GEOCHEMISTRY AND PALEO-TECTONIC ENVIRONMENT OF FENGYAN Pb-Zn ORE DEPOSIT IN MEIXIAN, CENTRAL FUJIAN PROVINCE
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摘要: 尤溪梅仙峰岩铅锌银矿床位于政和-德化前寒武纪变质分布区的南端, 处于北东向丽水-海丰断裂东侧闽东火山断拗带的次级寿宁-华安基底隆起带内。峰岩矿床的含矿岩系主要为上元古界马面山群东岩组(Pt3dy)。铅锌银矿体具层控特点。岩石学及地球化学研究表明赋矿地层东岩组为以绿片岩为主的一套古火山沉积建造。绿片岩的原岩为玄武岩类, 变粒岩主要为英安岩及流纹岩。玄武岩浆的形成可能和板块俯冲相关。矿床地球化学研究表明矿床存在多次成矿作用和多种硫源。铅同位素组成与演化表明从幔源至造山带和上地壳不同的铅源均有混入, 演化趋势较明显, 并显示多次地质事件叠加特点。金属硫化物的稀土分布型式都表现为一定程度的右倾斜, 轻重稀土分异显著。微量元素相对于MORB均有不同程度的亏损和富集。高场强元素(HFSE:Nb、Ta、Zr、Hf)表现为明显的负异常, 具较强烈的亏损; 而Pb、Rb和Ba等元素相对富集。东岩组变质火山岩也表现为明显的高场强元素的亏损及低场强元素的富集, 显示出典型和俯冲有关的岛弧岩浆的特征, 表明矿床与东岩组火山岩都形成于俯冲背景下的岛弧环境。Abstract: Pb-Zn-Ag ore deposit in Meixian, Youxi County is located at the south of the Zhenghe-Dehua pre-Cambrian metamorphic area, and geologically situated at Shouning-Hua' an sub-basement uplift zone in Eastern Fujian volcanic depression belt, east of the NE-striking Lishui-Haifeng fault. The ore-bearing beds of Fengyan ore deposit is mainly the Upper Proterozoic Dongyan Fomation of Mamianshan Group (Pt3dy). The Pb-Zn-Ag ore bodies are of strata bound type. Petrology and geochemistry studies show that the ore-bearing Dongyan Formation is a paleo-volcanic sedimentary formation dominated by greenshists. The formation of the basaltic magma may be related to the slab subduction.The original rocks of the greenshists are basaltic rocks, and granulites are mainly dacite and rhyolite. Geochemical study of ore deposit reveals that the ore deposit is characterized by multiple ore-forming processes and various kinds of sulfur sources. The composition and evolution of Pb isotopes show that different Pb sources from mantle to orogenic belt and upper crust are intermingled.The evolvement is of clear trend and demonstrates a superposition of multiple geological events. The REE pattern of metal sulfides shows a down-to-right slope with remarkable differentiation between LREE and HREE.Compared to MORB, the different trace elements are depleted and enriched to different degrees. High field strength elements (HFSE:Nb, Ta, Zr, Hf)show distinct negative anomaly and are strongly depleted while Pb, Rb and Ba are relatively enriched. Metavolcanics in the Dongyan Formation, with the same trend of HFSE depletion and the enrichment of LFSE, displays typical features of arc-magma related to subduction and indicates that the ore deposit and the Dongyan vocanics were formed under the arc environment with subduction background.
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Key words:
- Fengyan Pb-Zn ore deposit /
- geochemistry /
- paleo-arc /
- Dongyan Formation /
- central Fujian
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图 5 马面山群东岩组三角图解(图式据Pearce和Cann[9])
A区-岛弧拉斑玄武岩; B区-MORB、岛弧拉斑玄武岩和钙碱性玄武岩; C区-钙碱性玄武岩; D区-板内玄武岩
Figure 5. Ternary discrimination diagram of Dongyan Formation from Mamianshan Group
图 7 闽中地区东岩组绿片岩微量元素标准化蛛网图(图式据Pearce J A[10])
Figure 7. Normalized diagram of trace element concentrations for schist of Dongyan Group in central Fujian Province
图 9 梅仙峰岩及丁家山铅锌矿区铅同位素组成(图式据Doe和Zartman[11])
a-地幔演化线; b-造山带; c-上部地壳演化线; SK-两阶段演化线
Figure 9. Diagram of Pb stable isotope composition of Fengy an and Dingjiashan deposits
图 11 闽中尤溪梅仙峰岩矿石金属矿物微量元素标准化蛛网图(图式据Pearce J A[10])
Figure 11. Normalized diagram of trace element concentrations for schist of metal minerals from Fengyan deposit
表 1 闽中东岩组变质火山岩化学成分
Table 1. Chemical compositions of the Dongyan metamorphic volcanic rocks in central Fujian Province
表 2 闽中东岩组变质火山岩稀土元素分析数据
Table 2. REE data of the Dongyan metamorphic volcanic rocks in central Fujian Province
表 3 闽中尤溪梅仙一带铅、硫同位素组成
Table 3. Pb and S stable isotopic compositions of Meixian deposit in Youxi County, central Fujian Province
表 4 闽中尤溪梅仙峰岩矿床矿石中金属矿物微量及稀土化学元素测试结果
Table 4. Trace element and REE data of the Fengyan deposit in Youxi County, central Fujian Province
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