矿流体地球化学研究及其地质意义[J].矿物学报, 2009, (Supp.): 213~214. http://www.cnki.com.cn/Article/CJFDTOTAL-KWXB2009S1108.htm HE Ming-you, WANG Yu-ting, BAI Xian-zhou, et al. The ore-forming fluid geochemistry and its geological significance of Baiyangping orefield, Yunnan province[J]. Acta Mineralogica Sinica, 2009, (Supp.): 213~214. http://www.cnki.com.cn/Article/CJFDTOTAL-KWXB2009S1108.htm
[16]	冯彩霞, 毕献武, 胡瑞忠, 等.兰坪盆地白秧坪Cu-Pb-Zn-Ag多金属矿集区元素共生分异机制及物质来源[J].岩石学报, 2011, 27(9):2609~2624. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201109012.htm FENG Cai-xia, BI Xian-wu, HU Rui-zhong, et al. Study on paragenesis-separation mechanism and source of ore-forming element in the Baiyangping Cu-Pb-Zn-Ag polymetallic ore deposit, Lanping basin, southwestern China[J]. Acta Petrologica Sinica, 2011, 27(9): 2609~2624. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201109012.htm
[17]	邹志超, 胡瑞忠, 毕献武, 等.云南白秧坪银铜多金属矿集区成矿流体的稳定同位素地球化学研究[J].地球化学, 2012, 41(6):515~529. http://www.cnki.com.cn/Article/CJFDTOTAL-DQHX201206001.htm ZOU Zhi-chao, HU Rui-zhong, BI Xian-wu, et al. Study on isotope geochemistry compositions of the Baiyangping silver-copper polymetallic ore deposit area, Yunnan Province[J]. Geochimica, 2012, 41(6): 515~529. http://www.cnki.com.cn/Article/CJFDTOTAL-DQHX201206001.htm
[18]	Feng Cai-xia, Bi Xian-wu, Liu Shen, et al. Fluid inclusion, rare earth element geochemistry, and isotopic characteristics of the eastern ore zone of the Baiyangping polymetallic Ore district, northwestern Yunnan Province, China[J]. Journal of Asian Earth Sciences, 2014, 85: 140~153. doi: 10.1016/j.jseaes.2014.01.019
[19]	何龙清, 陈开旭, 余凤鸣, 等.云南兰坪盆地推覆构造及其控矿作用[J].地质与勘探, 2004, 40(4):7~12. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKT200404001.htm HE Long-qing, CHEN Kai-xu, YU Feng-ming, et al. Mappe tectonics and their ore-controlling of Lanping basin in Yunnan province[J]. Geology and Prospecting, 2004, 40(4): 7~12. http://www.cnki.com.cn/Article/CJFDTOTAL-DZKT200404001.htm
[20]	McCrea J M. On the isotope chemistry of carbonates and a paleotemperature scale[J]. Journal of Chemical Physics, 1950, 18(6): 849~857. doi: 10.1063/1.1747785
[21]	王银喜, 杨杰东, 陶仙聪, 等.化石、矿物和岩石样品的Sm-Nd同位素实验方法研究及其应用[J].南京大学学报:自然科学版, 1988, 24(2):297~308. http://www.cnki.com.cn/Article/CJFDTOTAL-NJDZ198802017.htm WANG Yin-xi, YANG Jie-dong, TAO Xian-cong, et al. A study of the Sm-Nd method for fossil mineral rock and its application[J]. Journal of Nanjing University: Natural Science Edition, 1988, 24(2): 297~308. http://www.cnki.com.cn/Article/CJFDTOTAL-NJDZ198802017.htm
[22]	王银喜, 顾连兴, 张遵忠, 等.博格达裂谷双峰式火山岩地质年代学与Nd-Sr-Pb同位素地球化学特征[J].岩石学报, 2006, 22(5):1215~1224. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200605013.htm WANG Yin-xi, GU Lian-xing, ZHANG Zun-zhong, et al. Geochronology and Nd-Sr-Pb isotopes of the bimodal volcanic rocks of the Bogda rift[J]. Acta Petroologica Sinica, 2006, 22(5): 1215~1224. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200605013.htm
[23]	王银喜, 顾连兴, 张遵忠, 等.东天山晚石炭世大石头群流纹岩Sr-Nd-Pb同位素地球化学研究[J].岩石学报, 2007, 23(7):1749~1755. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200707019.htm WANG Yin-xi, GU Lian-xing, ZHANG Zun-zhong, et al. Sr-Nd-Pb isotope geochemistry of rhyolite of the Late carboniferous Dashitou group in eastern Tianshan[J]. Acta Petroologica Sinica, 2007, 23(7): 1749~1755. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200707019.htm
[24]	叶庆同, 胡云中, 杨岳清.三江地区区域地球化学背景和金银铅锌成矿作用[M].北京:地质出版社, 1992:1~279. YE Qing-tong, HU Yun-zhong, YANG Yue-qing, et al. Regional geochemical background and gold silver and lead-zinc mineralization in the Nujiang-Lancangjiang-Jinshajiang area[M]. Beijing: Geological Publishing House, 1992: 1~279.
[25]	杨伟光. 云南兰坪白秧坪银铜多金属矿集区成矿作用的地质-地球化学条件和成矿机制[D]. 北京: 中国地质大学, 2002. http://d.wanfangdata.com.cn/Thesis_Y669471.aspx YANG Wei-guang. The geological-geochemical cinditions and mineralization mechanism of Baiyangping polymetallic ore concentration area, Lanping basin, Yunnan province[D]. Beijing: China University of Geosciences, 2002. http://d.wanfangdata.com.cn/Thesis_Y669471.aspx
[26]	赵海滨. 滇西兰坪盆地中北部铜多金属矿床成矿特征及地质条件[D]. 北京: 中国地质大学, 2006. http://d.wanfangdata.com.cn/Thesis/Y1052366 ZHAO Hai-bin. Study on the characteristics and metallogenic conditions of copper-polymetallic deposits in middle-northern Lanping basin, western Yunnan[D]. Beijing: China University of Geosciences, 2006. http://d.wanfangdata.com.cn/Thesis/Y1052366
[27]	Changkakoti A, Morton R D, Gray J, et al. Oxygen, hydrogen, and carbon isotopic of the Great Bear Lake silver deposits, Northwest Territories[J]. Canadian Journal Earth Sciences, 1986, 23: 1463~1469. doi: 10.1139/e86-141
[28]	Hoefs. Stable isotope geochemistry[M]. Springer, 1997: 1~208. http://www.oalib.com/references/19258121
[29]	Ohmoto H. Systematics of sulfur and carbon isotopes in hydrothermal ore deposits[J]. Economic Geology, 1972, 67: 551~555. doi: 10.2113/gsecongeo.67.5.551
[30]	陈式房, 刘仪来, 包育秀, 等.德钦—下关铅锌矿带矿床类型、成矿规律研究[J].云南地质, 1991, 10(2):119~144. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199102000.htm CHEN Shi-fang, LIU Yi-lai, BAO Yu-xiu, et al. Research in to Metallogenic Law, Ore Deposit Types of Deqin-Xiaguang Lead-zinc Ore Zone[J]. Yunnan Geology, 1991, 10(2): 119~144. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199102000.htm
[31]	朱创业, 夏文杰, 伊海生, 等.兰坪—思茅中生代盆地性质及构造演化[J].成都理工学院学报, 1997, 24(4):25~32. http://www.cnki.com.cn/Article/CJFDTOTAL-CDLG704.002.htm ZHU Chuang-ye, XIA Wen-jie, YI Hai-sheng, et al. The tectonic nature and evolution of Mesozoic Lanping-Simao basin[J]. Journal of Chengdu University of Technology, 1997, 24(4): 25~32. http://www.cnki.com.cn/Article/CJFDTOTAL-CDLG704.002.htm
[32]	Clark I D, Fritz P. Environmental isotopes in hydrogeology[M]. New York: Lewis Publishers, 1997: 1~328.
[33]	刘家军, 何明勤, 李志明, 等.云南白秧坪银铜多金属矿集区碳氧同位素组成及其意义[J].矿床地质, 2004, 23(1):1~10. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ200401000.htm LIU Jia-jun, HE Ming-qin, LI Zhi-ming, et al. Oxygen and carbon isotope geochemistry of Baiyangping silver-copper polymetallic ore concentration area in Lanping basin of Yunnan province and its significance[J]. Mineral Deposits, 2004, 23(1): 1~10. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ200401000.htm
[34]	韩吟文, 马振东, 张宏飞, 等.地球化学[M].北京:地质出版社, 2003:1~469. HAN Yin-wen, MA Zhen-dong, ZHANG Hong-fei, et al. Geochemistry[M]. Beijing: Geological Publishing House, 2003: 1~469.
[35]	覃功炯, 朱上庆.金顶铅锌矿床成因模式及找矿预测[J].云南地质, 1991, 10(2):145~190, 205. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199102001.htm QIN Gong-jiong, ZHU Shang-qing. Genetic model and prospecting prediction of Jinding lead-zinc ore deposit[J]. Yunnan Geology, 1991, 10(2): 145~190, 205. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199102001.htm
[36]	Ohmoto H, Rye R O. Isotope of sulfur and carbon[C]//Barnes H L. Geochemistry of hydrothermal ore deposits. Wiley-Inter Science, 1979: 509~567. http://www.ugr.es/~agcasco/gaia/conferencias/conferencias_08_09/ohmoto%20.htm
[37]	Orr W L. Rate and mechanism of non-microbial sulfate reduction[J]. Abstracts with Programs Geological Society of America, 1982, 14: 580. http://d.wanfangdata.com.cn/ExternalResource-zgkx-cd200005002%5e9.aspx
[38]	Machel H G, Krouse H R, Sassen R. Products and distinguishing criteria of bacterial and thermochemical sulfate reduction[J]. Applied Geochemistry, 1995, 10: 373~389. doi: 10.1016/0883-2927(95)00008-8
[39]	Ohmoto H, Goldhaber M. Sulfur and carbon isotopes[C]//Barnes L. Geochemistry of hydrothermal ore deposits (3^rd edition). Wiley-Inter Ccience, 1997: 509~567.
[40]	Hecht L, Freiberger R, Gilg H A, et al. Rare earth element and isotope (C, O, Sr) characteristics of hydrothermal carbonates: Genetic implications for dolomite-hosted talc mineralization at Göpfersgrün (Fichtelgebirge, Germany) [J]. Chemical Geology, 1999, 155: 115~130. doi: 10.1016/S0009-2541(98)00144-2
[41]	彭建堂, 胡瑞忠, 邓海琳, 等.湘中锡矿山锑矿床的Sr同位素地球化学[J].地球化学, 2001, 30(3):248~256. http://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200103007.htm PENG Jian-tang, HU Rui-zhong, DENG Hai-lin, et al. Strontium isotope geochemistry of the Xikuangshan antimony deposit, Central Hunan[J]. Geochimica, 2001, 30(3): 248~256. http://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200103007.htm
[42]	Li Wen-bo, Huang Zhi-long, Yin M. Isotope geochemistry of the Huize Zn-Pb ore field, Yunnan Province, Southwestern China: Implication for the sources of ore fluid and metals[J]. Geochemical Journal, 2007, 41: 65~81. doi: 10.2343/geochemj.41.65
[43]	Faure G, Powell J L. Strontium isotope geology[M]. Springer Verlag, 1972: 1~188. http://www.springer.com/us/book/9783642653698
[44]	朱炳泉.地球科学中同位素体系理论和应用——兼论中国大陆壳幔演化[M].北京:科学出版社, 1998:1~330. ZHU Bing-quan. The isotopic system theory and application of earth sciences: On Chinese mainland crust-mantle evolution[M]. Beijing: Science Press, 1998: 1~330.
[45]	云南省地质局. 1 : 20万兰坪幅区域地质调查报告[R]. 昆明: 云南省地质局, 1974. http://www.wenkuxiazai.com/doc/d0907e1ca300a6c30c229ffc.html Yunnan Bureau of Geology and Mineral Resource. Geological map (scale 1 :200000) with geological report of Lanping (block G-47-X Ⅵ)[R]. Kunming: Yunnan Bureau of Geology and Mineral Resource, 1974. http://www.wenkuxiazai.com/doc/d0907e1ca300a6c30c229ffc.html
[46]	牟传龙, 王剑, 余谦, 等.兰坪中新生代沉积盆地演化[J].矿物岩石, 1999, 19(3):30~36. http://www.cnki.com.cn/Article/CJFDTOTAL-KWYS199903006.htm MOU Chuan-long, WANG Jian, YU Jian, et al. The evolution of the sedimentary basin in Lanping area during Mesozoic-Cenozoic[J]. Journal of Mineralogy and Petrology, 1999, 19(3): 30~36. http://www.cnki.com.cn/Article/CJFDTOTAL-KWYS199903006.htm