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东昆仑哈日扎花岗闪长岩形成时代、地球化学特征及其构造意义

国显正 贾群子 李金超 孔会磊 姚学钢 栗亚芝 马忠元

国显正, 贾群子, 李金超, 等, 2019. 东昆仑哈日扎花岗闪长岩形成时代、地球化学特征及其构造意义. 地质力学学报, 25 (2): 286-300. DOI: 10.12090/j.issn.1006-6616.2019.25.02.027
引用本文: 国显正, 贾群子, 李金超, 等, 2019. 东昆仑哈日扎花岗闪长岩形成时代、地球化学特征及其构造意义. 地质力学学报, 25 (2): 286-300. DOI: 10.12090/j.issn.1006-6616.2019.25.02.027
GUO Xianzheng, JIA Qunzi, LI Jinchao, et al., 2019. THE FORMING AGE AND GEOCHEMISTRY CHARACTERISTICS OF THE GRANODIORITES IN HARIZHA, EAST KUNLUN AND ITS TECTONIC SIGNIFICANCE. Journal of Geomechanics, 25 (2): 286-300. DOI: 10.12090/j.issn.1006-6616.2019.25.02.027
Citation: GUO Xianzheng, JIA Qunzi, LI Jinchao, et al., 2019. THE FORMING AGE AND GEOCHEMISTRY CHARACTERISTICS OF THE GRANODIORITES IN HARIZHA, EAST KUNLUN AND ITS TECTONIC SIGNIFICANCE. Journal of Geomechanics, 25 (2): 286-300. DOI: 10.12090/j.issn.1006-6616.2019.25.02.027

东昆仑哈日扎花岗闪长岩形成时代、地球化学特征及其构造意义

doi: 10.12090/j.issn.1006-6616.2019.25.02.027
基金项目: 

中国地质大调查项目 DD20160013

中国地质大调查项目 12120115022101

详细信息
    作者简介:

    国显正(1990-), 男, 在读博士, 主要从事岩石学、矿床学研究。E-mail:cuggxz@126.com

    通讯作者:

    贾群子(1962-), 男, 研究员, 从事矿床学和区域成矿规律研究。E-mail: xajqunzi@126.com

  • 中图分类号: P548

THE FORMING AGE AND GEOCHEMISTRY CHARACTERISTICS OF THE GRANODIORITES IN HARIZHA, EAST KUNLUN AND ITS TECTONIC SIGNIFICANCE

  • 摘要: 为探讨东昆仑哈日扎银多金属矿岩浆演化序列及其岩石成因,对哈日扎花岗闪长岩进行了年代学和地球化学研究。结果表明,哈日扎花岗闪长岩LA-ICP-MS锆石U-Pb年龄为423.8±4.3 Ma,形成于晚志留世;地球化学特征显示花岗闪长岩高硅,SiO2介于71.21%~74.46%;高铝,Al2O3含量介于13.48%~14.46%;富钾贫钠,K2O/Na2O比值为1.32~1.54;A/CNK介于1.02~1.08,显示高钾钙碱性弱过铝质特征;稀土显示出轻稀土富集,重稀土亏损的右倾配分模式,富集Rb、Th、K元素,亏损Ba以及Nb、Ta、Ti等,具有I到S过渡型花岗岩特征,源区主要为上地壳砂屑岩部分熔融,是区域后碰撞伸展构造背景下的产物。

     

  • 图  1  哈日扎矿区地质简图

    Figure  1.  The sketch geological map of the Harizha mining area

    图  2  哈日扎花岗闪长岩野外及镜下显微结构照片

    Figure  2.  Outcrop picture and microstructure photograph of Harizha granodiorite

    图  3  哈日扎岩体TAS图解[22]与An-Ab-Or图解[23]

    Figure  3.  TAS diagram[22] and An-Ab-Or classification diagram[23] of Harizha granite

    图  4  哈日扎岩体的K2O-SiO2图解[22]及A/CNK—A/NK图解[24]

    Figure  4.  K2O-SiO2 diagram[22] and A/CNK-A/NK diagram[24]

    图  5  哈日扎花岗闪长岩的稀土元素球粒陨石标准化图解及微量元素原始地幔标准化图[25]

    Figure  5.  Chondrite-normalized REE patterns and primitive mantle-normalized trace element patterns for Harizha granodiorite[25]

    图  6  花岗闪长岩锆石阴极发光照片

    (圈内数字代表U-Pb分析点,下方数字代表206Pb/238U表面年龄)

    Figure  6.  CL images of zircons from Harizha granodiorite (numbers in the circles represent analytical spots of U-Pb, and the values respent ages of 206Pb/238U)

    图  7  花岗闪长岩锆石U-Pb年龄谐和图及加权平均年龄图

    Figure  7.  Zircon U-Pb concordia diagram and weighted mean ages diagram for Harizha granodiorite

    图  8  哈日扎花岗闪长岩成因类型判别图

    A—A型花岗岩;FG—分异I、S、M型花岗岩;OGT—未分异I、S、M型花岗岩a—Zr+Nb+Ce+Y—TFeO/MgO图解; b—Zr+Nb+Ce+Y—(K2O+Na2O)/CaO图解; c—ACF判别图解(底图据文献[40])

    Figure  8.  Various chemical discrimination diagrams of Harizha granodiorite

    图  9  花岗闪长岩微量元素构造判别图解[47]

    Syn-COLG-同碰撞花岗岩;WPG-板内花岗岩;VAG-火山岛弧花岗岩;ORG-洋脊花岗岩

    Figure  9.  Trace element tectonic discrimination diagrams of Harizha granodiorite[47]

    表  1  花岗闪长岩主量元素含量(%)

    Table  1.   Contents of major elements(%)in Harizha granodiorite

    岩性 花岗闪长岩(文中) 英云闪长岩(据张斌等)[21 ]
    样品号 16LLMH1 16LLMH2 16LLMH3 16LLMH4 16LLMH5 ZK1501H1 ZK1501H2 ZK1501H3 ZK1501H4 ZK1501H5
    SiO2 73.28 74.18 71.21 73.95 74.46 70.40 71.38 69.55 69.43 69.27
    TiO2 0.16 0.14 0.29 0.14 0.13 0.31 0.33 0.28 0.32 0.34
    Al2O3 13.77 13.48 14.46 13.57 13.54 14.03 14.13 13.43 14.28 14.03
    Fe2O3 0.53 0.33 0.44 0.25 0.3 0.86 0.61 1.66 0.74 0.70
    FeO 1.03 0.92 1.44 0.98 0.85 1.83 1.20 2.17 1.25 1.44
    MnO 0.032 0.034 0.04 0.03 0.028 0.11 0.07 0.11 0.08 0.08
    MgO 0.53 0.39 0.62 0.39 0.37 1.29 0.85 1.47 1.10 1.54
    CaO 1.13 1.03 1.97 1.06 0.84 1.95 1.88 2.46 2.94 2.84
    Na2O 3.33 3.51 3.2 3.5 3.47 3.61 3.46 1.64 2.43 2.24
    K2O 4.88 4.65 4.93 4.75 4.86 3.27 3.38 3.32 3.32 3.36
    P2O5 0.067 0.069 0.13 0.069 0.07 0.10 0.10 0.09 0.10 0.10
    灼失 1.21 1.23 1.22 1.25 1.03 2.15 2.54 3.74 3.94 3.98
    Total 99.95 99.96 99.95 99.94 99.95 99.91 99.93 99.92 99.92 99.92
    K2O/Na2O 1.47 1.32 1.54 1.36 1.40 0.91 0.98 2.02 1.37 1.50
    A/CNK 1.07 1.06 1.02 1.06 1.08 1.08 1.11 1.25 1.10 1.12
    A/NK 1.28 1.25 1.36 1.24 1.23 1.48 1.51 2.13 1.88 1.91
    Mg# 0.39 0.36 0.38 0.37 0.37 0.47 0.46 0.42 0.51 0.57
    DI 89.80 91.14 85.40 90.99 92.07 81.70 84.16 75.10 77.63 76.45
    刚玉(C) 1.13 0.98 0.60 0.92 1.22 1.26 1.64 2.99 1.64 1.86
    石英(Q) 32.05 33.23 28.46 32.54 33.36 30.68 33.59 40.26 35.77 35.99
    钙长石(An) 5.23 4.72 9.04 4.87 3.75 9.25 8.91 12.11 14.54 14.00
    钠长石(Ab) 28.54 30.08 27.43 30.01 29.68 31.25 30.06 14.43 21.42 19.76
    正长石(Or) 29.21 27.83 29.51 28.44 29.03 19.77 20.51 20.41 20.44 20.70
    下载: 导出CSV

    表  2  花岗闪长岩微量元素含量(×10-6)

    Table  2.   Contents of trace elements(×10-6)in Harizha granodiorite

    岩性 花岗闪长岩(文中) 英云闪长岩(据张斌等)[21]
    样品号 16LLMH1 16LLMH2 16LLMH3 16LLMH4 16LLMH5 ZK1501H1 ZK1501H2 ZK1501H3 ZK1501H4 ZK1501H5
    Cu 153 26.5 15 26.5 13.2 23.1 19.1 38.7 17.4 14.7
    Pb 43.9 40.9 44.6 38.7 40.1 1320 293 2020 137 198
    Zn 115 36.3 50.6 31.5 25.8 902 281 1510 113 184
    Cr 11.8 7.89 11.7 20 3 14.7 18 16.2 28.3 57.9
    Co 2.42 1.6 3.16 1.48 1.28 5.3 3.51 6.03 3.1 3.42
    Rb 225 215 225 220 224 108 143 167 137 156
    Sr 118 106 193 107 105 198 99.6 52.8 60.4 56.7
    Ba 245 238 499 240 254 354 253 170 130 154
    V 13.2 11.7 19.1 13.7 12.3 29 26 26.4 27.6 29.2
    Sc 4.94 4.1 5.57 4.06 3.62 8.62 7.76 5.77 7.74 8.94
    Nb 19.5 17.2 20 17.4 16.1 9.84 10.1 8.82 10.4 10.6
    Ta 2.69 2.14 1.62 2.28 2.22 0.8 0.8 0.79 0.84 0.85
    Zr 78.8 81.4 110 78.4 78.2 173 165 131 167 164
    Hf 2.34 1 2.7 1.27 1.11 4.69 4.6 3.68 4.75 4.52
    U 3.81 3.26 3.13 3.03 2.89 5.53 14 9.96 6.05 8.8
    Th 18 18.3 14.4 16.5 16.6 20.4 16.1 15.8 18.3 19
    La 20 22.1 28.5 19.8 19.2 30 27.5 23.4 23.8 28.9
    Ce 43.3 48.2 54.9 43 42.9 62.2 57.6 48.6 50.6 60.8
    Pr 5.34 5.79 6.57 5.23 5.04 7.32 6.74 5.81 6.03 7.09
    Nd 19.2 21.3 23.1 18.8 18.5 25.6 23.9 21.1 21.7 25
    Sm 4.64 5.04 5.18 4.43 4.24 4.76 4.83 4.24 4.63 5.22
    Eu 0.48 0.52 0.79 0.47 0.46 0.8 0.87 0.68 0.83 0.76
    Gd 3.83 4.16 4.41 3.75 3.62 4.01 4.18 3.83 4.17 4.49
    Tb 0.67 0.72 0.73 0.65 0.62 0.59 0.62 0.62 0.66 0.7
    Dy 3.51 3.86 3.78 3.32 3.17 3.35 3.56 3.54 3.91 4.14
    Ho 0.62 0.67 0.65 0.58 0.57 0.63 0.7 0.69 0.81 0.82
    Er 1.75 1.87 1.93 1.61 1.6 1.69 1.91 1.88 2.22 2.18
    Tm 0.26 0.29 0.3 0.25 0.24 0.25 0.29 0.28 0.34 0.33
    Yb 1.75 1.85 2.06 1.63 1.54 1.62 1.89 1.86 2.24 2.12
    Lu 0.26 0.27 0.32 0.24 0.23 0.24 0.29 0.27 0.34 0.32
    Y 17.4 18.4 18.7 16 15.5 15.6 18.8 19 20.6 20.4
    ΣREE 105.61 116.64 133.22 103.76 101.93 143.06 134.88 116.8 122.28 142.87
    LREE 92.96 102.95 119.04 91.73 90.34 130.68 121.44 103.83 107.59 127.77
    HREE 12.65 13.69 14.18 12.03 11.59 12.38 13.44 12.97 14.69 15.1
    LREE/HREE 7.35 7.52 8.39 7.63 7.79 10.56 9.04 8.01 7.32 8.46
    (La/Yb)N 8.2 8.57 9.92 8.71 8.94 13.28 10.44 9.02 7.62 9.78
    δEu 0.35 0.35 0.51 0.35 0.36 0.54 0.58 0.51 0.57 0.47
    δCe 1.03 1.04 0.98 1.04 1.07 1 1.01 0.99 1.01 1.01
    下载: 导出CSV

    表  3  哈日扎花岗闪长岩锆石LA-ICP-MS测年结果

    Table  3.   LA-ICP-MS isotopic data of zircon from Harizha granodiorite

    编号 w(Th)/
    ×10-6
    w(U)/
    ×10-6
    Th/U Pb207/Pb206 Pb207/U235 Pb206/U238 Pb207/Pb206 Pb207/U235 Pb206/U238
    比值 比值 比值 年龄 年龄 年龄
    043LH01 131.32 275.05 0.48 0.05766 0.00248 0.53534 0.02421 0.06745 0.00204 516.5 92.1 435.3 16.0 420.8 12.3
    044LH02 93.21 266.32 0.35 0.05875 0.00193 0.53925 0.01981 0.06668 0.00191 557.8 70.2 437.9 13.1 416.1 11.6
    045LH03 98.65 238.20 0.41 0.05816 0.00246 0.53665 0.02409 0.06703 0.00198 535.2 90.6 436.2 15.9 418.2 12.0
    046LH04 151.37 312.69 0.48 0.05355 0.00165 0.51658 0.0181 0.07007 0.00198 352.2 67.9 422.9 12.1 436.6 11.9
    047LH05 83.02 243.79 0.34 0.05262 0.00181 0.48657 0.01858 0.06717 0.00192 312.4 76.6 402.6 12.7 419.1 11.6
    048LH06 96.62 238.41 0.41 0.05661 0.00192 0.52484 0.0198 0.06734 0.00193 475.6 74.2 428.4 13.2 420.1 11.6
    052LH07 89.57 301.48 0.30 0.05687 0.00183 0.52152 0.01887 0.06659 0.00189 486.0 70.1 426.2 12.6 415.6 11.5
    053LH08 178.38 331.58 0.54 0.05434 0.00171 0.49587 0.01773 0.06627 0.00187 384.9 69.1 408.9 12.0 413.7 11.3
    054LH09 125.66 289.37 0.43 0.05224 0.00159 0.49705 0.01734 0.06909 0.00195 296.0 68.0 409.7 11.8 430.7 11.8
    055LH10 136.62 272.58 0.50 0.05235 0.00176 0.48279 0.01812 0.06696 0.0019 300.8 74.8 400.0 12.4 417.8 11.5
    056LH11 306.08 440.85 0.69 0.05444 0.00148 0.50843 0.01641 0.06781 0.0019 389.2 59.8 417.4 11.0 423.0 11.4
    059LH13 186.54 422.99 0.44 0.05552 0.0016 0.50719 0.01697 0.06633 0.00186 432.8 62.5 416.6 11.4 414.0 11.3
    060LH14 231.99 375.28 0.62 0.05362 0.00164 0.48406 0.01696 0.06553 0.00185 355.2 67.7 400.9 11.6 409.2 11.2
    061LH15 44.10 138.60 0.32 0.05521 0.00261 0.51764 0.02563 0.06806 0.00202 420.7 102.2 423.6 17.2 424.4 12.2
    062LH16 142.80 308.34 0.46 0.05387 0.00187 0.51095 0.0196 0.06886 0.00196 365.3 76.1 419.1 13.2 429.3 11.8
    063LH17 95.94 242.96 0.39 0.05867 0.00213 0.56639 0.02247 0.07008 0.00202 554.8 77.1 455.7 14.6 436.6 12.1
    064LH18 149.86 325.49 0.46 0.05906 0.00189 0.56916 0.02051 0.06996 0.00199 569.1 68.1 457.5 13.3 435.9 12.0
    068LH19 65.41 168.91 0.39 0.05559 0.00238 0.52091 0.02371 0.06801 0.00199 435.5 92.6 425.8 15.8 424.2 12.0
    069LH20 88.08 210.26 0.42 0.05736 0.00227 0.54989 0.02349 0.06957 0.00201 504.9 85.3 444.9 15.4 433.6 12.1
    070LH21 83.91 305.52 0.27 0.05074 0.00198 0.48979 0.02067 0.07005 0.00203 229.1 87.8 404.8 14.1 436.4 12.2
    071LH22 64.82 232.05 0.28 0.05516 0.00205 0.51568 0.0209 0.06784 0.00195 418.4 80.5 422.3 14.0 423.2 11.8
    072LH23 58.69 475.27 0.12 0.05348 0.00152 0.51686 0.01719 0.07013 0.00196 349.0 63.0 423.1 11.5 436.9 11.8
    073LH24 83.79 206.80 0.41 0.05856 0.00227 0.56564 0.0236 0.07008 0.00205 550.9 82.4 455.2 15.3 436.7 12.3
    075LH25 41.85 135.11 0.31 0.05023 0.00272 0.47086 0.02645 0.06801 0.00202 205.8 121.1 391.8 18.3 424.1 12.2
    076LH26 65.65 437.80 0.15 0.05483 0.00155 0.50014 0.01655 0.06618 0.00185 405.3 61.2 411.8 11.2 413.1 11.2
    077LH27 249.69 394.02 0.63 0.05489 0.00165 0.52177 0.01807 0.06896 0.00193 407.9 65.2 426.3 12.1 429.9 11.7
    078LH28 93.28 330.83 0.28 0.05651 0.00183 0.52212 0.01909 0.06703 0.00189 471.8 71.0 426.6 12.7 418.2 11.5
    079LH29 110.17 290.73 0.38 0.06062 0.00242 0.55691 0.02378 0.06665 0.00196 625.6 83.8 449.5 15.5 415.9 11.9
    080LH30 42.08 147.20 0.29 0.05271 0.00559 0.49771 0.05247 0.06849 0.00246 316.5 224.0 410.2 35.6 427.1 14.8
    下载: 导出CSV

    表  4  哈日扎矿区岩浆序列同位素年龄

    Table  4.   Isptopic ages of Harizha magmatic series

    岩性 定年方法 年龄 资料来源
    花岗岩 LA-ICP-MS 242.6±2.6 Ma [29]
    245.8±3.4 Ma
    石英闪长岩 LA-ICP-MS 239.3±2.2 Ma [15]
    花岗闪长斑岩 LA-ICP-MS 234.5±4.8 Ma [14]
    闪长岩 LA-ICP-MS 424.7±4.8 Ma [29]
    花岗闪长岩 LA-ICP-MS 423.8±4.3 Ma 文中
    英云闪长岩 LA-ICP-MS 422.3±1.9 Ma [21]
    下载: 导出CSV
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  • 收稿日期:  2018-03-03
  • 修回日期:  2018-08-30
  • 刊出日期:  2019-04-28

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