Element association anomaly of tectonites and prediction of concealed deposit in the Xiaozhuqing exploration area on the periphery of Huize lead-zinc mine area, northeastern Yunnan Province
-
摘要: 云南会泽超大型富锗铅锌矿位于扬子地块西南缘、川滇黔铅锌成矿区小江深断裂东侧,受北东向断褶构造控制。尽管会泽铅锌矿研究程度高,但作为矿区外围找矿重点区域的小竹箐勘查区地质研究程度较低。基于构造岩中金属元素组合晕(MEAHFZ)找矿方法,通过地质测量和构造解析,认为该勘查区具有良好的成矿地质条件,其构造样式为银厂坡左行斜冲走滑断层及其上盘的倒转倾伏背斜组成的断褶构造,与矿山厂、麒麟厂矿床控矿构造样式基本一致。结合已有研究成果,厘定印支期以来该勘查区构造体系成生发展为北东构造带—晚南北构造带—东西构造带。在此基础上,基于地表 1:10000构造地球化学、蚀变岩相精细填图及重力剖面勘查,绘制了铅-锌-镉元素组合和铅、锌单元素异常综合图,结合该区的重力异常,发现其综合异常沿银厂坡断裂上盘上震旦统灯影组、下石炭统摆佐组中的北北东—北东向压扭性层间断裂带分布,进而圈定了Ⅰ、Ⅱ和Ⅲ号重点找矿靶区。该成果不仅为该勘查区工程验证指明了方向,而且对同类矿床深部和外围找矿预测具有重要的指导意义。Abstract: The Huize super-large Ge-rich Pb-Zn deposit in Yunnan is located on the southwestern margin of the Yangtze block and east of the Xiaojiang deep fault in Sichuan-Yunnan-Guizhou lead-zinc metallogenic areas, and it is controlled by the NE-trending thrust-fold structures. Although the Huize Pb-Zn deposit has a high research level, the geological research level of the Xiaozhuqing exploration area, which is a key prospecting area on the periphery of the mining area, is relatively low. According to the prospecting method of Metal-element association halos within mineralization-related fault zones(MEAHFZ), through geological survey and structural analysis, it is considered that the Xiaozhuqing exploration area has good metallogenic geological conditions, and its tectonic style is the fault-fold structures composed of the Yinchangpo sinistral oblique strike-slip fault and its hanging wall inverted and tilted anticline, which is basically consistent with the ore-controlling structural style of the Kuangshanchang deposit and Qilinchang deposit. Combined with previous research results, it is determined that the structural system in the exploration area has developed from the NE structural zone to the late SN structural zone to the EW structural zone since the Indosinian period. On this basis, based on the 1:10000 tectono-geochemistry, altered lithofacies mapping and gravity profile survey, a comprehensive map of Pb-Zn-Cd element combination anomaly and Pb, Zn single element anomaly is drawn. Combined with the gravity anomaly in this area, it is found that the comprehensive anomalies distribute along the NE-directed compressive and torsional interlayer fault zone in the Upper Sinian Dengying Formation and Lower Carboniferous Baizuo Formation of the hanging wall of Yinchangpo fault, and the key prospecting target areas I, Ⅱ and Ⅲ are delineated. This achievement not only indicates the direction for the exploration and verification of the exploration area, but also has important guiding significance for the prospecting prediction of similar deep and peripheral deposits.
-
图 1 会泽铅锌矿区地质简图
a—中国华南构造简图(据Zhang et al., 2015修改);b—川滇黔铅锌成矿区主要断裂及矿床分布图(据柳贺昌和林文达,1999修改);c—会泽铅锌矿区地质简图(据韩润生等,2012修改)
Figure 1. Geological sketch map of the Huize Pb-Zn mine area
图 2 会泽铅锌矿区冲断褶皱构造与矿床分布剖面图(据韩润生等,2012修改)
Figure 2. Profile showing the thrust-fold structures and deposits in the Huize Pb-Zn mine area(modified after Han et al., 2012)
图 9 小竹箐勘查区印支期以来构造变形及其演化图解(据韩润生等,2014修改)
Figure 9. Diagram showing the tectonic deformation and evolution since the Indosinian period in the Xiaozhuqing exploration area (modified after Han et al., 2014)
表 1 不同方向断裂构造岩中铅锌含量表
Table 1. Contents of lead and zinc in fracture tectonites of different directions
断裂类型 样品数量/件 铅+锌/×10-6 均值/×10-6 北东向断裂 40 17.40~1367.97 140.40 北西向断裂 27 16.63~345.42 71.72 东西向断裂 6 21.90~510.32 147.86 南北向断裂 9 21.83~179.83 80.65 银厂坡断裂 31 18.24~423.86 96.56 总体 113 16.63~1367.97 107.60 表 2 小竹箐勘查区断裂构造岩主因子元素组合
Table 2. Element association of principal factors in the fracture tectonites in the Xiaozhuqing Pb-Zn exploration area
因子 元素组合 F1 Al、Fe、Ti、Ba、Cu、Ni、V、Be、Sc、Co、Ga、Ge、Y、Zr、Nb、In、Hf、Ta、LREE、HREE; F2 Mg、Mn、P、Cu; F3 Al、Ca(-)、K、Sr(-)、Li、Be、Rb、Sn、Cs、W、Tl、Bi、Th; F4 Zn、Cd、Pb; F5 Cu、Cr、V; -
CHEN S J, 1986. Research on the genesis of lead-zinc ore-deposits in western Guizhou and northeastern Yunnan[J]. Geology of Guizhou, (3):211-222. (in Chinese with English abstract) http://en.cnki.com.cn/Article_en/CJFDTOTAL-GZDZ198603000.htm CHENG C, HAN R S, WANG L, et al., 2019. The generation, development and ore-controlling of structures of the Fulaichang lead-zinc deposit, northeastern Guizhou[J]. Journal of Geomechanics, 25(1):90-104. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzlxxb201901010 DENG H L, LI C Y, TU G Z, et al., 2000. Strontium isotope geochemistry of the Lemachang independent silver ore deposit, northeastern Yunnan, China[J]. Science in China Series D:Earth Sciences, 43(4):337. doi: 10.1007/BF02959444 HAN K, LUO J H, WANG Z Q, et al., 2012. Feature of ore-bearing breccias of lead-zinc deposits in Sichuan-Yunnan-Guizhou border area and its tectonic significance[J]. Mineral Deposits, 31(3):629-641. (in Chinese with English abstract) http://www.sciencedirect.com/science/article/pii/S138589471200798X HAN R S, 2005. Orefield/deposit tectono-geochemical method for the localization and prognosis of concealed orebodies[J]. Geological Bulletin of China, 24(10-11):978-984. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgqydz200510018 HAN R S, CHEN J, HUANG Z L, et al., 2006. Dynamics of tectonic Ore-forming processes and Localization-prognosis of concealed orebodies:As exemplified by the Huize Super-large Zn-Pb-(Ag-Ge) district, Yunnan[M]. Beijing:Science Press:1-200. (in Chinese) HAN R S, CHEN J, LI Y, et al., 2001. Discovery of concealed No. 8 orebody in Qilinchang Lead-Zinc deposit in Huize mine, Yunnan[J]. Geology-Geochemistry, 29(3):191-195. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzdqhx200103034 HAN R S, CHEN J, Wang F, et al., 2015. Analysis of metal-element association halos within fault zones for the exploration of concealed ore-bodies-A case study of the Qilinchang Zn-Pb-(Ag-Ge) deposit in the Huize mine district, northeastern Yunnan, China[J]. Journal of Geochemical Exploration, 159:62-78. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=3c3a61c568a9fc77480c490cb2b630d6 HAN R S, HU Y Z, LUO D F, et al., 2011. Discussion on the metallogenic structure background of the germanium-rich lead-zinc deposit in northeast Yunnan[J]. Acta Mineralogica Sinica, 31(S1):200-201. (in Chinese with English abstract) HAN R S, HU Y Z, WANG X K, et al., 2012. Mineralization model of rich Ge-Ag bearing Zn-Pb polymetallic deposit concentrated district in northeastern Yunnan, China[J]. Acta Geologica Sinica, 86(2):280-294. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201202007 HAN R S, WANG F, HU Y Z, et al., 2014. Metallogenic tectonic dynamics and chronology constrains on the Huize-type (HZT) germanium-rich silver-zinc-lead deposits[J]. Geotectonica et Metallogenia, 38(4):758-771. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ddgzyckx201404003 HAN R S, WANG F, ZHAO G S, et al., 2010. The new progress of deep prospecting for Maoping zinc-lead deposit at Zhaotong, northeastern Yunnan[J]. Earth Science Frontiers, 17(3):275. (in Chinese with English abstract) HU R Z, CHEN T W, XU D R, et al., 2017a. Reviews and new metallogenic models of mineral deposits in South China:an introduction[J]. Journal of Asian Earth Sciences, 137:1-8. http://www.sciencedirect.com/science/article/pii/S1367912017300895 HU R Z, FU S, HUANG Y, et al., 2017b. The giant South China Mesozoic low-temperature metallogenic domain:reviews and a new geodynamic model[J]. Journal of Asian Earth Sciences, 137:9-34. http://www.sciencedirect.com/science/article/pii/S1367912016303170 JIN Z G, 2006. Research on the ore-controlling factors, metallogenic regularity and prediction of lead-zinc ore district in Northwest, Guizhou[D]. Changsha: Central South University: 16-17. (in Chinese with English abstract) https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CDFD&dbname=CDFD9908&filename=2006173426.nh&v=MDA0ODcvSGRYT3FaRWJQSVI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUjdxZllPZG5GeTdrV3I3QVYxMjdHTEs= LEACH D L, BRADLEY D C, HUSTON D, et al., 2010. Sediment-hosted lead-zinc deposits in earth history[J]. Economic Geology, 105(3):593-625. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=4a7ea38b531377f82b99b0d797e1e257 LI C Y, 1999. Some geological characteristics of concentrated distribution area of epithermal deposits in China[J]. Earth Science Frontiers, 6(1):163-170. (in Chinese with English abstract) http://www.researchgate.net/publication/306946628_Some_geological_characteristics_of_concentrated_distribution_area_of_epithermal_deposits_in_China LIAO W, 1984. A discussion on the S and Pb isotopic composition characteristics and metallogenic model of the Pb-Zn ore zones in eastern Yunnan and western Guizhou[J]. Geology and Prospecting, (1):2-6. (in Chinese with English abstract) LIN F C, 1994. Some new opinions on the genesis on the Daliangzi lead-zinc deposit, Huidong county, Sichuan province[J]. Mineral Deposits, 13(2):126-136. (in Chinese with English abstract) http://en.cnki.com.cn/Article_en/CJFDTotal-KCDZ402.003.htm LIU H C, 1995. Structural ore-controlling of the Yunnan-Sichuan-Guizhou Pb-Zn mineralized areas[J]. Yunnan Geology, 14(3):173-189. (in Chinese with English abstract) LIU H C, LIN W D, 1999. Regularity research of Ag, Z, Pb ore deposits North-East Yunnan province[M]. Kunming:Yunnan University Press:47-56, 302-426. (in Chinese) LIU W Z, XU X H, 1996. On the relationship between the deposits and tectonics of the Sichuan-Yunnan-Guizhou Pb-Zn mineralized belt[J]. Journal of Chengdu Institute of Technology, 23(1):71-77. (in Chinese with English abstract) http://www.researchgate.net/publication/294098895_On_the_relationship_between_the_deposits_and_tectonics_of_the_Sichuan-Yunnan-Guizhou_Pb-Zn_mineralized_belt SHEN B, 2004. The metallogenetic characteristics of stratabound Pb-Zn deposit in Chuan-Dian-Qian[J]. Yunnan Geology, 23(2):207-211. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yndz200402008 TU G C, 1998. The low temperature geochemistry[M]. Beijing:Science Press. (in Chinese) WANG J Z, Li C Y, Li Z Q, et al., 2002. The comparison of Mississippi valley-type lead-zinc deposits in Southwest of China and in Mid-Continent of United States[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 21(2):127-132. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kwysdqhxtb200202011 WANG M Z, HAN R S, ZHOU W, et al., 2019. Ore-forming structure analysis of the Liangyan lead-zinc mining area in northwestern Guizhou deposit concentration district, China[J]. Journal of Geomechanics, 25(2):187-197. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzlxxb201902005 WU Y, 2013. The age and ore-forming process of MVT deposits in the boundary area of Sichuan-Yunnan-Guizhou provinces, Southwest China[D]. Beijing: China University of Geosciences (Beijing). (in Chinese with English abstract) https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CDFD&dbname=CDFD1214&filename=1013261806.nh&v=MDg1MDU3cWZZT2RuRnk3a1c3ek1WRjI2SGJHK0g5bk1xWkViUElSOGVYMUx1eFlTN0RoMVQzcVRyV00xRnJDVVI= ZHANG C Q, MAO J W, Wu S P, et al., 2005. Distribution, characteristics and genesis of Mississippi Valley-Type lead-zinc deposits in Sichuan-Yunnan-Guizhou area[J]. Mineral Deposits, 24(3):336-348. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcdz200503013 ZHANG C Q, WU Y, HOU L, et al., 2015. Geodynamic setting of mineralization of Mississippi Valley-type deposits in world-class Sichuan-Yunnan-Guizhou Zn-Pb triangle, Southwest China:Implications from age-dating studies in the past decade and the Sm-Nd age of Jinshachang deposit[J]. Journal of Asian Earth Sciences, 103:103-114. http://www.sciencedirect.com/science/article/pii/S1367912014003563 ZHANG W J, 1984. A preliminary discussion on the sedimentary origin and metallogenic rule of Pb-Zn deposits in northeastern Yunnan[J]. Geology and Prospecting, (7):11-16. (in Chinese with English abstract) ZHANG Z B, LI C Y, TU G C, et al., 2006. Geotectonic evolution background and ore-forming process of Pb-Zn deposits in Chuan-Dian-Qian area of Southwest China[J]. Geotectonica et Metallogenia, 30(3):343-354. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ddgzyckx200603010 ZHOU C X, WEI C S, GUO J Y, et al., 2001. The source of metals in the Qilinchang Zn-Pb deposit, northeastern Yunnan, China:Pb-Sr isotope constraints[J]. Economic Geology, 96(3):583-598. http://pubs.geoscienceworld.org/segweb/economicgeology/article-pdf/96/3/583/3495109/p0583-p0598.pdf ZHOU Y M, 2003. Geological characteristics of Thelehong lead-zinc deposit in northeastern Yunnan and its Orr-search prospects[J]. Geology-Geochemistry, 31(4):16-21. (in Chinese with English abstract) http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzdqhx200304003 陈士杰, 1986.黔西滇东北铅锌矿成因探讨[J].贵州地质, (3):211-222. http://www.cnki.com.cn/article/cjfd1986-gzdz198603000.htm 成晨, 韩润生, 王雷, 等, 2019.黔西北福来厂铅锌矿床构造成生发展及其控矿作用[J].地质力学学报, 25(1):90-104. https://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?flag=1&file_no=20190109&journal_id=dzlxxb 邓海琳, 李朝阳, 涂光炽, 等, 1999.滇东北乐马厂独立银矿床Sr同位素地球化学[J].中国科学(D辑), 29(6):496-503. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd199906003 韩奎, 罗金海, 王宗起, 等, 2012.川滇黔交界地区铅锌矿床含矿角砾岩特征及其构造意义[J].矿床地质, 31(3):629-641. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcdz201203019 韩润生, 陈进, 李元, 等, 2001.云南会泽麒麟厂铅锌矿床八号矿体的发现[J].地质地球化学, 29(3):191-195. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzdqhx200103034 韩润生, 2005.隐伏矿定位预测的矿田(床)构造地球化学方法[J].地质通报, 24(10-11):978-984. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgqydz200510018 韩润生, 陈进, 黄智龙, 等, 2006.构造成矿动力学及隐伏矿定位预测:以云南会泽超大型铅锌(银、锗)矿床为例[M].北京:科学出版社:1-200. 韩润生, 王峰, 赵高山, 等, 2010.滇北东矿集区昭通毛坪铅锌矿床深部找矿新进展[J].地学前缘, 17(3):275. http://www.cnki.com.cn/Article/CJFDTotal-DXQY201003030.htm 韩润生, 胡煜昭, 罗大峰, 等, 2011.滇东北富锗铅锌矿床成矿构造背景讨论[J].矿物学报, 31(S1):200-201. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7684575 韩润生, 胡煜昭, 王学琨, 等, 2012.滇东北富锗银铅锌多金属矿集区矿床模型[J].地质学报, 86(2):280-294. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dizhixb201202007 韩润生, 王峰, 胡煜昭, 等, 2014.会泽型(HZT)富锗银铅锌矿床成矿构造动力学研究及年代学约束[J].大地构造与成矿学, 38(4):758-771. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ddgzyckx201404003 金中国, 2006.黔西北地区铅锌矿控矿因素、成矿规律与找矿预测研究[D].长沙: 中南大学: 16-17. https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CDFD&dbname=CDFD9908&filename=2006173426.nh&v=MDIwMjFyQ1VSN3FmWU9kbkZ5N2xVTHZJVjEyN0dMSy9IZFhPcVpFYlBJUjhlWDFMdXhZUzdEaDFUM3FUcldNMUY= 李朝阳, 1999.中国低温热液矿床集中分布区的一些地质特点[J].地学前缘, 6(1):163-170. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dxqy199901013 廖文, 1984.滇东、黔西铅锌金属区硫、铅同位素组成特征与成矿模式探讨[J].地质与勘探, (1):2-6. http://www.cnki.com.cn/Article/CJFDTotal-DZKT198401000.htm 林方成, 1994.四川会东大梁子铅锌矿床成因新探[J].矿床地质, 13(2):126-136. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400667992 柳贺昌, 1995.滇、川、黔铅锌成矿区的构造控矿[J].云南地质, 14(3):173-189. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199500584750 柳贺昌, 林文达, 1999.滇东北铅锌银矿床规律研究[M].昆明:云南大学出版社:47-56, 302-426. 刘文周, 徐新煌, 1996.论川滇黔铅锌矿成矿带矿床与构造的关系[J].成都理工学院学报, 23(1):71-77. http://www.cqvip.com/Main/Detail.aspx?id=2190842 沈冰, 2004.川滇黔层控型铅锌矿成矿特征[J].云南地质, 23(2):207-211. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yndz200402008 涂光炽, 1998.低温地球化学[M].北京:科学出版社. 王奖臻, 李朝阳, 李泽琴, 等, 2002.川、滇、黔交界地区密西西比河谷型铅锌矿床与美国同类矿床的对比[J].矿物岩石地球化学通报, 21(2):127-132. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kwysdqhxtb200202011 王明志, 韩润生, 周威, 等, 2019.黔西北矿集区亮岩铅锌矿区成矿构造解析[J].地质力学学报, 25(2):187-197. https://journal.geomech.ac.cn/ch/reader/view_abstract.aspx?flag=1&file_no=20190204&journal_id=dzlxxb 吴越, 2013.川滇黔地区MVT铅锌矿床大规模成矿作用的时代与机制[D].北京: 中国地质大学(北京). http://cdmd.cnki.com.cn/Article/CDMD-11415-1013261806.htm 张长青, 毛景文, 吴锁平, 等, 2005.川滇黔地区MVT铅锌矿床分布、特征及成因[J].矿床地质, 24(3):336-348. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kcdz200503013 张位及, 1984.试论滇东北铅锌矿床的沉积成因和成矿规律[J].地质与勘探, (7):11-16. http://www.cnki.com.cn/Article/CJFDTotal-DZKT198407002.htm 张志斌, 李朝阳, 涂光炽, 等, 2006.川、滇、黔接壤地区铅锌矿床产出的大地构造演化背景及成矿作用[J].大地构造与成矿学, 30(3):343-354. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ddgzyckx200603010 周云满, 2003.滇东北乐红铅锌矿床地质特征及找矿远景[J].地质地球化学, 31(4):16-21. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzdqhx200304003