THE CHARACTERISTICS OF SHALE RESERVOIR FROM QIONGZHUSI FORMATION IN LOWER CAMBRIAN IN QUJING AREA, EASTERN YUNNAN PROVINCE, CHINA:A CASE STUDY OF WELL QUYE NO.1
-
摘要: 下寒武统筇竹寺组页岩是南方页岩气勘查开发重点关注的层位之一,但滇东地区下寒武统筇竹寺组黑色页岩储层研究程度较低。样品采自2014年新钻的曲页1井,对下寒武统筇竹寺组黑色泥页岩进行全岩和粘土矿物X衍射分析、TOC、岩石物性、比表面积等测试和扫描电镜实验,综合分析了滇东曲靖地区筇竹寺组泥页岩储层特征及孔隙类型。结果表明:滇东曲靖地区下寒武统筇竹寺组泥页岩矿物组成主要是石英(44.75%)、粘土矿物(25.47%)、长石(16.44%);发育粒间孔、粒内孔和有机孔3种类型孔隙;有机质孔隙发育,以中孔为主,具有一定的页岩气勘探开发潜力;页岩储层自上而下孔隙体积有逐渐变小的趋势,但在井深400 m~500 m发育高孔隙体积;泥页岩储集性能的重要指标—孔隙度主要受有机质含量及发育程度的制约。Abstract: Shale from Qiongzhusi formation in Lower Cambrian is one of the most important focuses in shale gas exploration and development in South China; however, the black shale reservoir from Qiongzhusi formation in Lower Cambrian in eastern Yunnan province stays in a low level of study. Take Well Quye No.1 drilled in 2014 as an example, on the black shales from Qiongzhusi formation in Lower Cambrian, X-ray diffraction analysis of the whole rock and clay minerals are made; tests and SEM experiments like TOC, physical property and specific surface area are conducted; the characteristics and types of shale reservoir are analyzed comprehensively. The results show that shales are mainly composed of quartz (44.75%), clay minerals(25.47%)and feldspar (16.44%), consisting of three major pore types, which are intergranular pore, intragranular pore and organic-matter pore. It is worth mentioning that organic-matter pores are abundant and of great importance, in which mesopores are the main force with a certain potential of shale gas exploration and development. The volumes of pores decrease with the depth, and with increasing TOC, micropore volumes relatively increase. The porosity is mainly restricted by the organic-matter content and the development degree.
-
Key words:
- pore type /
- pore volume /
- characteristics of reservoir /
- shale /
- Qiongzhusi formation /
- Well Quye NO.1
-
表 1 曲页1井下寒武统筇竹寺组泥页岩孔隙度和渗透率
Table 1. Porosity vs. permeability of shales in Qiongzhusi formation in lower Cambrian, Well Quye NO. 1
样品
编号埋深
/m孔隙度
/%渗透率
/×10-3μm2QY1-Y57 276.03 1.78 0.0193 QY1-Y56 281.26 1.56 0.0184 QY1-J4 295.03 2.18 0.0136 QY1-J5 301.94 3.01 0.0275 QY1-Y52 302.95 1.94 0.0196 QY1-Y50 313.75 1.35 0.0476 QY1-Y48 324.29 1.73 0.0149 QY1-J9 326.42 2.45 0.0361 QY1-Y47 328.54 1.69 0.0190 QY1-Y46 333.39 1.14 0.0188 QY1-J13 362.48 2.57 0.0275 QY1-Y41 371.07 1.64 0.0170 QY1-Y40 378.8 2.24 0.0153 QY1-J16 388.19 2.00 0.0116 QY1-J18 402.37 1.18 0.0030 QY1-J19 415.83 0.77 0.0076 QY1-J21 430.6 1.82 0.0110 QY1-J23 442.31 0.86 0.0103 QY1-Y33 442.75 1.94 0.0429 QY1-J25 451.23 1.18 0.0121 QY1-J27 457.06 2.10 0.0088 QY1-Y32 457.66 2.34 0.0399 QY1-J29 463.02 1.59 0.0067 QY1-J31 469.14 1.61 0.0117 QY1-Y30 471.00 1.72 0.0308 QY1-J32 474.12 1.72 0.0078 QY1-Y28 484.47 2.17 0.0256 QY1-J34 484.64 1.81 0.0077 QY1-Y27 492.56 0.91 0.0211 QY1-J36 496.78 1.43 0.0113 QY1-Y26 498.44 0.38 0.0179 QY1-Y25 501.06 0.48 0.0279 QY1-J38 513.22 1.07 0.0103 QY1-Y22 523.81 1.88 0.0255 QY1-Y20 535.75 0.81 0.0276 QY1-J40 535.91 1.89 0.0073 QY1-Y18 547.95 0.26 0.0104 QY1-Y17 552.47 1.47 0.0150 QY1-Y16 556.93 0.37 0.0183 QY1-Y14 567.17 1.65 0.0162 QY1-Y13 572.19 1.15 0.0095 表 2 曲页1井下寒武统筇竹寺组泥页岩比表面积测试结果
Table 2. Test results of specific surface area of shales in Qiongzhusi formation in lower Cambrian, Well Quye NO. 1
样品编号 QY1-J1 QY1-J5 QY1-J9 QY1-J11 QY1-J13 QY1-J15 QY1-J19 QY1-J21 QY1-J23 QY1-J25 QY1-J27 QY1-J32 QY1-J36 QY1-J38 QY1-J40 井深/m 245.75 301.94 326.42 338.15 362.48 382.89 415.83 430.6 442.31 451.23 457.06 474.12 496.78 513.22 535.91 表面积/(m2/g) 5.3130 3.9960 4.0330 3.2980 2.0870 2.8000 10.5310 6.1420 1.8000 4.3920 4.2500 4.7990 8.2760 1.9500 2.6860 孔隙体积/(ml/g) 0.0103 0.0076 0.0074 0.0068 0.0050 0.0060 0.0147 0.0116 0.0030 0.0072 0.0096 0.0081 0.0118 0.0042 0.0054 平均孔径/nm 3.8690 3.7985 3.6923 4.1234 4.8119 4.2959 2.7823 3.7632 3.3439 3.2928 4.5177 3.3714 2.8579 4.2600 4.0343 -
[1] 李新民. 我国首个超千亿立方米页岩气田诞生[OL]. http://www.mlr.gov.cn/xwdt/mtsy/xinhuanet/201407/t20140722_1324552.htm.LI Xinmin. The birth of China's first billion cubic meters of shale gas field[OL]. http://www.mlr.gov.cn/xwdt/jrxw/201407/t20140722_1324457.htm.2014, 7.22. (in Chinese) [2] 郭旭升.南方海相页岩气"二元富集"规律-四川盆地及周缘龙马溪组页岩气勘探实践认识[J].地质学报, 2014, 88(7):1209~1218. https://mall.cnki.net/qikan-DZXE201407001.htmlGUO Xusheng. Rules of two~factor enrichiment for marine shale gas in Sourthern China-Understanding from the Longmaxi formation shale gas in Sichuan basin and its surroungding area[J]. Geological Journal, 2014, 88(7):1209~1218. (in Chinese with English abstract) https://mall.cnki.net/qikan-DZXE201407001.html [3] 郭彤楼, 张汉荣.四川盆地焦石坝页岩气田形成与富集高产模式[J].石油勘探与开发, 2014, 41(1):28~36. doi: 10.11698/PED.2014.01.03GUO Tonglou, ZHANG Hanrong. Formation and enrichment mode of Jiaoshiba shale gas field, Sichuan basin[J]. Petroleum Exploration and Development, 2014, 41(1):28~36. (in Chinese with English abstract) doi: 10.11698/PED.2014.01.03 [4] 王玉芳, 翟刚毅, 王劲铸, 等.四川盆地及周缘龙马溪组页岩产气效果影响因素[J].地质力学学报, 2017, 23(4):540~547. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20170405&flag=1WANG Yufang, ZHAI Gangyi, WANG Jinzhu, et al. Factors influencing gas production effectiveness of Longmaxi formation shale in Sichun basin and adjacent areas[J]. Journal of Geomechanics, 2017, 23(4):540~547. (in Chinese with English abstract) http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20170405&flag=1 [5] 程克明, 王世谦, 董大忠, 等.上扬子区下寒武统筇竹寺组页岩气成藏条件[J]..天然气工业, 2009, 29(5):40~44. http://www.oalib.com/paper/4982341CHENG Keming, WANG Shiqian, DONG Dazhong, et al. Accumulation conditions of shale gas reservoirs in the lower Cambrian Qiongzhusi formation, the upper Yangtze region[J]. Natural Gas Industry, 2009, 29(5):40~44. (in Chinese with English abstract) http://www.oalib.com/paper/4982341 [6] 张聪, 包书景, 石砥石, 等.云南曲靖地区下寒武统筇竹寺组页岩气成藏地质条件及有利区预测[J].海相油气地质, 2017, 22(1):69~74. http://www.oalib.com/paper/4982341ZHANG Cong, BAO Shujing, SHI Dishi, et al. Geological conditions for shale gas accumulation and favorable area prediction in Qujing of Eastern Yunnan[J]. Marine Origin Petroleum Geology, 2017, 22(1):69~74. (in Chinese with English abstract) http://www.oalib.com/paper/4982341 [7] 王丽波, 久凯, 曾维特, 等.上扬子黔北地区下寒武统海相黑色泥页岩特征及页岩气远景区评价[J].岩石学报, 2013, 29(9):3263~3278. http://d.wanfangdata.com.cn/Periodical/ysxb98201309024WANG Libo, JIU kai, ZENG Weiye, et al. Characteristics of lower Cambrian marine black shales and evaluation of shale gas prospective area in Qianbei area, upper Yangtze region[J]. Acta Petrologica Sinica, 2013, 29(9):3263~3278. (in Chinese with English abstract) http://d.wanfangdata.com.cn/Periodical/ysxb98201309024 [8] 周新桂, 刘和甫, 王宗秀, 等.我国叠合盆地油气调查战略思考[J].地质力学学报, 2011, 17(2):111~120. http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20110201&flag=1ZHOU Xingui, LIU Hepu, WANG Zongxiu, et al. Thoughts of strategic Hydrocabron survey on superimposed basins in China[J]. Journal of Geomechanics, 2011, 17(2):111~120. (in Chinese with English abstract) http://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?file_no=20110201&flag=1 [9] 杨勤生.滇东下古生界页岩气成藏层位及远景[J].云南地质, 2010, 29(1):1~6. http://www.cqvip.com/qk/95791X/201001/33201747.htmlYANG Qinsheng. The horizon & potentiality of lower Palaeozoic shale gas deposit in East Yunnan[J]. Yunnan Geology, 2010, 29(1):1~6. (in Chinese with English abstract) http://www.cqvip.com/qk/95791X/201001/33201747.html [10] 梁兴, 叶熙, 张介辉, 等.滇黔北下古生界海相页岩气藏赋存条件评价[J].海相油气地质, 2011, 16(4):11~21. http://www.cnki.com.cn/Article/CJFDTotal-HXYQ201104004.htmLIANG Xing, YE Xi, ZHANG Jiehui, et al. Evaluation of preservation conditions of lower Paleozoic marine shale gas reservoirs in the Northern part of Dianqianbei depression[J]. Marine Origin Petroleum Geology, 2011, 16(4):11~21.(in Chinese with English abstract) http://www.cnki.com.cn/Article/CJFDTotal-HXYQ201104004.htm [11] 梁兴, 叶熙, 张介辉, 等.滇黔北坳陷威信凹陷页岩气成藏条件分析与有利区优选[J].石油勘探与开发, 2011, 38(6):641~6519. http://www.wenkuxiazai.com/doc/c2c0399ddd88d0d233d46a31-2.htmlLIANG Xing, YE Xi, ZHANG Jiehui, et al. Reservoir forming conditions and favorable exploration zones of shale gas in the Weixin sag, Dianqianbei depression[J]. Petroleum Exploration and Development, 2011, 38(6):693~699. (in Chinese with English abstract) http://www.wenkuxiazai.com/doc/c2c0399ddd88d0d233d46a31-2.html [12] 云南省地质矿产局.云南省岩石地层[M].北京:中国地质大学出版社, 1996. 21~45.Bureau of Geology and Mineral Resources of Yunnan Province. Rock Strata in Yunnan Province[M]. Beijing:China University of Geosciences Press, 1996, 21~45. (in Chinese) [13] 云南省地质矿产局.云南省区域地质志[M].北京:地质出版社, 1990. 1~728.Bureau of Geology and Mineral Resources of Yunnan Province. Regional Geology of Yunnan Province[M]. Beijing:Geological Publishing House, 1990. 1~728. (in Chinese) [14] 云南省地质矿产局.云南省岩相古地理图集[M].昆明:云南科技出版社, 1995. 53~60.Bureau of Geology and Mineral Resources of Yunnan Province. Atlas of the Palaeo Geography of Yunnan Province[M]. Kunming:Yunnan Science and Technology Press, 1995. 53~60. (in Chinese) [15] Rouquerol J, Avnir D, Fairbridge C W, et al. Recommendations for the characterization of porous solids[J]. Pure Applied Chemistry, 1994, 66(8):1739~1758. http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.460.3717 [16] Ross D J K, Bustin R M. The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs[J]. Marine and Petroleum Geology, 2009, 26(6):916~927. doi: 10.1016/j.marpetgeo.2008.06.004 [17] 蒲泊伶, 董大忠, 耳闯, 等.川南地区龙马溪组页岩有利储层发育特征及其影响因素[J].天然气工业, 2013, 33(12):41~47. http://www.doc88.com/p-4562199214457.htmlPU Boling, DONG Dazhong, ER Chuang, et al. Favorable reservoir characteristics of the Longmaxi shale in the southern Sichuan basin and their influencing factors[J]. Natural Gas Industry, 2013, 33(12):41~47. (in Chinese with English abstract) http://www.doc88.com/p-4562199214457.html [18] 杨峰, 宁正福, 胡昌蓬, 等.页岩储层微观孔隙结构特征[J].石油学报, 2013, 34(2):301~311. doi: 10.7623/syxb201302012YANG Feng, NING Zhengfu, HU Changpeng, et al. Characterization of microscopic pore structures in shale reservoirs[J]. Acta Petrolei Sinica, 2013, 34(2):301~311. (in Chinese with English abstract) doi: 10.7623/syxb201302012 [19] 于炳松.页岩气储层的特殊性及其评价思路和内容[J].地学前缘, 2012, 19(3):252~258. http://d.wanfangdata.com.cn/Periodical/dxqy201203027YU Bingsong. Particularity of shale gas reservoir and its evaluation[J]. Earth Science Frontiers, 2012, 19(3):252~258. (in Chinese with English abstract) http://d.wanfangdata.com.cn/Periodical/dxqy201203027 [20] 于炳松.页岩气储层孔隙分类与表征[J].地学前缘, 2013, 20(4):211~220. https://mall.cnki.net/qikan-CXYY201715138.htmlYU Bingsong. Classification and characterization of gas shale pore system[J]. Earth Science Frontiers, 2013, 20(4):211~220. (in Chinese with English abstract) https://mall.cnki.net/qikan-CXYY201715138.html