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西藏尕尔勤铜矿床花岗闪长斑岩地球化学特征及成矿作用研究

何阳阳 温春齐 刘显凡

何阳阳, 温春齐, 刘显凡, 2018. 西藏尕尔勤铜矿床花岗闪长斑岩地球化学特征及成矿作用研究. 地质力学学报, 24 (3): 341-349. DOI: 10.12090/j.issn.1006-6616.2018.24.03.036
引用本文: 何阳阳, 温春齐, 刘显凡, 2018. 西藏尕尔勤铜矿床花岗闪长斑岩地球化学特征及成矿作用研究. 地质力学学报, 24 (3): 341-349. DOI: 10.12090/j.issn.1006-6616.2018.24.03.036
HE Yangyang, WEN Chunqi, LIU Xianfan, 2018. GEOCHEMICAL CHARACTERISTICS OF GRANODIORITE PORPHYRY AND MINERALIZATION STUDY IN THE GAERQIN COPPER DEPOSIT, TIBET. Journal of Geomechanics, 24 (3): 341-349. DOI: 10.12090/j.issn.1006-6616.2018.24.03.036
Citation: HE Yangyang, WEN Chunqi, LIU Xianfan, 2018. GEOCHEMICAL CHARACTERISTICS OF GRANODIORITE PORPHYRY AND MINERALIZATION STUDY IN THE GAERQIN COPPER DEPOSIT, TIBET. Journal of Geomechanics, 24 (3): 341-349. DOI: 10.12090/j.issn.1006-6616.2018.24.03.036

西藏尕尔勤铜矿床花岗闪长斑岩地球化学特征及成矿作用研究

doi: 10.12090/j.issn.1006-6616.2018.24.03.036
基金项目: 

国土资源部公益性行业科研专项项目 201011013

四川省教育厅科研项目 17ZB0223

详细信息
    作者简介:

    何阳阳(1984-), 男, 博士, 主要从事矿床学及区域成矿学研究工作。E-mail:yangyang.he@qq.com

    通讯作者:

    温春齐(1945-), 男, 教授, 主要从事矿床学及区域成矿学研究工作。E-mail:wcq@cdut.edu.cn

  • 中图分类号: P588.121;P618

GEOCHEMICAL CHARACTERISTICS OF GRANODIORITE PORPHYRY AND MINERALIZATION STUDY IN THE GAERQIN COPPER DEPOSIT, TIBET

  • 摘要: 对尕尔勤铜矿床花岗闪长斑岩及其锆石的稀土元素进行了分析,并对其成矿作用进行了研究。结果表明,花岗闪长斑岩稀土元素总含量变化范围不大(ΣREE=48.64×10-6~78.12×10-6),LREE/HREE=8.67~11.68,所有样品都呈轻稀土元素相对富集、重稀土元素亏损的右倾型分配模式;δEu由弱负异常→弱正异常演化,这是因为地幔底辟作用引发地壳部分重熔形成长英质岩浆的过程中,逐步消弱了结晶分异导致的负Eu异常进而出现弱的正Eu异常。锆石具有典型的振荡环带,稀土总量较高(ΣREE=735.78×10-6~6792.10×10-6),相对亏损轻稀土,富集重稀土,正Ce异常明显,并呈现弱的负Eu异常,这是因为在地幔流体作用下,重稀土元素及Ce较其它轻稀土元素更容易进入锆石晶格所致,Eu呈弱的负异常则是成岩后期岩体受氧化淋滤所致。综合分析,揭示出地幔流体作用导致花岗闪长斑岩具有壳幔混染甚至成矿特征,同时还能透过岩浆与围岩发生物质和能量的交换,导致变质砂岩成矿的成因机制。

     

  • 图  1  尕尔勤铜矿床大地构造位置及矿体平面图

    Figure  1.  Geotectonic location and ore body plan of the Gaerqin porphyry copper deposit

    图  2  花岗闪长斑岩手标本及镜下照片

    Figure  2.  Manual samples and microscopic photographs of granodiorite porphyry

    图  3  代表性锆石阴极发光图像

    Figure  3.  Cathodoluminescence(CL) images of typical zircons

    图  4  尕尔勤花岗闪长斑岩稀土元素标准化图解

    Figure  4.  Standardization diagram of rare earth elements in granodiorite porphyry

    图  5  锆石稀土元素标准化图解

    Figure  5.  Standardization diagram of rare earth elements in zircon

    表  1  花岗闪长斑岩稀土元素测试分析表(×10-6)

    Table  1.   Test analysis table for rare earth elements of granodiorite porphyry

    序号 样号 岩性 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
    1 DL025 花岗闪长斑岩 17.6 34.5 3.77 12.9 2.57 0.62 1.86 0.28 1.56 0.33 0.93 0.13 0.92 0.15
    2 DL027 花岗闪长斑岩 14.4 26.2 2.86 10.4 1.87 0.58 1.44 0.24 1.36 0.27 0.82 0.11 0.80 0.14
    3 DL031 花岗闪长斑岩 16.0 30.0 3.19 11.6 2.19 0.59 1.63 0.26 1.49 0.32 0.87 0.12 0.85 0.14
    4 DL033 花岗闪长斑岩 14.1 22.1 2.56 9.16 1.76 0.50 1.34 0.24 1.47 0.34 1.00 0.15 1.03 0.17
    5 DL037 花岗闪长斑岩 10.5 20.9 2.32 7.79 1.60 0.50 1.22 0.22 1.34 0.30 0.86 0.12 0.83 0.14
    下载: 导出CSV

    表  2  花岗闪长斑岩稀土元素相关参数计算

    Table  2.   Rare earth elements related parameter calculation of granodiorite porphyry

    序号 样号 LREE HREE L/H ΣREE La/Yb Sm/Nd Eu/Sm (La/Sm)N (Gd/Yb)N δCe δEu
    1 DL025 71.96 6.16 11.68 78.12 19.13 0.20 0.24 4.31 1.63 0.97 0.83
    2 DL027 56.31 5.18 10.87 61.49 18.00 0.18 0.31 4.84 1.45 0.93 1.04
    3 DL031 63.57 5.68 11.19 69.25 18.82 0.19 0.27 4.60 1.55 0.95 0.92
    4 DL033 50.18 5.74 8.74 55.92 13.69 0.19 0.28 5.04 1.05 0.82 0.96
    5 DL037 43.61 5.03 8.67 48.64 12.65 0.21 0.31 4.13 1.19 0.98 1.05
    下载: 导出CSV

    表  3  单颗粒锆石稀土元素LA-ICP-MS分析结果(×10-6)

    Table  3.   LA-ICP-MS Rare earth elements data of single grain zircon

    样品 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu ΣREE L/H δCe δEu (La/Sm)N (Lu/Gd)N
    DL007-01 0.01 59.02 0.09 2.30 5.31 2.62 36.16 13.75 182.22 78.35 402.64 97.23 1045.11 246.87 2171.69 0.03 191.74 0.43 0.00 53.26
    DL007-02 0.03 31.64 0.06 0.91 2.67 1.43 18.09 7.30 102.66 47.24 252.58 65.34 739.84 190.28 1460.06 0.03 135.78 0.47 0.01 82.05
    DL007-03 0.00 33.44 0.09 1.47 2.68 1.64 21.26 8.02 108.37 50.00 271.72 70.18 784.29 202.28 1555.43 0.03 115.61 0.46 0.00 74.22
    DL007-04 0.14 34.74 0.14 2.04 4.12 1.93 24.68 8.94 117.70 51.36 268.49 64.81 738.05 182.95 1500.08 0.03 55.19 0.45 0.02 57.82
    DL007-05 0.09 30.17 0.05 0.77 2.12 0.84 10.44 4.20 54.58 23.55 126.01 31.69 360.45 90.83 735.78 0.05 112.33 0.45 0.03 67.84
    DL007-06 0.05 44.08 0.10 1.67 4.18 2.13 25.24 9.55 133.92 59.79 317.80 81.66 917.62 231.11 1828.90 0.03 112.90 0.49 0.01 71.43
    DL007-07 0.00 54.70 0.02 2.52 6.76 2.50 51.08 20.50 266.22 115.58 563.37 128.20 1301.24 284.79 2797.46 0.02 842.78 0.29 0.00 43.49
    DL007-08 1.15 34.40 0.32 2.01 3.02 1.52 18.16 6.86 90.41 40.55 212.63 54.12 616.05 154.21 1235.41 0.04 13.56 0.48 0.24 66.26
    DL007-09 0.21 45.81 0.17 2.05 5.32 2.12 25.53 8.67 117.42 49.28 248.21 59.33 657.05 157.01 1378.16 0.04 55.36 0.46 0.03 47.98
    DL007-10 0.00 44.55 0.03 1.65 4.87 1.50 33.87 14.51 204.75 93.72 486.29 121.06 1284.51 297.99 2589.30 0.02 392.23 0.26 0.00 68.64
    DL007-11 0.12 36.32 0.14 2.06 3.37 1.68 19.76 7.44 99.80 45.95 239.97 62.10 708.75 179.06 1406.49 0.03 58.88 0.49 0.02 70.70
    DL007-12 0.00 29.23 0.02 0.76 1.63 1.10 11.85 4.56 61.93 28.16 145.71 37.17 423.29 106.68 852.09 0.04 438.10 0.55 0.00 70.25
    DL007-13 0.02 58.84 0.17 1.87 6.29 2.34 41.59 15.86 207.85 89.80 455.47 111.93 1224.45 290.68 2507.15 0.03 101.28 0.33 0.00 54.52
    DL007-14 0.00 49.55 0.06 1.58 4.19 1.70 28.27 10.72 137.70 61.17 312.84 78.16 843.54 204.64 1734.13 0.03 232.58 0.35 0.00 56.46
    DL007-15 0.00 34.94 0.07 1.35 3.52 1.05 20.49 7.88 107.96 47.01 241.11 59.16 645.20 155.05 1324.77 0.03 153.61 0.29 0.00 59.03
    DL007-16 0.03 28.77 0.07 0.88 2.49 1.35 16.95 7.66 110.24 50.74 278.10 71.44 817.01 208.43 1594.16 0.02 107.11 0.47 0.01 95.94
    DL007-17 0.00 43.72 0.06 1.18 4.43 1.51 28.37 11.69 151.42 65.62 337.43 80.66 860.27 199.28 1785.63 0.03 232.02 0.31 0.00 54.80
    DL007-18 0.00 30.62 0.07 1.60 1.21 1.09 14.43 5.90 76.41 33.53 176.18 44.34 510.97 127.88 1024.23 0.03 127.90 0.48 0.00 69.12
    DL007-19 0.06 157.53 0.23 4.36 13.64 4.84 124.32 51.03 697.12 291.49 1391.49 312.44 3078.32 665.23 6792.10 0.03 190.58 0.24 0.00 41.75
    平均值 0.10 46.43 0.10 1.74 4.31 1.84 30.03 11.84 159.40 69.62 354.11 85.84 924.00 219.75 1909.11 0.03 193.13 0.41 0.02 63.45
    DL037-1 0.65 84.65 0.28 4.39 8.55 4.12 49.82 17.45 210.57 90.52 446.45 105.82 1119.54 270.40 2413.20 0.04 47.93 0.47 0.05 42.34
    DL037-2 0.00 37.92 0.06 1.42 3.81 1.65 27.82 10.69 145.48 60.11 310.51 75.20 801.92 194.14 1670.72 0.03 208.11 0.35 0.00 54.45
    DL037-3 0.04 47.72 0.16 1.91 5.48 1.91 38.09 16.12 224.18 94.36 486.35 116.40 1235.91 290.14 2558.77 0.02 83.57 0.30 0.00 59.42
    DL037-4 0.12 44.66 0.16 3.26 7.59 2.43 56.88 23.76 297.69 122.89 605.45 137.09 1385.14 305.45 2992.56 0.02 64.78 0.26 0.01 41.89
    DL037-5 0.03 39.13 0.04 1.42 4.09 2.01 26.92 9.70 130.52 56.82 304.80 74.86 846.32 210.87 1707.53 0.03 220.54 0.44 0.00 61.11
    DL037-8 0.34 33.20 0.46 4.17 3.89 2.56 17.17 7.03 88.12 39.45 208.20 54.36 623.82 160.12 1242.90 0.04 16.87 0.81 0.05 72.73
    DL037-9 0.00 135.15 0.27 4.35 14.12 7.35 73.10 26.19 324.32 135.07 674.09 160.15 1683.28 396.17 3633.63 0.05 148.64 0.56 0.00 42.28
    DL037-11 0.06 25.23 0.05 0.70 2.80 1.86 16.69 6.75 92.98 39.89 220.82 56.85 640.45 165.02 1270.14 0.02 97.83 0.64 0.01 77.15
    DL037-12 0.00 23.35 0.03 0.78 1.42 0.97 12.54 4.47 60.54 27.95 152.14 40.02 471.96 122.85 919.03 0.03 268.66 0.47 0.00 76.41
    DL037-13 0.01 73.97 0.14 3.01 8.59 3.70 42.32 15.00 204.39 88.31 454.27 111.08 1212.54 295.05 2512.38 0.04 158.39 0.48 0.00 54.40
    DL037-14 0.00 55.90 0.07 2.08 3.20 2.73 26.26 10.28 140.25 61.14 326.88 82.44 915.89 228.23 1855.36 0.04 225.36 0.63 0.00 67.80
    DL037-15 0.00 27.56 0.05 0.61 2.54 1.20 17.99 7.51 106.36 47.02 255.39 66.63 771.96 197.01 1501.82 0.02 159.22 0.40 0.00 85.42
    DL037-16 0.13 34.16 0.06 1.05 3.18 1.85 31.36 12.92 170.07 73.29 366.20 86.21 928.32 213.46 1922.24 0.02 94.19 0.37 0.03 53.10
    DL037-17 0.00 23.91 0.07 0.72 1.30 1.15 14.31 4.81 70.66 28.34 148.11 36.94 414.00 101.20 845.51 0.03 105.22 0.51 0.00 55.17
    DL037-18 0.00 17.09 0.06 0.76 1.73 0.87 12.85 4.65 57.67 27.06 146.53 39.59 433.91 111.44 854.21 0.02 88.54 0.41 0.00 67.64
    DL037-19 0.02 28.62 0.04 1.01 2.60 1.47 18.46 7.43 103.07 45.74 245.43 61.79 689.25 174.53 1379.45 0.03 188.32 0.47 0.00 73.75
    DL037-20 0.04 30.14 0.05 0.92 1.70 1.11 12.04 4.75 66.60 29.33 159.76 41.30 475.57 118.30 941.62 0.04 143.74 0.55 0.02 76.67
    平均值 0.08 44.85 0.12 1.92 4.50 2.29 29.10 11.15 146.67 62.78 324.20 79.22 861.75 209.08 1777.71 0.03 136.47 0.48 0.01 62.45
    下载: 导出CSV
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  • 收稿日期:  2017-07-09
  • 修回日期:  2018-05-20
  • 刊出日期:  2018-06-01

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