THE PETROGENESIS AND TECTONIC SIGNIFICANCES OF SILURIAN WEST-LUOTOUJUAN ROCKS FROM BEISHAN NIUJUANZI AREA IN GANSU PROVINCE, NW CHINA
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摘要: 北山牛圈子地区的骆驼圈西埃达克岩为过铝质钙碱性岩浆系列,具有高的SiO2(>57.94%)、Al2O3(>16.66%)和低的MgO( < 4.32%)含量, 较高的Na2O/K2O比值(>3.13),显示富钠的特征; 而在微量元素上,高Sr(589×10-6~1170×10-6),低Y (4.60×10-6~13.90×10-6)和Yb (0.43×10-6~1.32×10-6);轻重稀土分异明显(La/Dy)N=4.60~13.87、(La/Yb)N=7.17~20.58,Eu异常不明显(Eu/Eu*=0.85~1.32);富集轻稀土和大离子亲石元素,而亏损高场强元素Nb,Ta,Ti和重稀土HREE,与世界上典型的俯冲洋壳熔融形成的埃达克岩特征相似。结合区域上埃达克岩的研究成果和岀露的构造位置,以及与牛圈子蛇绿岩的关系,认为骆驼圈西埃达克岩是志留纪(U-Pb年龄为428.9 Ma)时期热的洋壳向公婆泉—东七一山早古生代活动陆缘带俯冲过程中部分熔融的产物。对该岩体的研究,为进一步研究北山造山带早古生代北山洋盆闭合和晚古生代北山洋盆重新裂开提供新的依据。Abstract: West-Luotuojuan Adakitesin Beishan Niujuanzi Area belongs to Peraluminous calcium alkaline magma series with a high content of SiO2(>57.94%), Al2O3(>16.66%), a low content of MgO( < 4.32%), a relatively high Na2O/K2O ratio, displaying Na-rich feature. In respect of trace elements, it has a high content of Sr (589×10-6~1170×10-6), a low content of Y (4.60×10-6~13.90×10-6) and Yb (0.43×10-6~1.32×10-6).The differentiation of light and heavy rare earth is obvious ((La/Dy)N=4.60~13.87, (La/Yb)N=7.17~20.58), and there is not obvious anomaly of Eu (Eu/Eu*=0.85~1.32). Rich in light rare earth and large ionlithophile elements, and the loss of high field-strength elements Nb, Ta, Ti and heavy rare earth HREE, are similar with the typical Adakite rocks which formed by subducted oceanic crust melting.It is believed that West-Luotuojuan Adakite is a partial melting product which warm oceanic crust in Silurian (U-Pb age of 428.9 Ma) period moving to Gongpo spring-east Qiyi mountain early Paleozoic active continental margin in the process of subduction. The study of the rock mass provides evidence for the view that Beishan orogenic belt closed in the late early Paleozoic and split anew in the early late Paleozoic.
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图 1 牛圈子地区地质简图[22]
Figure 1. Geological sketch in Niujuanzi area
图 4 骆驼圈西岩体位微量元素蛛网图和稀土元素配分曲线[24]
Figure 4. Primitive mantle normalized trace elements spider diagrams and chondrite normalized REE distribution patterns of West-Luotuojuan Rocks
图 7 骆驼圈西岩体Sr/Y-Y和(La/Yb)N-YbN判别图[2]
Figure 7. Discrimination diagram of Sr/Y-Y and (La/Yb)N-YbN for West-Luotuojuan rocks
图 8 埃达克岩与玄武岩的实验熔融体的SiO2-MgO图解[29]
Figure 8. SiO2-MgO diagrams of the experimental melt of adakite and the basalts
表 1 牛圈子地区埃达克岩主量(%)与微量元素(10-6)化学分析结果
Table 1. Major and trace element compositions of the adakite from Niujuanzi region
sample岩性 131042 131062 131044 131064 132001 131061 131012 131041 英云闪长岩 石英闪长岩 SiO2 69.17 66.68 67.70 66.87 65.10 57.94 60.16 60.54 TiO2 0.25 0.34 0.35 0.31 0.36 0.86 0.67 0.67 Al2O3 16.59 17.42 16.66 17.35 17.32 18.49 17.05 17.10 Fe2O3 0.90 1.14 1.15 1.18 1.83 1.99 1.86 1.84 FeO 1.37 1.72 1.88 1.56 1.42 2.79 3.79 3.49 MnO 0.05 0.05 0.06 0.05 0.06 0.08 0.09 0.10 MgO 0.97 1.35 1.37 1.27 1.54 4.32 3.61 3.33 CaO 3.86 4.46 4.48 4.70 4.63 7.58 6.47 5.69 K2O 1.03 1.26 1.20 1.07 0.81 0.94 0.92 1.21 Na2O 4.64 4.73 4.24 4.57 4.85 3.33 3.60 3.77 P2O5 0.11 0.13 0.14 0.13 0.13 0.13 0.19 0.21 LOI 0.89 0.51 0.55 0.77 1.79 1.22 1.15 1.63 total 99.84 99.79 99.78 99.82 99.84 99.67 99.56 99.57 AR 1.77 1.75 1.69 1.69 1.69 1.39 1.48 1.56 A/CNK 1.74 1.67 1.68 1.68 1.68 1.56 1.55 1.6 Mg # 0.44 0.47 0.46 0.46 0.47 0.63 0.54 0.54 Cr 8.5 8.9 14 9.8 11.7 34.9 55.4 48.9 Ni 5.55 7.94 10.4 7.05 13.2 18.7 46 40.8 V 39.2 54.4 51.4 50.5 59.7 112 147 121 Sc 4.82 5.21 5.22 5.25 7.28 12.1 14.5 15 Co 5.99 8 8.49 7.43 9.34 18.2 20.5 19.6 Rb 21.5 29.1 25.8 16.3 13 20.1 23.5 37.6 Cs 1 2.28 1.46 1.34 0.76 0.8 1.26 1.74 Sr 595 654 602 695 694 1170 592 589 Ba 313 355 408 407 277 191 272 315 Ga 17.4 18.7 17.9 18.1 18.3 19.3 19.3 19.1 Pb 12.6 12 9.02 11.3 9.6 6.89 10.1 10.2 U 0.57 0.62 0.58 0.47 0.52 0.44 1.06 1.56 Th 4.05 1.17 3.79 1.5 1.99 1.08 4.32 4.76 Nb 2.36 2.36 3.11 1.92 2.42 2.54 3.42 5.38 Ta 0.22 0.22 0.28 0.18 0.15 0.2 0.29 0.43 Zr 84.1 74.5 103 63.3 90.1 79.3 129 88.9 Hf 2.79 2.1 2.86 1.69 2.57 2.47 3.44 2.65 Y 5.05 5.22 6.41 4.6 6.93 10.9 13 13.9 La 13.2 6.47 11.6 8.58 7.56 10 12.9 16.8 Ce 26.5 14 23.9 18.2 17.6 24.8 29.5 38.2 Pr 3.28 1.72 2.8 2.13 2.43 3.32 3.85 5.03 Nd 11.2 7.29 10.6 8.17 10 13.5 15.6 19.6 Sm 2.19 1.81 2.19 1.62 2.13 2.91 3.76 4.31 Eu 0.56 0.65 0.8 0.67 0.69 1.08 1.1 1.12 Gd 1.53 1.47 1.8 1.42 1.78 2.65 3.28 3.57 Tb 0.2 0.19 0.25 0.18 0.25 0.4 0.48 0.52 Dy 1.02 1.03 1.42 0.97 1.46 2.33 2.72 2.96 Ho 0.18 0.2 0.24 0.19 0.29 0.44 0.52 0.54 Er 0.47 0.5 0.64 0.48 0.71 1.1 1.32 1.41 Tm 0.06 0.08 0.09 0.07 0.10 0.16 0.20 0.21 Yb 0.46 0.47 0.64 0.43 0.65 1 1.29 1.32 Lu 0.059 0.074 0.076 0.066 0.093 0.14 0.19 0.2 ∑REE 60.91 35.95 57.04 43.17 45.74 63.83 76.71 95.79 LREE 56.93 31.94 51.89 39.37 40.41 55.61 66.71 85.06 HREE 3.98 4.01 5.15 3.80 5.33 8.22 10.00 10.73 Eu/Eu * 0.89 1.18 1.20 1.32 1.05 1.17 0.94 0.85 (La/Yb) N 20.58 9.87 13 14.31 8.34 7.17 7.17 9.13 (Ho/Yb) N 1.18 1.28 1.13 1.33 1.34 1.32 1.21 1.23 (La/Dy) N 13.87 6.73 8.75 9.48 5.55 4.60 5.08 6.08 Eu/Eu*=EuN/(SmN×GdN)1/2,(La/Yb)N、(Ho/Yb)N、(La/Dy)N is ratio of Chondrite [24] 表 2 北山造山带骆驼圈西英云闪长岩锆石U-Pb同位素分析结果
Table 2. LA-ICP-MS U-Pb zircons dating results of sample (132053) from West-Luotuojuan in Beishan orogen
Analysis_# Th U Th/U Pb207/Pb206 Pb207/U235 Pb206/U238 Pb208/Th232 Pb207/U235 Pb206/U238 Pb208/Th232 ratio 1sigma ratio 1sigma ratio 1sigma ratio 1sigma ratio 1sigma ratio 1sigma ratio 1sigma 132053-01 81.69 3550.82 0.02 0.05571 0.00092 0.43564 0.00730 0.05672 0.00079 0.04629 0.00186 367.2 5.16 355.6 4.8 914.5 35.84 132053-02 28.94 1223.24 0.02 0.05675 0.00089 0.44718 0.00720 0.05715 0.00077 0.02215 0.00060 375.3 5.05 358.3 4.69 442.9 11.95 132053-03 157.31 4170.61 0.04 0.05856 0.00099 0.46470 0.00796 0.05755 0.00081 0.03784 0.00155 387.5 5.52 360.7 4.92 750.6 30.28 132053-04 50.28 2494.59 0.02 0.05756 0.00095 0.46393 0.00781 0.05845 0.00080 0.02060 0.00064 387 5.41 366.2 4.89 412.1 12.6 132053-05 223.89 2183.09 0.10 0.10248 0.00165 0.84796 0.01387 0.06001 0.00083 0.06666 0.00205 623.5 7.62 375.7 5.07 1304.4 38.86 132053-06 503.50 554.08 0.91 0.05582 0.00092 0.52517 0.00878 0.06823 0.00093 0.02101 0.00057 428.6 5.84 425.5 5.62 420.3 11.22 132053-07 197.21 450.71 0.44 0.05550 0.00103 0.52273 0.00967 0.06831 0.00097 0.02156 0.00070 427 6.45 426 5.88 431.2 13.79 132053-08 366.42 421.73 0.87 0.05524 0.00117 0.52042 0.01076 0.06833 0.00102 0.02038 0.00063 425.4 7.18 426.1 6.16 407.9 12.45 132053-09 205.79 313.27 0.66 0.05508 0.00099 0.51935 0.00935 0.06838 0.00097 0.02067 0.00062 424.7 6.25 426.4 5.83 413.5 12.19 132053-10 184.73 419.12 0.44 0.05537 0.00097 0.52254 0.00920 0.06844 0.00096 0.02217 0.00067 426.8 6.14 426.8 5.76 443.3 13.25 132053-11 425.11 672.40 0.63 0.05454 0.00089 0.51680 0.00858 0.06872 0.00093 0.02161 0.00059 423 5.74 428.5 5.64 432.1 11.71 132053-12 166.55 281.16 0.59 0.05709 0.00120 0.54205 0.01111 0.06885 0.00103 0.02243 0.00074 439.8 7.32 429.2 6.2 448.3 14.65 132053-13 257.49 655.48 0.39 0.05789 0.00147 0.55007 0.01334 0.06891 0.00114 0.01945 0.00132 445 8.74 429.6 6.85 389.4 26.22 132053-14 431.94 865.59 0.50 0.05818 0.00118 0.55336 0.01103 0.06899 0.00103 0.02131 0.00217 447.2 7.21 430.1 6.23 426.1 42.92 132053-15 206.52 355.68 0.58 0.06019 0.00129 0.57471 0.01196 0.06925 0.00106 0.02185 0.00076 461.1 7.71 431.6 6.37 436.9 15.01 132053-16 65.00 248.92 0.26 0.06119 0.00120 0.58951 0.01143 0.06987 0.00102 0.02470 0.00101 470.6 7.3 435.4 6.15 493.2 19.97 132053-17 54.30 125.52 0.43 0.06421 0.00193 0.61913 0.01749 0.06994 0.00128 0.02492 0.00119 489.3 10.97 435.8 7.72 497.6 23.43 -
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