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激光拉曼光谱在有机包裹体研究中的应用——以苏里格气田西部盒8段油气包裹体为例

董会 王志海 董敏 李宏 魏小燕 梁积伟

董会, 王志海, 董敏, 等, 2017. 激光拉曼光谱在有机包裹体研究中的应用——以苏里格气田西部盒8段油气包裹体为例. 地质力学学报, 23 (4): 594-601.
引用本文: 董会, 王志海, 董敏, 等, 2017. 激光拉曼光谱在有机包裹体研究中的应用——以苏里格气田西部盒8段油气包裹体为例. 地质力学学报, 23 (4): 594-601.
DONG Hui, WANG Zhihai, DONG Min, et al., 2017. APPLICATION OF LASER RAMAN SPECTROSCOPY IN THE STUDY OF ORGANIC INCLUSIONS: A CASE STUDY ON OIL AND GAS INCLUSIONS IN THE 8th MEMBER OF THE SHIHEZI FORMATION IN WESTERN SULIGE GASFIELD. Journal of Geomechanics, 23 (4): 594-601.
Citation: DONG Hui, WANG Zhihai, DONG Min, et al., 2017. APPLICATION OF LASER RAMAN SPECTROSCOPY IN THE STUDY OF ORGANIC INCLUSIONS: A CASE STUDY ON OIL AND GAS INCLUSIONS IN THE 8th MEMBER OF THE SHIHEZI FORMATION IN WESTERN SULIGE GASFIELD. Journal of Geomechanics, 23 (4): 594-601.

激光拉曼光谱在有机包裹体研究中的应用——以苏里格气田西部盒8段油气包裹体为例

基金项目: 

国家重点基础研究发展计划("973"计划)项目 2003CB214602

国家科技重大专项 2008ZX05005-004-09HZ

西北大学大陆动力学国家重点实验开放基金项目 07LCB11

详细信息
    作者简介:

    董会(1981-), 女, 硕士, 工程师, 从事流体包裹体测试分析研究工作.E-mail:donghuidy@163.com

  • 中图分类号: TE135

APPLICATION OF LASER RAMAN SPECTROSCOPY IN THE STUDY OF ORGANIC INCLUSIONS: A CASE STUDY ON OIL AND GAS INCLUSIONS IN THE 8th MEMBER OF THE SHIHEZI FORMATION IN WESTERN SULIGE GASFIELD

  • 摘要: 以苏里格气田西部盒8段储层砂岩油气包裹体为例,应用激光拉曼探针微区原位分析技术,对其赋存于石英颗粒表面愈合裂隙、次生加大边的2期含烃有机包裹体的成分及其相对摩尔百分含量进行测定:早期包裹体主要为含气态烃和含盐水气态烃的气液两相有机包裹体,晚期包裹体为含气态烃气液两相有机包裹体;其气相成分以CO2、CH4和N2等气体为主,溶解有CO、H2S、H2、C2H2、C2H4、C2H6、C4H6等气体;液相成分以H2O和CO2为主,此外还含有极少量的阴离子SO42-和CO32-离子(小于0.03 mol/L)。研究表明:早期有机包裹体含有大量CO2无机气体、H2O和少量低碳烷烃,说明早期有机质成熟度处于未成熟—低成熟阶段,虽有天然气生成,但运移规模有限,形成的有机包裹体极少,反映了天然气进入储层后置换地层水的过程;晚期有机包裹体与之相反,烃类和N2含量均较高,而CO2无机气体和H2O含量均较低,可见晚期有机包裹体代表了油气形成高峰和大规模进入储层成藏期间的流体特征,为有机质的热演化程度,油气生成、运移,划分油气成藏期次提供了科学依据。

     

  • 图  1  不同相态流体包裹体激光拉曼光谱图

    Figure  1.  Laser raman spectroscopy of fluid inclusions in different phases

    图  2  苏53井盒8段早、晚期包裹体气相成分特征对比图

    Figure  2.  Comparison diagrams of composition characteristics of the fluid inclusions in gas phase in early and late stages in the 8th He of Su 53 gas & liquid field

    图  3  苏53井盒8段早、晚期包裹体气、液相成分对比图

    Figure  3.  Comparison diagrams of composition of inclusions in gas-liquid phases in early and late stages in the 8th He of Su 53 gas & liquid field

    表  1  苏里格西部探区盒8段油气包裹体样品地质特征

    Table  1.   Geological characteristics of oil and gas inclusion samples in the 8th member of the Shihezi formation of Western Sulige exploration area

    井号样号层位深度/m气/水层岩性
    苏53S53-2-1盒83340.75石英砂岩
    苏53S53-1盒83339.67石英砂岩
    苏53S53-2-2盒83340.75石英砂岩
    苏65S65-1(1)盒83558.55石英砂岩
    苏65S65-1-1(2)盒83558.55石英砂岩
    苏65S65-1-2盒83558.55含气层石英砂岩
    苏75S75-2盒83342.1石英砂岩
    苏60S60-4盒83672.62含气层岩屑石英砂岩
    苏89S89-2-2盒83581.2含气层岩屑石英砂岩
    苏100S100-3盒83334.93石英砂岩
    下载: 导出CSV

    表  2  苏里格气田西部探区盒8段流体包裹体气相激光拉曼分析结果

    Table  2.   Analysis results of laser raman spectroscopy of fluid inclusions in the 8th member of the Shihezi formation of Western Sulige exploration area

    井号样号包裹体
    期次
    层位宿主
    矿物
    包裹体
    类型
    气相/%(摩尔数的相对百分含量)
    CO2H2SCH4N2H2O2C2H2C2H4C2H6C4H6总和
    苏53S53-2-1晚期盒8石英裂隙气液两相包裹体51.444.21.13.3100.0
    苏53S53-1早期盒8石英裂隙气液两相包裹体91.82.92.82.5100.0
    苏75S75-2早期盒8石英碎屑气液两相包裹体84.713.81.5100.0
    苏65S65-1(1)晚期盒8石英碎屑气液两相包裹体84.615.4100.0
    苏65S65-1-2早期盒8石英裂隙气液两相包裹体60.932.17.0100.0
    苏60S60-4早期盒8石英裂隙纯气相包裹体96.83.2100.0
    苏89S89-2-2早期盒8石英裂隙纯气相包裹体92.65.51.9100.0
    苏100S100-3晚期盒8石英裂隙气液两相包裹体9.151.739.2100.0
    下载: 导出CSV

    表  3  苏里格气田西部探区盒8段流体包裹体液相激光拉曼分析结果

    Table  3.   Analysis results of laser raman spectroscopy of fluid inclusions in liquid phase

    井号样号包裹体
    期次
    层位宿主
    矿物
    包裹体
    类型
    液相/%(摩尔数的相对百分含量)
    CO2H2SCH4COH2OC2H6C4H6总和SO42-CO32-
    苏53S53-2-1晚期盒8石英裂隙气液两相包裹体1.091.67.4100.0
    苏53S53-1早期盒8石英裂隙气液两相包裹体16.482.61.0100.00.01
    苏75S75-2早期盒8石英碎屑气液两相包裹体32.068.0100.00.03
    苏65S65-1(1)晚期盒8石英碎屑气液两相包裹体90.29.8100.0
    苏65S65-1-2晚期盒8石英碎屑气液两相包裹体18.974.46.7100.0
    苏53S53-2-2早期盒8石英裂隙纯液相包裹体63.70.435.9100.00.03
    苏65S65-1-1(2)早期盒8石英裂隙纯液相包裹体34.066.0100.0
    苏100S100-3晚期盒8石英裂隙气液两相包裹体4.82.889.33.1100.0
    下载: 导出CSV
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  • 收稿日期:  2017-02-01
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